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ChemicalBook >> CAS DataBase List >>4-bromo-2-(bromomethyl)-1-nitrobenzene

4-bromo-2-(bromomethyl)-1-nitrobenzene

4-bromo-2-(bromomethyl)-1-nitrobenzene Structure
4-bromo-2-(bromomethyl)-1-nitrobenzene structure
CAS No.
35287-42-4
Chemical Name:
4-bromo-2-(bromomethyl)-1-nitrobenzene
Synonyms
5-bromo-2-nitrobenzyl bromide;L-Valine,5-mercapto-,methylester;4-bromo-2-(bromomethyl)-1-nitrobenzene;Benzene, 4-bromo-2-(bromomethyl)-1-nitro-
CBNumber:
CB01559376
Molecular Formula:
C7H5Br2NO2
Molecular Weight:
294.93
MDL Number:
MFCD11848689
MOL File:
35287-42-4.mol
Last updated:2025-08-08 17:45:00
Product description Number Pack Size Price
5-Bromo-2-nitrobenzylbromide OR400606 250mg $114
5-Bromo-2-nitrobenzyl bromide 4754-9-45 250mg $125
5-Bromo-2-nitrobenzylbromide OR400606 1g $279
5-Bromo-2-nitrobenzyl bromide 4754-9-45 1g $308
4-BROMO-2-(BROMOMETHYL)-1-NITROBENZENE 95.00% HCH0047104 5MG $505.65
Request For Quotation

4-bromo-2-(bromomethyl)-1-nitrobenzene Properties

Boiling point 330.2±27.0 °C(Predicted)
Density 2.006±0.06 g/cm3(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form crystalline solid
color Light yellow

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H319
Precautionary statements  P305+P351+P338
HS Code  2904990090

4-bromo-2-(bromomethyl)-1-nitrobenzene price

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Apolloscientific OR400606 5-Bromo-2-nitrobenzylbromide 35287-42-4 250mg $114 2021-12-16 Buy
SynQuest Laboratories 4754-9-45 5-Bromo-2-nitrobenzyl bromide 35287-42-4 250mg $125 2021-12-16 Buy
Apolloscientific OR400606 5-Bromo-2-nitrobenzylbromide 35287-42-4 1g $279 2021-12-16 Buy
SynQuest Laboratories 4754-9-45 5-Bromo-2-nitrobenzyl bromide 35287-42-4 1g $308 2021-12-16 Buy
American Custom Chemicals Corporation HCH0047104 4-BROMO-2-(BROMOMETHYL)-1-NITROBENZENE 95.00% 35287-42-4 5MG $505.65 2021-12-16 Buy
Product number Packaging Price Buy
OR400606 250mg $114 Buy
4754-9-45 250mg $125 Buy
OR400606 1g $279 Buy
4754-9-45 1g $308 Buy
HCH0047104 5MG $505.65 Buy

4-bromo-2-(bromomethyl)-1-nitrobenzene Chemical Properties,Uses,Production

Synthesis

(5-bromo-2-nitrophenyl)methanol

1241894-37-0

4-bromo-2-(bromomethyl)-1-nitrobenzene

35287-42-4

To a stirred solution of (5-bromo-2-nitrophenyl)methanol (2.8 g, 12.06 mmol) in a solvent mixture of dichloromethane (DCM) and acetonitrile (MeCN) (1:1, 100 mL) was added sequentially at 0 °C carbon tetrabromide (CBr4) (5.2 g, 15.68 mmol) and triphenylphosphine (PPh3) (4.1 g. 15.68 mmol). The reaction mixture was stirred at room temperature for 16 hours. Upon completion of the reaction, the mixture was concentrated under reduced pressure and the residue was purified by fast column chromatography on silica gel (petroleum ether (PE)/ethyl acetate (EA) = 50:1 to 10:1 gradient elution) to afford the target product 4-bromo-2-(bromomethyl)-1-nitrobenzene (1.1 g, 31% yield).

References

[1] Patent: WO2018/68017, 2018, A1. Location in patent: Page/Page column 154; 155; 156; 157

4-bromo-2-(bromomethyl)-1-nitrobenzene synthesis

1241894-37-0
35287-42-4
Synthesis of 4-bromo-2-(bromomethyl)-1-nitrobenzene from (5-bromo-2-nitrophenyl)methanol

4-bromo-2-(bromomethyl)-1-nitrobenzene Preparation Products And Raw materials

Raw materials

Benzene, 2-bromo-4-(bromomethyl)-1-nitro- 3-Bromobenzyl bromide (5-bromo-2-nitrophenyl)methanol 4-BROMO-2-METHYL-1-NITROBENZENE 5-BROMO-2-NITRO-BENZOIC ACID
Triphenylphosphine Acetonitrile Dichloromethane Carbon tetrabromide

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Preparation Products

4-bromo-2-(bromomethyl)-1-nitrobenzene Suppliers

Global( 53)Suppliers
Supplier Tel Email Country ProdList Advantage
Shaanxi Dideu Medichem Co. Ltd 		+86-029-81138252 +86-173 9270 1263 1057@dideu.com China 4000 58
Changzhou Ansciep Chemical Co., Ltd. 		+86 519 86305871 sales@ansciepchem.com CHINA 4241 58
Fuxin Pharmaceutical 		+86-021-021-50872116 +8613122107989 contact@fuxinpharm.com China 10035 58
Hefei TNJ Chemical Industry Co.,Ltd. 		+86-0551-65418671 +8618949823763 sales@tnjchem.com China 34563 58
Win-Win chemical CO., Limited 		+86-0086-577-64498589 +86-15355981851 sales@win-winchemical.com China 14360 58
Aromsyn Co., Ltd. 		+86-0571-85585865 +8613336024896 CB@aromsyn.com China 19183 58
Aceschem Inc. 		+1-817863-6948 +1-（817）863-6948 sales@aceschem.com United States 19632 58
Aladdin Scientific 		tp@aladdinsci.com United States 52924 58
Amadis Chemical Company Limited 		571-89925085 sales@amadischem.com China 131957 58
Chengdu Feibo Pharm Technology Co., Ltd +86 028-84641798 15982321820 abby@arkpharm.com China 10000 58
Supplier Advantage
Shaanxi Dideu Medichem Co. Ltd 		58
Changzhou Ansciep Chemical Co., Ltd. 		58
Fuxin Pharmaceutical 		58
Hefei TNJ Chemical Industry Co.,Ltd. 		58
Win-Win chemical CO., Limited 		58
Aromsyn Co., Ltd. 		58
Aceschem Inc. 		58
Aladdin Scientific 		58
Amadis Chemical Company Limited 		58
Chengdu Feibo Pharm Technology Co., Ltd 58

View Lastest Price from 4-bromo-2-(bromomethyl)-1-nitrobenzene manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
4-bromo-2-(bromomethyl)-1-nitrobenzene pictures 2024-08-17 4-bromo-2-(bromomethyl)-1-nitrobenzene
35287-42-4
 US $1.00 / KG 1KG 99% 20T Shaanxi Dideu Medichem Co. Ltd

4-bromo-2-(bromomethyl)-1-nitrobenzene Spectrum

4-bromo-2-(bromomethyl)-1-nitrobenzene(35287-42-4)1HNMR
4-bromo-2-(bromomethyl)-1-nitrobenzene 5-bromo-2-nitrobenzyl bromide Benzene, 4-bromo-2-(bromomethyl)-1-nitro- L-Valine,5-mercapto-,methylester 35287-42-4