(2S,3S)-(-)-BIS(DIPHENYLPHOSPHINO)BUTANE
- CAS No.
- 64896-28-2
- Chemical Name:
- (2S,3S)-(-)-BIS(DIPHENYLPHOSPHINO)BUTANE
- Synonyms
- 93.0%(GC);(S,S)-CHIRAPHOS;(2S,3S)-Chiraphos;(S,S)-Chiraphos,97%;(S,S)-Chiraphos, 97% 250MG;(2S 3S)-(-)-2 3-BIS(DIPHENYLPHOSPHINO)-&;(2S,3S)-(-)-BIS(DIPHENYLPHOSPHINO)BUTANE;(2S,3S)-(-)-2,3-BIS(DIPHENYLPHOSPHINO)BUTANE;Chiraphos, bis(diphenylphosphino)-2,3 butane;(2S,3S)-Butane-2,3-diylbis(diphenylphosphine)
- CBNumber:
- CB7163229
- Molecular Formula:
- C28H28P2
- Molecular Weight:
- 426.47
- MDL Number:
- MFCD00009836
- MOL File:
- 64896-28-2.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| (2S,3S)-(?)-Bis(diphenylphosphino)butane | 259098 | 250mg | $215 |
| (2S,3S)-(?)-Bis(diphenylphosphino)butane | 259098 | 1g | $810 |
| (2S,3S)-(-)-Bis(diphenylphosphino)butane >93.0%(GC) | B2704 | 1g | $294 |
| (2S,3S)-(-)-Bis(diphenylphosphino)butane >93.0%(GC) | B2704 | 100mg | $54 |
| (2S,3S)-(-)-Bis(diphenylphosphino)butane (S,S)-CHIRAPHOS | 15-0160 | 250mg | $110 |
| More product size | |||
| Melting point | 104-109 °C |
|---|---|
| alpha | D27 -211° (c = 1.5 in CHCl3) |
| Boiling point | 529.2±33.0 °C(Predicted) |
| storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
| solubility | Acetonitrile, Chloroform |
| form | crystal |
| color | white |
| optical activity | [α]22/D 191°, c = 1.5 in chloroform |
| Sensitive | Air Sensitive |
| Merck | 14,2063 |
| BRN | 4268869 |
| InChI | InChI=1/C28H28P2/c1-23(29(25-15-7-3-8-16-25)26-17-9-4-10-18-26)24(2)30(27-19-11-5-12-20-27)28-21-13-6-14-22-28/h3-24H,1-2H3/t23-,24-/s3 |
| InChIKey | FWXAUDSWDBGCMN-DPVGMKQNNA-N |
| SMILES | P([C@@H](C)[C@H](C)P(C1C=CC=CC=1)C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1 |&1:1,3,r| |
| CAS DataBase Reference | 64896-28-2(CAS DataBase Reference) |
| FDA UNII | 6QR78GZL9B |
| UNSPSC Code | 12352002 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) | ![]() GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 | |||||||||
| target organs | Respiratory system | |||||||||
| PPE | dust mask type N95 (US), Eyeshields, Gloves | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 37/39-26-36 | |||||||||
| WGK Germany | 3 | |||||||||
| TSCA | No | |||||||||
| HS Code | 29310099 | |||||||||
| Storage Class | 11 - Combustible Solids | |||||||||
| Hazard Classifications | Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
|||||||||
| NFPA 704 |
|
(2S,3S)-(-)-BIS(DIPHENYLPHOSPHINO)BUTANE price More Price(41)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 259098 | (2S,3S)-(?)-Bis(diphenylphosphino)butane | 64896-28-2 | 250mg | $215 | 2026-03-19 | Buy |
| Sigma-Aldrich | 259098 | (2S,3S)-(?)-Bis(diphenylphosphino)butane | 64896-28-2 | 1g | $810 | 2026-03-19 | Buy |
| TCI Chemical | B2704 | (2S,3S)-(-)-Bis(diphenylphosphino)butane >93.0%(GC) | 64896-28-2 | 1g | $294 | 2026-03-19 | Buy |
| TCI Chemical | B2704 | (2S,3S)-(-)-Bis(diphenylphosphino)butane >93.0%(GC) | 64896-28-2 | 100mg | $54 | 2026-03-19 | Buy |
| Strem Chemicals | 15-0160 | (2S,3S)-(-)-Bis(diphenylphosphino)butane (S,S)-CHIRAPHOS | 64896-28-2 | 250mg | $110 | 2024-03-01 | Buy |
(2S,3S)-(-)-BIS(DIPHENYLPHOSPHINO)BUTANE Chemical Properties,Uses,Production
Uses
(2S,3S)-(-)-Bis(diphenylphosphino)butane, also known as (S,S)-Chiraphos, is a chiral ligand used in the preparation of bimetallic chromium and diphosphine-ruthenium (II) diallyl complexes.
