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(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamino-cobalt(II)

(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamino-cobalt(II) structure

CAS No.: 176763-62-5

Chemical Name:: (R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamino-cobalt(II)

Synonyms: (R,R)-Salen-Co;R-SALEN-CO;(R,R)-Co(salen);idene)-1,2-cycL;(R，R)-(-)-N，N’ohexanediaminocobaL;-Didemethyl Atracurium Oxalate;(R,R)-Jacobsen cobalt (II) catalyst;(R,R)-(-)-N,N'-Bis(3,5-di-tert-butyL;bis(3,5-di-t-butylsalicylidene)cobalt (II)

CBNumber:: CB7424685

Molecular Formula:: C36H52CoN2O2

Molecular Weight:: 603.74

MDL Number:: MFCD01631277

MOL File:: 176763-62-5.mol

MSDS File:: SDS

Last updated:2026-09-12 18:54:56

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(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamino-cobalt(II) Properties

Melting point	>350 °C(lit.)
storage temp.	Keep in dark place,Inert atmosphere,Room temperature
form	Powder
color	Orange to red to brown
InChIKey	ZFWPDJKMASHRPT-DKZUAMKGNA-L
SMILES	C12O[Co]OC3=C(C=N[C@@H]4CCCC[C@H]4N=CC=1C=C(C(C)(C)C)C=C2C(C)(C)C)C=C(C(C)(C)C)C=C3C(C)(C)C \|t:6,15,&1:8,13,r\|
UNSPSC Code	12352001
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07,GHS08
Signal word	Danger
Hazard statements	H317-H372-H412
Precautionary statements	P260-P264-P273-P280-P302+P352-P314
PPE	dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes	Xn
Risk Statements	20/21/22-36/37/38
Safety Statements	36/37/39-26
WGK Germany	3
HS Code	29349990
Storage Class	6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects
Hazard Classifications	Aquatic Chronic 3 Skin Sens. 1A STOT RE 1

(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamino-cobalt(II) price More Price(46)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	474592	(R,R)-(?)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)	176763-62-5	1g	$60.4	2026-04-30	Buy
Sigma-Aldrich	474592	(R,R)-(?)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)	176763-62-5	5g	$162	2026-04-30	Buy
TCI Chemical	B5732	(R,R)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)	176763-62-5	5G	$49	2026-04-30	Buy
TCI Chemical	B5732	(R,R)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)	176763-62-5	25G	$184	2026-04-30	Buy
Strem Chemicals	27-0525	(1R,2R)-(-)-1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)cobalt(II)	176763-62-5	1g	$54	2026-04-30	Buy

Product number	Packaging	Price	Buy
474592	1g	$60.4	Buy
474592	5g	$162	Buy
B5732	5G	$49	Buy
B5732	25G	$184	Buy
27-0525	1g	$54	Buy

(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamino-cobalt(II) Chemical Properties, Uses, Production

Reaction

Catalyst used in the kinetic resolution of racemic, terminal epoxides yielding a chiral diol and the unreacted enantiomer of the epoxide.
Precursor to a Co(III) catalyst for the kinetic resolution of terminal epoxides with alcohols.
Desymmetrization of meso-epoxides with carboxylic acids and fluoride.
Catalyst for asymmetric cyclopropanation of styrene.
Catalyst for copolymerization of CO2 and epoxides.
Enantioselective intramolecular openings of oxetanes.

Chemical Properties

Orange to red-brown powder

Uses

Catalyst for the hydrolytic kinetic resolution of terminal epoxides and the enantioselective ring opening of meso epoxides.

