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1-Naphthoic acid

CAS No.
86-55-5
Chemical Name:
1-Naphthoic acid
Synonyms
1-NAPHTHALENECARBOXYLIC ACID;NAPHTHALENE-1-CARBOXYLIC ACID;NSC 37569;1-naphthoic;1-phthoic acid;1-Naphthoesure;1-NAPTHOIC ACID;1-Naphtoic Acid;a-naphthoic acid;1-NAPHTHOIC ACID
CBNumber:
CB6475509
Molecular Formula:
C11H8O2
Molecular Weight:
172.18
MDL Number:
MFCD00004007
MOL File:
86-55-5.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-28 03:46:52

1-Naphthoic acid Properties

Melting point 157-160 °C (lit.)
Boiling point 300 °C (lit.)
Density 1.398
refractive index 1.4600 (estimate)
Flash point 195°C
storage temp. Sealed in dry,Room Temperature
solubility Slightly soluble in hot water; freely soluble in hot ethanol, ether
form Powder
pka 3.7(at 25℃)
color Slightly yellow to brown
Specific Gravity 1.398
PH Range Non& uorescence (2.5) to blue & uorescence (3.5)
Water Solubility Freely soluble in hot alcohol and ether. Slightly soluble in hot water.
λmax 293nm
Merck 14,6381
BRN 1908896
Stability Stable. Incompatible with strong bases, strong oxidizing agents.
Major Application Photoresists, recording materials, waveguides, battery, ink, rubber, plastic films, agriculture, cosmetics, Sunscreen, method for preserving food, drugs, biosensors
InChI 1S/C11H8O2/c12-11(13)10-7-3-5-8-4-1-2-6-9(8)10/h1-7H,(H,12,13)
InChIKey LNETULKMXZVUST-UHFFFAOYSA-N
SMILES OC(=O)c1cccc2ccccc12
CAS DataBase Reference 86-55-5(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII 2NIV4O66BH
NIST Chemistry Reference 1-Naphthalenecarboxylic acid(86-55-5)
EPA Substance Registry System 1-Naphthalenecarboxylic acid (86-55-5)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319-H303-H335
Precautionary statements  P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P261-P280a-P304+P340-P305+P351+P338-P405-P501a
PPE dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36-24/25-37
WGK Germany  2
RTECS  QL0960000
TSCA  TSCA listed
HS Code  29163900
Storage Class 11 - Combustible Solids
NFPA 704
1
2 0

1-Naphthoic acid price More Price(66)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich N1909 1-Naphthoic acid 96% 86-55-5 25g $44.6 2026-04-30 Buy
TCI Chemical N0024 1-Naphthoic Acid >98.0%(T) 86-55-5 25g $48 2026-04-30 Buy
TCI Chemical N0024 1-Naphthoic Acid >98.0%(T) 86-55-5 500g $226 2021-12-16 Buy
Cayman Chemical 11322 1-Naphthoic Acid ≥98% 86-55-5 25g $25 2021-12-16 Buy
Cayman Chemical 11322 1-Naphthoic Acid ≥98% 86-55-5 50g $48 2021-12-16 Buy
Product number Packaging Price Buy
N1909 25g $44.6 Buy
N0024 25g $48 Buy
N0024 500g $226 Buy
11322 25g $25 Buy
11322 50g $48 Buy

1-Naphthoic acid Chemical Properties, Uses, Production

Chemical Properties

Off-white to beige powder

Uses

1-Naphthoic acid is used as an intermediate for the synthesis of pharmaceuticals, photochemicals, plant growth hormones, dyes and other organic compounds.

Definition

ChEBI: 1-naphthoic acid is a naphthoic acid carrying a carboxy group at position 1. It has a role as a fungal xenobiotic metabolite and a bacterial xenobiotic metabolite. It is a conjugate acid of a 1-naphthoate.

Application

1-Naphthoic acid has been used as a novel asymmetric chromophore for exciton-coupled circular dichroism (ECCD), which can be used to induce chirality[1]. 1-Naphthoic acid has also been used as an organic synthesis reactant for the preparation of naphthanones, isocoumarin derivatives, and naphthalene carboxylic acid cellulose. Microcrystalline cellulose (MCC) and cellulose nanofibres (CNFs) were modified by esterification using 1-Naphthoic acid in a toluenesulfonyl chloride/pyridine solvent system to produce fluorophore labelled cellulose. Cellulose modification decreases the degradation temperature and hence the thermal stability of cellulose. After induction of naphthoate side chains, a glass transition temperature (Tg) of about 160 °C was observed. Cellulose naphthalenecarboxylate shows a strong ultraviolet (UV) absorption peak at 282 nm and has good fluorescent properties. Therefore, it can be used for fluorescent coatings, sensors and packaging[2].

