ChemicalBook >> CAS DataBase List >>2-Bromoanthracene

2-Bromoanthracene

CAS No.
7321-27-9
Chemical Name:
2-Bromoanthracene
Synonyms
2-BROMOANTHRACENE;2-BroMoantharacene;2-Bromonatthracene;Anthracene, 2-broMo-;2-Bromoanthracene >2-Bromoanthracene,97%;2-Bromoanthracene 97%
CBNumber:
CB6413244
Molecular Formula:
C14H9Br
Molecular Weight:
257.13
MDL Number:
MFCD07784002
MOL File:
7321-27-9.mol
MSDS File:
SDS
Last updated:2026-05-28 05:14:38

2-Bromoanthracene Properties

Melting point 220 °C
Boiling point 389.7±11.0 °C(Predicted)
Density 1.479±0.06 g/cm3(Predicted)
storage temp. Sealed in dry,Room Temperature
solubility Chloroform (Slightly), DMSO (Sparingly), Methanol (Very Slightly)
form Solid
color Pale Yellow
InChI InChI=1S/C14H9Br/c15-14-6-5-12-7-10-3-1-2-4-11(10)8-13(12)9-14/h1-9H
InChIKey PYXBCVWIECUMDW-UHFFFAOYSA-N
SMILES C1=C2C(C=C3C(=C2)C=CC=C3)=CC=C1Br
CAS DataBase Reference 7321-27-9(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319
Precautionary statements  P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313
Safety Statements  24/25
HS Code  29039990

2-Bromoanthracene price More Price(40)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical B2616 2-Bromoanthracene >97.0%(GC) 7321-27-9 1g $65 2026-04-30 Buy
TCI Chemical B2616 2-Bromoanthracene >97.0%(GC) 7321-27-9 5g $271 2026-04-30 Buy
TRC TRC-B680133-100MG 2-Bromoanthracene 7321-27-9 100mg $68 2026-06-03 Buy
AstaTech 36004 2-BROMO-ANTHRACENE 97% 7321-27-9 5G $30 2026-04-30 Buy
AstaTech 36004 2-BROMO-ANTHRACENE 97% 7321-27-9 25G $112 2026-04-30 Buy
Product number Packaging Price Buy
B2616 1g $65 Buy
B2616 5g $271 Buy
TRC-B680133-100MG 100mg $68 Buy
36004 5G $30 Buy
36004 25G $112 Buy

2-Bromoanthracene Chemical Properties, Uses, Production

Uses

2-Bromoanthracene exhibits high chemical reactivity at its 9 and 10 positions. By introducing different functional groups at these positions, a series of anthracene derivatives with good film-forming properties, high thermal stability, high fluorescence, suitable carrier transport, and good photoelectric performance can be obtained. 2-Bromoanthracene organic materials possess high fluorescence efficiency and are commonly used blue light materials in OLEDs.

Chemical Properties

Yellow solid

Synthesis

2-Bromoanthraquinone

572-83-8

2-Bromoanthracene

7321-27-9

In the preferred embodiment, 275.0 g of diethylene glycol dimethyl ether was added to a 500 mL three-necked flask, 68.0 g (0.51 mol) of aluminum chloride solids were slowly added, the temperature was controlled at 60°C, and the addition process took about 20 min, and the system became grey or milky white and cloudy. Cool to 30 °C and set aside. To another 1 L three-necked flask was added 49.2 g (0.17 mol) of 2-bromoanthracene-9,10-dione, 200.0 g of diethylene glycol dimethyl ether, and 27.5 g (0.51 mol) of potassium with stirring. Subsequently, borohydride was added and the system was changed to a yellow-green turbid solution, which was heated to 105 °C and maintained for 30 min. During heating, the system was changed from a yellow-green turbid solution to a pink turbid solution and finally to a brown turbid solution. After the reaction was completed, the above aluminum chloride solution was slowly added to the system, and the internal temperature was controlled to be between 90 and 110 °C. In the exothermic reaction of the first 1/3 stage of the drop, the second 2/3 stage of the heat-absorbing reaction, drop during the process of gas bubbles, the system from the brown turbid liquid to bright yellow turbid liquid, and ultimately become a yellow turbid liquid. The dosing process took about 20 min, and the system was quickly cooled down to 40°C in a water bath after the dosing was completed. The system was poured into a mixture of concentrated hydrochloric acid, water and ethanol (100 g/400 g/300 g), accompanied by the generation of large amounts of gas. The temperature was controlled to be below 60°C during the hydrolysis. After completion of hydrolysis, it was cooled to 25 °C, filtered, and the filter cake was washed with 100.0 g of water and 100.0 g of anhydrous ethanol to obtain a yellow filter cake, which is the crude product. Mix the crude product with anhydrous ethanol in the ratio of 1:10, heat to 50~60°C, stirring for 1.0 h, cool to 25~30°C, keep warm for 0.5 h, extract and filter, wash the filter cake with a small amount of anhydrous ethanol to get a white solid, which is the pure product. After drying (50 °C, 200 Pa, 5 h), 35.8 g of white powdery solid was obtained with 82.02% yield.

References

[1] Patent: CN106916049, 2017, A. Location in patent: Paragraph 0031; 0032; 0033; 0034; 0035; 0036; 0037-0042
[2] Dyes and Pigments, 2015, vol. 120, p. 30 - 36
[3] Bulletin of the Korean Chemical Society, 2012, vol. 33, # 11, p. 3810 - 3816
[4] Journal of Nanoscience and Nanotechnology, 2012, vol. 12, # 5, p. 4269 - 4273
[5] Tetrahedron Letters, 2003, vol. 44, # 6, p. 1215 - 1219

572-83-8
7321-27-9
Synthesis of 2-Bromoanthracene from 2-Bromoanthraquinone
Global Suppliers ( 270)
Supplier Tel Email Country ProdList Advantage
Liuyang huarui material technology co., ltd. 13467605171 2580432242@qq.com China 184 58
T&W GROUP 021-61551611 13296011611 contact@trustwe.com China 9884 58
Harbin Jiekai new material Co., Ltd. 15104587591; 18245017205 sales@jiekaichem.com China 38 58
Xi'an duokai Trading Co., Ltd 029-82283472 15091869467 1055507341@qq.com China 298 58
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24512 81
Ark Pharm, Inc. 847-367-3680 sales@arkpharminc.com United States 1669 56
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Shijiazhuang Sdyano Fine Chemical Co., Ltd. 0311-89250318 13582355795 master@sjzsdyn.com China 2776 65

View Latest Price from 2-Bromoanthracene manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-Bromoanthracene pictures 2026-09-16 2-Bromoanthracene
7321-27-9
$5.00 1kg ≥99% 100mt/year Jinan Finer Chemical Co., Ltd
2-Bromoanthracene pictures 2026-09-16 2-Bromoanthracene
7321-27-9
1KG 98%min 30tons/month WUHAN FORTUNA CHEMICAL CO., LTD
2-Bromoanthracene pictures 2023-11-08 2-Bromoanthracene
7321-27-9
1kg 99.9% 30000 KG Hebei Xinsheng New Material Technology Co., LTD.
2-BROMOANTHRACENE 2-BroMoantharacene 2-Bromoanthracene 97% Anthracene, 2-broMo- 2-Bromonatthracene 2-Bromoanthracene,97% 2-Bromoanthracene > 7321-27-9 73321-27-9 Anthracenes Anthracene derivatives OLED materials,pharm chemical,electronic Electronic Chemicals Anthracenes Anthracene series OLED