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3-Bromobenzyl bromide

3-Bromobenzyl bromide Structure
3-Bromobenzyl bromide structure
CAS No.
823-78-9
Chemical Name:
3-Bromobenzyl bromide
Synonyms
m-Bromobenzyl;3-BromobenzyL;α,3-dibromotoluene;à,3-dibromotoluene;3-Bromoben bromide;3-BroMobenl broMide;3-Brombenzyl bromide;3-Bromobenzyl bromid;BroMobenzyl chloride;Toluene,m,α-dibromo-
CBNumber:
CB6381257
Molecular Formula:
C7H6Br2
Molecular Weight:
249.93
MDL Number:
MFCD00000176
MOL File:
823-78-9.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-06-04 16:00:12
Product description Number Pack Size Price
3-Bromobenzyl bromide 99% 187062 5g $46.4
3-Bromobenzyl bromide 99% 187062 25g $64
3-Bromobenzyl Bromide B1570 5G $21
3-Bromobenzyl Bromide B1570 25G $40
3-Bromobenzyl bromide Asreported 264202 25g $352
More product size
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3-Bromobenzyl bromide Properties

Melting point 39-41 °C(lit.)
Boiling point 130 °C12 mm Hg
Density 1,56 g/cm3
refractive index 1.6066 (estimate)
Flash point >230 °F
storage temp. Keep in dark place,Inert atmosphere,2-8°C
solubility Chloroform (Sparingly), Methanol (Slightly)
form Adhering Crystals or Crystalline Powder
color White
Water Solubility Insoluble in water.
BRN 2078683
InChI InChI=1S/C7H6Br2/c8-5-6-2-1-3-7(9)4-6/h1-4H,5H2
InChIKey ZPCJPJQUVRIILS-UHFFFAOYSA-N
SMILES C1(Br)=CC=CC(CBr)=C1
CAS DataBase Reference 823-78-9(CAS DataBase Reference)
EPA Substance Registry System Benzene, 1-bromo-3-(bromomethyl)- (823-78-9)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Corrosion (GHS05)
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363
PPE Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Hazard Codes  C
Risk Statements  34-37
Safety Statements  26-36/37/39-45-25
RIDADR  UN 3261 8/PG 2
WGK Germany  3
F  19
TSCA  TSCA listed
HazardClass  8
PackingGroup  III
HS Code  29036990
Storage Class 8A - Combustible corrosive hazardous materials
Hazard Classifications Skin Corr. 1B
Limited Quantities 1 Kg (2.2 lbs) (solid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)
NFPA 704
1
3 0

3-Bromobenzyl bromide price More Price(71)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 187062 3-Bromobenzyl bromide 99% 823-78-9 5g $46.4 2026-04-30 Buy
Sigma-Aldrich 187062 3-Bromobenzyl bromide 99% 823-78-9 25g $64 2026-04-30 Buy
TCI Chemical B1570 3-Bromobenzyl Bromide 823-78-9 5G $21 2026-04-30 Buy
TCI Chemical B1570 3-Bromobenzyl Bromide 823-78-9 25G $40 2026-04-30 Buy
Usbiological 264202 3-Bromobenzyl bromide Asreported 823-78-9 25g $352 2026-06-03 Buy
Product number Packaging Price Buy
187062 5g $46.4 Buy
187062 25g $64 Buy
B1570 5G $21 Buy
B1570 25G $40 Buy
264202 25g $352 Buy

3-Bromobenzyl bromide Chemical Properties,Uses,Production

Chemical Properties

White to yellow solid

Uses

3-Bromobenzyl bromide was used in the synthesis of, 1,7-di(3-bromobenzyl)cyclen and substituted 8-arylquinoline, phosphodiesterase 4 (PDE4) inhibitors.

Uses

3-Bromobenzyl bromide was used in the synthesis of:

  • 1,7-di(3-bromobenzyl)cyclen
  • substituted 8-arylquinoline, phosphodiesterase 4 (PDE4) inhibitors

General Description

3-Bromobenzyl bromide undergoes reduction with diethylzinc in the presence of Pd(PPh3)4 to yield corresponding hydrocarbon.

Synthesis

3-Bromotoluene

591-17-3

3-Bromobenzyl bromide

823-78-9

General procedure for the synthesis of 3-bromobenzyl bromide from 3-bromomethylbenzene: To a mixture of N-bromosuccinimide (NXS) and substrate (1 or 6) in acetonitrile (CH3CN), silicon tetrachloride (SiCl4) was slowly added at room temperature, and the reaction mixture was stirred continuously until thin-layer chromatography (TLC) monitoring showed complete disappearance of the feedstock. Subsequently, the reaction mixture was poured into water and extracted with dichloromethane (CH2Cl2). All organic phase extracts were combined and dried with anhydrous magnesium sulfate (MgSO4), followed by concentration under reduced pressure to remove the solvent. The residue was purified by recrystallization (petroleum ether-ether, 3:1) to give the pure products 2b-2g or 3b; or by silica gel column chromatography (hexane-ethyl acetate, 10:1 or 30:1) to give the pure products 2a, h, i, 3a-5 or 7-9.