(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamino-cobalt(II) synthesis

Synthesis of (R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamino-cobalt(II) from Cobalt(II) acetate tetrahydrate and Phenol, 2,2'-[(1R,2R)-1,2-cyclohexanediylbis(nitrilomethylidyne)]bis[4,6-bis(1,1-dimethylethyl)-

(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamino-cobalt(II) Preparation Products And Raw materials

Raw materials

Phenol, 2,2'-[(1R,2R)-1,2-cyclohexanediylbis(nitrilomethylidyne)]bis[4,6-bis(1,1-dimethylethyl)- Cobalt(II) acetate tetrahydrate Dimethyl fumarate

Preparation Products

(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamino-cobalt(II) Suppliers

Global Suppliers ( 163)

Supplier	Tel	Email	Country	ProdList	Advantage
Shenzhen Feiming Science and Technology Co.,Ltd.	0755-85232577	sale@fmect.com	China	96	62
Zhende Chemical Technology (Shanghai) Co., Ltd.	15601952568	sales4@myuchem.com	China	2999	58
SHAOXING ZHIJUN PHARMACEUTICAL TECHNOLOGY CO.,LTD	0575-82126188 15395856318	service@zejunpharma.com	China	487	58
Shanghai UCHEM Inc.	18939844854	sales6@myuchem.com	China	4982	58
Chengdu Forest Science and Technology Development Co., Ltd.	18030648795 18030648795	sales@cdforestchem.com	China	1997	58
J & K SCIENTIFIC LTD.	18210857532 18210857532	jkinfo@jkchemical.com	China	96815	76
Beijing HwrkChemical Technology Co., Ltd	89508211 18501085097	sales.bj@hwrkchemical.com	China	9407	55
Energy Chemical	400-0056266	sales8178@energy-chemical.com	China	44850	61
Beijing Ouhe Technology Co., Ltd	13552068683 13522913783	2355560935@qq.com	China	11777	60
Shanghai Hanhong Scientific Co.,Ltd.	021-54306202 13764082696	info@hanhongsci.com	China	42917	64

Supplier	Advantage
Shenzhen Feiming Science and Technology Co.,Ltd.	62
Zhende Chemical Technology (Shanghai) Co., Ltd.	58
SHAOXING ZHIJUN PHARMACEUTICAL TECHNOLOGY CO.,LTD	58
Shanghai UCHEM Inc.	58
Chengdu Forest Science and Technology Development Co., Ltd.	58
J & K SCIENTIFIC LTD.	76
Beijing HwrkChemical Technology Co., Ltd	55
Energy Chemical	61
Beijing Ouhe Technology Co., Ltd	60
Shanghai Hanhong Scientific Co.,Ltd.	64

View Latest Price from (R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamino-cobalt(II) manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2026-09-15	(1R,2R)-(-)-N,N-Bis(3,5-di-t-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II) 176763-62-5	$170.00-500.00	1g	0.98	10kg	Shanghai UCHEM Inc.
2026-08-07	(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II) 176763-62-5		1kG	99%	1000KG	Shaanxi Dideu Medichem Co. Ltd
2026-06-30	(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II) 176763-62-5		1KG	98.0%	10000KGS	Shaanxi Dideu New Materials Co. Ltd

(1R,2R)-(-)-N,N-Bis(3,5-di-t-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)
176763-62-5
$170.00-500.00
0.98
Shanghai UCHEM Inc.

(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II)
176763-62-5
99%
Shaanxi Dideu Medichem Co. Ltd

(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II)
176763-62-5
98.0%
Shaanxi Dideu New Materials Co. Ltd

(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamino-cobalt(II) Spectrum

(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II)(176763-62-5)IR

176763-62-5 ((R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamino-cobalt(II)) Related Search:

1,4-Bis(diphenylphosphino)butane-palladium(II) chloride SPhos Pd G2 RuPhos Pd G2 Dichloro(N,N,N',N'-tetramethylethylenediamine)palladium(II) Bis(3 5 3' 5'-dimethoxydibenzylideneace&

Allylchloro[1,3-bis(2,6-di-I-propylphenyl)imidazol-2-ylidene]palladium (II) (R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine Cobalt (1R,2R)-(-)-1,2-Diaminocyclohexane SALCOMINE

N,N'-Bis(salicylidene)-1,2-propanediamine N,N'-Bis(salicylidene)ethylenediamine (S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamino-cobalt(II) (R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamino-cobalt(II) Dibenzylidene ethylenediamine

