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1,6-Dibromohexane

1,6-Dibromohexane Structure
1,6-Dibromohexane structure
CAS No.
629-03-8
Chemical Name:
1,6-Dibromohexane
Synonyms
1,6-Dibromhexan;1,6-Dibromohexan;6-Dibromohexane;1,6-dibromo-hexan;1,6-Dibromotexane;1,6-DIBROMOHEXANE;Dibromo-1,6 hexane;Hexane,1,6-dibromo-;1,6-DIBROMO-N-HEXANE;1,6-Dibromohexane,98%
CBNumber:
CB7435155
Molecular Formula:
C6H12Br2
Molecular Weight:
243.97
MDL Number:
MFCD00000272
MOL File:
629-03-8.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-28 03:33:08
Request For Quotation

1,6-Dibromohexane Properties

Melting point -2-2.5 °C (lit.)
Boiling point 243 °C (lit.)
Density 1.586 g/mL at 25 °C (lit.)
vapor pressure <1 hPa (20 °C)
refractive index n20/D 1.507(lit.)
Flash point 110 °C
storage temp. Store below +30°C.
solubility soluble in Chloroform, Ethyl Acetate
form Liquid
color colorless to brownish-yellow
Water Solubility insoluble
BRN 1236322
Dielectric constant 8.8900000000000006
Stability Stable. Incompatible with strong oxidizing agents.
InChI 1S/C6H12Br2/c7-5-3-1-2-4-6-8/h1-6H2
InChIKey SGRHVVLXEBNBDV-UHFFFAOYSA-N
SMILES BrCCCCCCBr
CAS DataBase Reference 629-03-8(CAS DataBase Reference)
FDA UNII 7L71Q7Y230
NIST Chemistry Reference Hexane, 1,6-dibromo-(629-03-8)
EPA Substance Registry System Hexane, 1,6-dibromo- (629-03-8)
UNSPSC Code 12352101
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)Environment (GHS09)
GHS07,GHS09
Signal word  Warning
Hazard statements  H302-H317-H411
Precautionary statements  P261-P264-P273-P280-P301+P312-P302+P352
PPE Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes  T,N,C
Risk Statements  25-51/53-43
Safety Statements  36-45-61-36/37
RIDADR  UN 2810 6.1/PG 3
WGK Germany  3
RTECS  MO1515000
TSCA  TSCA listed
HazardClass  9
PackingGroup  III
HS Code  29033036
Storage Class 10 - Combustible liquids
Hazard Classifications Acute Tox. 4 Oral
Aquatic Chronic 2
Skin Sens. 1
Toxicity LD50 orally in Rabbit: 1800 mg/kg LD50 dermal Rabbit > 2000 mg/kg
REACH Registrations Active
NFPA 704
0
2 0

1,6-Dibromohexane price More Price(78)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich D41007 1,6-Dibromohexane 96% 629-03-8 25g $21.3 2026-04-30 Buy
Sigma-Aldrich D41007 1,6-Dibromohexane 96% 629-03-8 100g $43.2 2026-04-30 Buy
Sigma-Aldrich 8.02921 1,6-Dibromohexane for synthesis 629-03-8 250ml $131 2026-04-30 Buy
TCI Chemical D0185 1,6-Dibromohexane >97.0%(GC) 629-03-8 25g $21 2026-04-30 Buy
TCI Chemical D0185 1,6-Dibromohexane >97.0%(GC) 629-03-8 100g $25 2026-04-30 Buy
Product number Packaging Price Buy
D41007 25g $21.3 Buy
D41007 100g $43.2 Buy
8.02921 250ml $131 Buy
D0185 25g $21 Buy
D0185 100g $25 Buy

1,6-Dibromohexane Chemical Properties, Uses, Production

Chemical Properties

colourless or pale yellow liquid. soluble in ethanol, ether, benzene and chloroform, insoluble in water. It is used in the synthesis of the hypotensive drug hexamethonium bromide.

Uses

1,6-Dibromohexane is used as a reagent in the synthesis of novel benzo[b]xanthone derivatives which have a potential antitumor activity. It is also used as a cross-linker for the cross-linking of glycuronans.

Uses

1,6-Dibromohexane is generally used to introduce C6 spacer in the molecular architecture. Some of the examples are:
Synthesis of solvent processable and conductive polyfluorene ionomers for alkaline fuel cell applications.
Synthesis of cross-linkable regioregular poly(3-(5-hexenyl)thiophene) (P3HNT) for stabilizing the film morphology in polymer photovoltaic cells.
Synthesis of pyrrolo-tetrathiafulvalene molecular bridge (6PTTF6) to study redox switching behavior of single molecules.
Synthesis of water-soluble thermoresponsive polylactides.

Preparation

1,6-Dibromohexane is synthesized from hexanediol by bromination.

Synthesis

1,6-Hexanediol

629-11-8

1,6-Dibromohexane

629-03-8

The general procedure for the synthesis of 1,6-dibromohexane from 1,6-hexanediol was as follows: N-bromosuccinimide (NBS, 534 mg, 3 mmol) was dissolved in dichloromethane (CH2Cl2, 10 mL) in a 50 mL round-bottomed flask. Triphenylphosphine (Ph3P, 786 mg, 3 mmol) and 1,6-hexanediol (1 mmol) were added dropwise to the NBS solution at -78 °C. The reaction mixture was stirred at room temperature away from light for 12 h, during which the progress of the reaction was monitored by thin layer chromatography (TLC, eluent: petroleum ether-ethyl acetate, 20:1). Upon completion of the reaction, the mixture was concentrated under vacuum and purified by fast chromatography on silica gel column (eluent: petroleum ether-ethyl acetate, 30:1) to afford the target product 1,6-dibromohexane.