Synthesis Reference(s)

Organic Syntheses, Coll. Vol. 2, p. 425, 1943
Tetrahedron Letters, 22, p. 1013, 1981 DOI: 10.1016/S0040-4039(01)82853-7

Purification Methods

Crystallise the acid from toluene (3mL/g) (charcoal), pet ether (b 80-100o), or aqueous 50% EtOH. The amide has m 202o (from EtOH). [Beilstein 9 IV 2402.]

References

[1] BIANCA SCHREDER. 1-Naphthoic acid: A new type of asymmetric chromophore for exciton-coupled circular dichroism (ECCD)[J]. Tetrahedron, asymmetry, 1996, 7 6: Pages 1543-1546. DOI:10.1016/0957-4166(96)00176-0.
[2] LEASE J, SAHIN Z M, FARID M A A, et al. Synthesis of Nanocellulose Derivatives through Esterification with Naphthoic Acid as a Fluorescent Additive[J]. ACS Sustainable Chemistry & Engineering, 2024, 343 1. DOI:10.1021/acssuschemeng.4c04206.

941-98-0
86-55-5
Synthesis of 1-Naphthoic acid from 1'-Acetonaphthone
Global Suppliers ( 450)
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Shanghai Fenghuida Chemical Co.Ltd 15821050869; 13651654205 1060281603@qq.com China 14 58
Beijing Century Richap Chemistry Co., Ltd. 010-64446226 13146983882 info@bj-newcenturychem.com China 111 55
cuicheng bio 13186333400 m13108465082@163.com China 885 58
Changzhou Zeyuan Pharmaceutical Technology Co., Ltd 19026388314 2589694173@qq.com China 164 58
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Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
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TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24512 81
Beijing HwrkChemical Technology Co., Ltd 89508211 18501085097 sales.bj@hwrkchemical.com China 9407 55
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61

View Latest Price from 1-Naphthoic acid manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
1-Naphthoic acid pictures 2026-05-28 1-Naphthoic acid
86-55-5
$10.70 10KG 99% 10000kg Hebei Chuanghai Biotechnology Co,.LTD
1-Naphthoic acid pictures 2026-03-20 1-Naphthoic acid
86-55-5
$10.00 100KG 99% 100 mt Hebei Chuanghai Biotechnology Co., Ltd
1-Naphthoic acid pictures 2025-04-04 1-Naphthoic acid
86-55-5
1kg 98% 1Ton Henan Aochuang Chemical Co.,Ltd.
LABOTEST-BB LT00855493 a-naphthoic acid ALPHA-NAPHTHOIC ACID 1-NAPHTHOIC ACID 1-NAPTHOIC ACID RARECHEM AL BO 0197 α-Naphthoic acid NAPHTHALENE-1-CARBOXYLIC ACID OTAVA-BB BB7210540007 1-Carboxynaphthalene 1-Naphthioic acid 1-naphthoic alpha-Naphthylcarboxylic acid alpha-naphthylcarboxylicacid Naphthalene-alpha-carboxylic acid naphthalene-alpha-carboxylicacid 1-naphthoic acid (alpha) 1-NAPHTHOIC ACID 98% 1-NaphthoicAcid98% 1-Naphthalenecarboxylicaci 1-Naphthylcarboxylic acid 1-Naphthoic acid, 98% 25GR 1-Naphtoic Acid 1-NAPHTHOIC ACID FOR SYNTHESIS NSC 37569 α-Naphthylcarboxylic acid 1 - naphthalene forMic acid 1-phthoic acid 1-Naphthoesure 1-NaphthoicAcid> 1-Naphthoic acid (8CI) Difethialone Impurity 4 1-NAPHTHALENECARBOXYLIC ACID 86-55-5 86-55-2 86-65-5 C10H7CO2H C10H7COOH Organic Building Blocks Building Blocks C11 to C12 Carboxylic Acids Carbonyl Compounds CARBOXYLIC ACID Building Blocks C11 to C12 Carbonyl Compounds Carboxylic Acids Chemical Synthesis Organic Building Blocks intermediates Fluorescent Naphthalene Naphthalene series Aromatic Compounds Naphthalene derivatives Organic acids bc0001