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(2S)-(+)-Glycidyl 4-nitrobenzoate

CAS No.
115459-65-9
Chemical Name:
(2S)-(+)-Glycidyl 4-nitrobenzoate
Synonyms
Ccris 6396;Brn 0087687;(S)-(+)-GLYCIDYL-4-NITROBENZOATE;(2S)-(+)-Glycidyl 4-nitr0benzoate;(2S)-(+)-Glycidyl 4-nitrobenzoate;4-nitrobenzoate,(s)-oxiranemethano;2,3-EPOXYPROPYLESTER-4-NITROBENZOATE;Oxiranemethanol, 4-nitrobenzoate, (S)-;(S)-(+)-Oxirane-2-methanol 4-nitrobenzoate;4-17-00-01007 (Beilstein Handbook Reference)
CBNumber:
CB6722979
Molecular Formula:
C10H9NO5
Molecular Weight:
223.18
MDL Number:
MFCD00064490
MOL File:
115459-65-9.mol
Last updated:2026-09-12 18:54:22

(2S)-(+)-Glycidyl 4-nitrobenzoate Properties

Melting point 60-62 °C (lit.)
storage temp. 2-8°C
optical activity [α]19/D +37°, c = 1.08 in chloroform
BRN 87687
EWG's Food Scores 1
FDA UNII 45LBL78MB2

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3
RTECS  RR0511020
10-21

(2S)-(+)-Glycidyl 4-nitrobenzoate price More Price(2)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 300446 (2S)-(+)-Glycidyl 4-nitrobenzoate 98% 115459-65-9 1g $78.5 2023-01-07 Buy
AHH MT-14276 (2S)-(+)-Glycidyl 4-nitr0benzoate 97% 25g $430 2026-05-26 Buy
Product number Packaging Price Buy
300446 1g $78.5 Buy
MT-14276 25g $430 Buy

(2S)-(+)-Glycidyl 4-nitrobenzoate Chemical Properties, Uses, Production

Purification Methods

Purify glycidol by fractional distillation.The 4-nitrobenzoates have m 56o (±); m 60-62o, [] D 20 -37.9o (c 3.38 CHCl3) for R-(-)-isomer [106268-95-5];m 60-62o, [] D 20 +38o (c 1 CHCl3) for the S-(+)-isomer [115459-65-9] and are recrystallised from Et2O or Et2O/pet ether (b 40-60o) [S-isomer: Burgos et al. J Org Chem 52 4973 1987, Sowden & Fischer J Am Chem Soc 64 1291 1942.] [Beilstein 17 I 50, 17 III/IV 985, 17/3 V 9.] Gramine.

57044-25-4
62-23-7
115459-65-9
Synthesis of (2S)-(+)-Glycidyl 4-nitrobenzoate from (R)-(+)-Glycidol and 4-Nitrobenzoic acid

(2S)-(+)-Glycidyl 4-nitrobenzoate Preparation Products And Raw materials

Raw materials

Preparation Products

(2S)-(+)-Glycidyl 4-nitrobenzoate Suppliers

Global Suppliers ( 13)
Supplier Tel Email Country ProdList Advantage
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51389 80
Shaanxi Dideu Medichem Co. Ltd 81148925 17391631969 1023@dideu.com China 9999 58
Aladdin Scientific tp@aladdinsci.com United States 50089 58
(S)-(+)-GLYCIDYL-4-NITROBENZOATE (2s)-(+)-(2,3-epoxypropylester)-4-nitrobenzoate 4-nitrobenzoate,(s)-oxiranemethano (2S)-(+)-Glycidyl 4-nitr0benzoate 4-17-00-01007 (Beilstein Handbook Reference) 2,3-EPOXYPROPYLESTER-4-NITROBENZOATE (S)-(+)-Glycidyl 4-nitrobenzoate, (S)-(+)-Oxirane-2-methanol 4-nitrobenzoate (S)-(+)-Oxirane-2-methanol 4-nitrobenzoate Brn 0087687 Ccris 6396 Oxiranemethanol, 4-nitrobenzoate, (S)- 2-Oxiranemethanol, 2-(4-nitrobenzoate), (2S)- (2S)-(+)-Glycidyl 4-nitrobenzoate 115459-65-9 Epoxides Organic Building Blocks Asymmetric Synthesis Chiral Building Blocks