N,N'-Bis(salicylidene)-1,6-hexanediamine N-benzylidenecyclohexylamine Cis/trans-disalycylidene-1,2-cyclohexylidenediamine

1of4

(1R,2R)-(-)-N,N'-BIS(3,5-DI-T-BUTYLSALICYDENE)-1,2-CYCLOHEXANEDIAMINOCOBALT(II) (1R,2R)-(-)-1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)COBALT(II) (1R,2R)-(-)-N,N-Bis(3,5-di-t-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II) CyclohexanediaminoNNbisditbutylsalicylidene (R,R)-(-)-N,N'-BIS(3,5-DI-T-BUTYLSALICYL ID -ENE)-1,2-CYCLOHEXANEDIAMINOCOBALT(II (1R,2R)-(-)-1,2-Cyclohexanediamino-N,N'-bis(3,5-di-tert-butylsalicylidene)cobalt(II) (1r,2r)-(-)-1,2-cyclohexanediamino-n,n'-bis(3,5- di-t-butylsalicylidene)cobalt (R,R)-(-)-N,N'-Bis(3,5-di-t-butylsalicylidene)-1,2-cyclohexanediaminocobalt(ii),98% (R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II),98% (1R,2R)-(-)-1,2-Cyclohexanediamino-N,N'-bis(3,5- (1R,2R)-(-)-1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene) cobalt(Ⅱ) (R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(Ⅱ) Cobalt,[[2,2'-[(1R,2R)-1,2-cyclohexanediylbis[(nitrilo-kN)Methylidyne]]bis[4,6-bis(1,1-diMethylethyl)phenolato-kO]](2-)]-, (SP-4-2)- (1R,2R)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2- cyclohexanediaminocobalt(II)
(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocob alt(II) (R，R)-(-)-N，N&rsquo (1R,2R)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2- cyclohexanediaminocobalt(II),99%e.e. -Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III) Chloride -Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine -Bis(3,5-dibutylsalicylidene)-1,2-cyclohexanediaminoaluminum(III) Chloride -Didemethyl Atracurium Oxalate (R,R)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-diaminocyclohexane cobalt(II) (R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II), 98%, for synthesis ohexanediaminocobaL idene)-1,2-cycL (R,R)-(-)-N,N'-Bis(3,5-di-tert-butyL (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO- (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II) ISO 9001：2015 REACH (1R,2R)-(-)-1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsa... bis(3,5-di-t-butylsalicylidene)cobalt (II) TIANFU CHEM (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II) 2,4-ditert-butyl-6-[[[(1R,2S)-2-[(3,5-ditert-butyl-6-oxocyclohexa-2,4-dien-1-ylidene)methylamino]cyclohexyl]amino]methylidene]cyclohexa-2,4-dien-1-one 2,4-ditert-butyl-6-[[(1R,2R)-2-[(3,5-ditert-butyl-2-oxido-phenyl)methyleneamino]cyclohexyl]iminomethyl]phenolate (R,R)-Jacobsen cobalt (II) catalyst (1R,2R)-(-)-1,2-Cyclohexanediamino-N,N'-bis-(3,5-di-tert-butylsalicylidene)cobalt (II) (1R,2R)-(-)-1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)cobalt (II) (1R,2R)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II) (R,R)-(?)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II) cobaltous,2,4-ditert-butyl-6-[[(1R,2R)-2-[(3,5-ditert-butyl-2-oxido-phenyl)methyleneamino]cyclohexyl]iminomethyl]phenolate (R,R)-Salen-Co (R,R)-Co(salen) R-SALEN-CO (R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamino-cobalt(II) 176763-62-5 176763-62-4 C36H54CoN2O2 CH33C2C6H22OCHN2C6H10Co C36H52CoN2O2 Kinetic Resolution Asymmetric Synthesis Chiral Catalysts, Ligands, and Reagents Jacobsen Metal Co fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis Kinetic ResolutionChiral Catalysts, Ligands, and Reagents Asymmetric Synthesis Chiral Catalysts, Ligands, and Reagents Privileged Ligands and Complexes