Reaction
Useful as a ligand in the Ni-catalyzed asymmetric additions to allylic ketals.
Chemical Properties
white granular powder
Uses
Ligand for palladium-catalyzed carbon-carbon bond formation.
Uses
Ligand for Pd-catalyzed carbon-carbon bond formation.
Uses
(2S,3S)-(-)-Bis(diphenylphosphino)butane, also known as (S,S)-Chiraphos, is a chiral ligand used in the preparation of bimetallic chromium and diphosphine-ruthenium (II) diallyl complexes.
(2S,3S)-(-)-BIS(DIPHENYLPHOSPHINO)BUTANE Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shanghai Daken Advanced Materials Co.,Ltd | +86-2158073036 | info@dakenam.com | China | 13815 | 58 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29821 | 58 |
| Richest Group Ltd | 18017061086 | oled@richest-group.com | CHINA | 5600 | 58 |
| XINXIANG RUNYU MATERIAL CO., LTD. | +86-13592593621; +8613592593621 | sales@runvmat.com | China | 453 | 58 |
| Henan Alfa Chemical Co., Ltd | +8615838112936 | sale03@alfachem.cn | China | 9659 | 58 |
| changzhou huayang technology co., ltd | +8615250961469 | 2571773637@qq.com | China | 9653 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418684 +8618949823763 | sales@tnjchem.com | China | 25356 | 58 |
| HANGZHOU LEAP CHEM CO., LTD. | +86-571-87711850 | market18@leapchem.com | China | 24597 | 58 |
| Hangzhou MolCore BioPharmatech Co.,Ltd. | +86-057181025280; +8617767106207 | sales@molcore.com | China | 49734 | 58 |
| Henan Allgreen Chemical Co.,LTD | +86-37155567971 +86-13633837469 | info@allgreenchem.com | China | 5998 | 58 |
View Lastest Price from (2S,3S)-(-)-BIS(DIPHENYLPHOSPHINO)BUTANE manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2026-04-02 | ((2S,3S)-butane-2,3-diyl)bis(diphenylphosphane)
64896-28-2
|
US $0.00-0.00 / KG | 1KG | 99% | 250KG | XINXIANG RUNYU MATERIAL CO., LTD. | |
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2019-08-08 | (2S,3S)-(-)-BIS(DIPHENYLPHOSPHINO)BUTANE
64896-28-2
|
US $1.00-2.00 / KG | 1KG | 98% | 1kg,10kg,100kg | Career Henan Chemical Co |
-

- ((2S,3S)-butane-2,3-diyl)bis(diphenylphosphane)
64896-28-2
- US $0.00-0.00 / KG
- 99%
- XINXIANG RUNYU MATERIAL CO., LTD.
-

- (2S,3S)-(-)-BIS(DIPHENYLPHOSPHINO)BUTANE
64896-28-2
- US $1.00-2.00 / KG
- 98%
- Career Henan Chemical Co
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