References

[1] Synthesis (Germany), 2015, vol. 47, # 8, p. 1154 - 1162
[2] Journal of the American Chemical Society, 1936, vol. 58, p. 488
[3] Archiv der Pharmazie (Weinheim, Germany), 1935, p. 323
[4] Zhurnal Obshchei Khimii, 1935, vol. 5, p. 1508
[5] Journal of the Chemical Society, 1948, p. 46

1,6-Dibromohexane synthesis

629-11-8
629-03-8
Synthesis of 1,6-Dibromohexane from 1,6-Hexanediol

1,6-Dibromohexane Preparation Products And Raw materials

Raw materials

2-Methyl-2,4-pentanediol 1,6-Hexanediol Triphosgene acrylic acid methyl ester 6-Azido-hexylamine
Triphenylphosphine N-Bromosuccinimide Dichloromethane

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Preparation Products

HEXAMETHONIUM BROMIDE 1,8-Octanedinitrile 6-bromohexan-1-amine 7-Bromoheptanenitrile 16-Hydroxyhexadecanoic acid
1-Hexene 6-(Boc-amino)-hexyl bromide 4,4’-(1,6-Hexanediyl)dioxydibenzaldehyde Vilanterol Impurity 14 2-(6-Bromohexyl)-5-nitroisoindoline-1,3-dione
1H-Isoindole-1,3(2H)-dione, 2-(6-mercaptohexyl)- Benzene, 1-[(6-bromohexyl)oxy]-4-nitro-

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1,6-Dibromohexane Suppliers

Global Suppliers ( 597)
Supplier Tel Email Country ProdList Advantage
Shanghai Aladdin Bio-Chem Technology Co.,LTD 400-6206333 13167063860 anhua.mao@aladdin-e.com China 29985 65
Yancheng Longshen Chemical Co.,Ltd. 0515-88718898 18352070236 2355801706@qq.com China 100 60
CHANGZHOU XINYOU GOODS AND MAT 0519-88861658 15351933796 601763459@qq.com China 37 58
Shouguang Tongshun Chemical Co., Ltd 13792625218 2103858215@qq.com China 64 58
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
future industrial shanghai co., ltd 400-0066400 13621662912 sales@jonln.com China 1989 65
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24512 81
ShangHai DEMO Chemical Co.,Ltd 400-021-7337 2355568890 sales@demochem.com China 2569 57
Supplier Advantage
Shanghai Aladdin Bio-Chem Technology Co.,LTD 65
Yancheng Longshen Chemical Co.,Ltd. 60
CHANGZHOU XINYOU GOODS AND MAT 58
Shouguang Tongshun Chemical Co., Ltd 58
J & K SCIENTIFIC LTD. 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 62
future industrial shanghai co., ltd 65
Alfa Aesar 84
TCI (Shanghai) Development Co., Ltd. 81
ShangHai DEMO Chemical Co.,Ltd 57

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View Latest Price from 1,6-Dibromohexane manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
1,6-Dibromohexane pictures 2026-09-16 1,6-Dibromohexane
629-03-8
 1KG 98%min 30tons/month WUHAN FORTUNA CHEMICAL CO., LTD
1,6-Dibromohexane pictures 2026-09-15 1,6-Dibromohexane
629-03-8
 0.99 RongNa Biotechnology Co.,Ltd
1,6-Dibromohexane pictures 2026-09-14 1,6-Dibromohexane
629-03-8
 1KG ≥99% 50 Tons/Month Yancheng Longshen Chemical Co.,Ltd.

1,6-Dibromohexane Spectrum

1,6-Dibromohexane(629-03-8)MS1,6-Dibromohexane(629-03-8)1HNMR1,6-Dibromohexane(629-03-8)13CNMR1,6-Dibromohexane(629-03-8)IR11,6-Dibromohexane(629-03-8)IR21,6-Dibromohexane(629-03-8)Raman

629-03-8 (1,6-Dibromohexane ) Related Search:

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1,6-Dibromhexan 1,6-dibromo-hexan 1,6-Dibromohexane,98% 1,6-DibroMohexane, 98% 100ML 1,6-DibroMohexane, 98% 500ML Hexamethylene Bromide Hexamethylene Dibromide 1,6-DIBROMOHEXANE FOR SYNTHESIS alpha,omega-dibromohexane Dibromo-1,6 hexane ColesevelaM IMpurity (1,6-DibroMohexane) Hexamethylene Bromide 〔1,6-Dibromohexane〕 6-Dibromohexane 1,6-Dibromotexane 1,6-DIBROMOHEXANE, 98%1,6-DIBROMOHEXANE, 98%1,6-DIBROMOHEXANE, 98%1,6-DIBROMOHEXANE, 98% Hexane,1,6-dibromo- 1,6-Dibromohexane,97% HEXAMETHYLENE BROMIDE HEXAMETHYLENE DIBROMIDE 1,6-DIBROMOHEXANE 1,6-DIBROMO-N-HEXANE 1,6-DIBROMOHEXANESALMETEROL Hexamethylendibromide 1,6-Dibromohexane > hexamethylene dibromide，98% 1,6-Dibromohexane, 96% 1,6-Dibromohexan 629-03-8 1798-04-1 629038 C6H12Br2 BrCH26Br Alkyl Building Blocks Organic Building Blocks Halogenated Hydrocarbons Monofunctional & 伪,蠅-Bifunctional Alkanes 伪,蠅-Dibromoalkanes 伪,蠅-Bifunctional Alkanes Industrial/Fine Chemicals DIBROMOALKANE Bromine Compounds alpha,omega-Bifunctional Alkanes alpha,omega-Dibromoalkanes Monofunctional & alpha,omega-Bifunctional Alkanes bc0001