References

[1] Journal of Organic Chemistry, 2014, vol. 79, # 1, p. 223 - 229
[2] Synthetic Communications, 2010, vol. 40, # 7, p. 998 - 1003
[3] Tetrahedron Letters, 2011, vol. 52, # 31, p. 4026 - 4029
[4] Patent: US2009/12171, 2009, A1. Location in patent: Page/Page column 11
[5] Patent: WO2005/105736, 2005, A1. Location in patent: Page/Page column 28

3-Bromobenzyl bromide Preparation Products And Raw materials

Raw materials

3-Bromotoluene N-Bromosuccinimide Acetonitrile Tetrachlorosilane

Preparation Products

Butylamine Hydrobromide 4-bromo-2-(bromomethyl)-1-nitrobenzene (3-BROMOBENZYL)METHYLAMINE 3-Bromostyrene 3-Bromobenzylamine
3-Bromobenzyl alcohol 1-(3-BROMOBENZYL)-1H-INDOLE-3-CARBALDEHYDE Acetic acid, 2-[[(3-bromophenyl)methyl]sulfonyl]- diethyl (acetylamino)(3-bromobenzyl)malonate [(3-bromobenzyl)sulfanyl]acetic acid

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3-Bromobenzyl bromide Suppliers

Global( 342)Suppliers
Supplier Tel Email Country ProdList Advantage
Henan Fengda Chemical Co., Ltd 		+86-371-86557731 +86-13613820652 info@fdachem.com China 20111 58
Capot Chemical Co.,Ltd. 		+86-（0）57185586718 +86-13336195806 sales@capot.com China 29626 60
Shanghai Daken Advanced Materials Co.,Ltd 		+86-2158073036 info@dakenam.com China 14036 58
Henan Tianfu Chemical Co.,Ltd. 		+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21533 55
career henan chemical co 		+86-0371-86658258 sales@coreychem.com China 29766 58
Xiamen AmoyChem Co., Ltd 		+86-86-5926051114 sales@amoychem.com China 6339 58
CONIER CHEM AND PHARMA LIMITED 		sales@conier.com China 49906 58
SIMAGCHEM CORP 		+86-5922680277 +86-13806087780 sale@simagchem.com China 17339 58
Hefei TNJ Chemical Industry Co.,Ltd. 		+86-0551-65418671 +86-189 4982 3763 sales@tnjchem.com China 34526 58
Shaanxi Dideu Medichem Co. Ltd 		+86-29-81139210 +86-17392587031 1059@dideu.com China 9984 58
Supplier Advantage
Henan Fengda Chemical Co., Ltd 		58
Capot Chemical Co.,Ltd. 		60
Shanghai Daken Advanced Materials Co.,Ltd 		58
Henan Tianfu Chemical Co.,Ltd. 		55
career henan chemical co 		58
Xiamen AmoyChem Co., Ltd 		58
CONIER CHEM AND PHARMA LIMITED 		58
SIMAGCHEM CORP 		58
Hefei TNJ Chemical Industry Co.,Ltd. 		58
Shaanxi Dideu Medichem Co. Ltd 		58

View Lastest Price from 3-Bromobenzyl bromide manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
3-Bromobenzyl bromide pictures 2026-08-20 3-Bromobenzyl bromide
823-78-9
 $1.00-100.00 1KG 99% Henan Fengda Chemical Co., Ltd
3-Bromobenzyl bromide pictures 2025-06-27 3-Bromobenzyl bromide
823-78-9
 $10.00-30.00 50KG 99% 500000kg Hebei Chuanghai Biotechnology Co., Ltd
3-Bromobenzyl bromide pictures 2025-06-20 3-Bromobenzyl bromide
823-78-9
 1kg 0.99 20 tons Hebei Yanxi Chemical Co., Ltd.

3-Bromobenzyl bromide Spectrum

3-Bromobenzyl bromide(823-78-9)MS3-Bromobenzyl bromide(823-78-9)1HNMR3-Bromobenzyl bromide(823-78-9)13CNMR3-Bromobenzyl bromide(823-78-9)IR13-Bromobenzyl bromide(823-78-9)IR23-Bromobenzyl bromide(823-78-9)Raman

823-78-9(3-Bromobenzyl bromide )Related Search:

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3-Bromotoluene Diethylstilbestrol Sodium bromate BRETYLIUM TOSYLATE 3-Bromofluorobenzene
3-Bromobenzyl alcohol 3-Nitrobenzyl bromide (3-NITROPHENYL)ACETIC ACID METHYL ESTER 3-Bromoanisole 3-Nitroacetophenone
3-Nitrobenzaldehyde 1-Bromo-3-iodobenzene 3-Bromobenzonitrile Bromobenzyl Chloride

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3-Brombenzyl bromide ALPHA,3-DIBROMOTOLUENE ALPHA,M-DIBROMOTOLUENE 3-BROMOBENZYL BROMIDE 3-Bromo Benzyl Bromide m-Bromobenzyl Bromide 3-BromobenzylBromide98% 3-Bromobenzylbromide,99% m-Bromobenzyl Benzene, 1-bromo-3-(bromomethyl)- à,3-dibromotoluene α,3-dibromotoluene 1-bromo-3-(bromomethyl)-benzene 1-(Bromomethyl)-3-bromobenzene 3-Bromobenzyl bromide,95% 3-Bromobenzyl bromid BroMobenzyl chloride 3-BroMobenzyl broMide, 95% 25GR 3-BroMobenzyl broMide, 95% 5GR [(3-broMophenyl)Methyl]broManuide 3-BroMobenl broMide alpha,3-Dibromotoluene, 1-Bromo-3-(bromomethyl)benzene 1-bromo-3-(bromomethyl)-benzen Toluene,m,α-dibromo- M-BROMOBENZYL BROMIDE Benzyl broMide broMine between 3-Bromoben bromide 3-BroMobenzyl BroMide, 97+% 3-BromobenzyL 3-Bromobenzyl Bromide > 3-Bromobenzyl bromide ISO 9001：2015 REACH 1-bromo-3-(bromomethyl)benzene D6 High purity CAS 823-78-9 3-Bromobenzyl bromide in stock 823-78-9 C7H6Br2 BrC6H4CH2Br Halogenated Hydrocarbons Organic Building Blocks BENZYL HALIDE Aryl C7 Building Blocks alkyl bromide Benzyl Aromatic Halides (substituted) bc0001