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2-Ethylhexyl nitrate

CAS No.
27247-96-7
Chemical Name:
2-Ethylhexyl nitrate
Synonyms
2-EHN;nitronal;2-ethylhexylester;2-Ethylhexylni;ethylhexylnitrate;2-Ethylhexylnitrat;2-ETHYLHEXYL NITRATE;Cetane number improver;2-ETHYL-HEXYL-1-NITRATE;Nitricacid,2-ethylhexylester
CBNumber:
CB7479115
Molecular Formula:
C8H17NO3
Molecular Weight:
175.23
MDL Number:
MFCD00011582
MOL File:
27247-96-7.mol
MSDS File:
SDS
Last updated:2026-06-05 18:38:38

2-Ethylhexyl nitrate Properties

Boiling point 306.53°C (rough estimate)
Density 0.963 g/mL at 25 °C(lit.)
vapor pressure 27Pa at 20℃
refractive index n20/D 1.432(lit.)
Flash point 168 °F
Odor Fruity, pungent, ester, characteristic
Appearance olourless to pale yellow liquid
Viscosity 1.8 cSt @ 20℃
Water Solubility 12.5mg/L at 20℃
Decomposition >100℃
Stability Stability Heating may cause an explosion. Contact with combustible material may cause fire or explosion.
InChI InChI=1S/C8H17NO3/c1-3-5-6-8(4-2)7-12-9(10)11/h8H,3-7H2,1-2H3
InChIKey NKRVGWFEFKCZAP-UHFFFAOYSA-N
SMILES [N+]([O-])(=O)OCC(CC)CCCC
LogP 5.24 at 40℃
CAS DataBase Reference 27247-96-7(CAS DataBase Reference)
FDA UNII R11MG529IT
EPA Substance Registry System 2-Ethylhexyl nitrate (27247-96-7)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)Environment (GHS09)
GHS07,GHS09
Signal word  Warning
Hazard statements  H302+H312+H332-H411
Precautionary statements  P273-P280-P301+P312+P330-P302+P352+P312-P304+P340+P312
PPE Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes  O,Xn,N
Risk Statements  5-8-20/21/22-36/37/38-66-51/53-44
Safety Statements  15-26-27-36/37/39-61-60-24/25
OEL 0.25% v/v in air
RIDADR  UN 3139 5.1/PG 2
WGK Germany  2
RTECS  QU7925000
Autoignition Temperature 130℃ - (decomposes)
TSCA  TSCA listed
HazardClass  9
Storage Class 10 - Combustible liquids
Hazard Classifications Acute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Aquatic Chronic 2
REACH Registrations Active
Limited Quantities 5.0 L (1.3 gallons) (liquid) or 5.0 kg (11 lbs) (solid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)

2-Ethylhexyl nitrate price More Price(4)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 293784 2-Ethylhexyl nitrate 97% 27247-96-7 1l $95.7 2026-04-30 Buy
Sigma-Aldrich 293784 2-Ethylhexyl nitrate 97% 27247-96-7 2.5l $198 2026-04-30 Buy
American Custom Chemicals Corporation CHM0115280 2-ETHYLHEXYL NITRATE 95.00% 27247-96-7 1L $6414.52 2021-12-16 Buy
American Custom Chemicals Corporation CHM0115280 2-ETHYLHEXYL NITRATE 95.00% 27247-96-7 2.5L $6476.66 2021-12-16 Buy
Product number Packaging Price Buy
293784 1l $95.7 Buy
293784 2.5l $198 Buy
CHM0115280 1L $6414.52 Buy
CHM0115280 2.5L $6476.66 Buy

2-Ethylhexyl nitrate Chemical Properties, Uses, Production

Chemical Properties

solid

Uses

2-Ethylhexyl nitrate (2-EHN) is a major fuel additive, has been used to increase the cetane number of diesel.

General Description

Biodegradation of 2-ethylhexyl nitrate (2-EHN) by Mycobacterium austroafricanum IFP 2173 has been studied. Biodegradation of 2-EHN was studied in biphasic liquid cultures using an inert non-aqueous phase liquid such as 2,2,4,4,6,8,8-heptamethylnonane as solvent.

Flammability and Explosibility

Not classified

Synthesis

A production method of 2-Ethylhexyl nitrate, the steps are: (1) 1500L reactor add 100 kg of 98% nitric acid, water cooling, vigorous stirring under the addition of 424 kg of 87% sulfuric acid, made of sulfuric acid and nitric acid acid mixture; (2) 156 kg of isooctyl nitrate to 195 kg of iso-octanol and mix it well; (3) (2) isooctyl nitrate and iso-octanol mixture prepared by adding to the (1) mixed acid. (3) The mixture of isooctyl nitrate and isooctanol prepared in (2) was added to the mixed acid prepared in (1), the process of adding speed control to keep the reaction temperature between 10-30 , add the stirring reaction for 45 minutes, static liquid separation, organic phase alkali washing, water washing, to obtain the product of isooctyl nitrate purity of 99.1%, the yield of 98.2%.

104-76-7
27247-96-7
Synthesis of 2-Ethylhexyl nitrate from 2-Ethylhexanol

2-Ethylhexyl nitrate Preparation Products And Raw materials

Global Suppliers ( 240)
Supplier Tel Email Country ProdList Advantage
Jinan Chengyuan Chemical Co., LTD 0531-88274992; 15064038081 1278740859@qq.com China 42 58
Shandong fengpan New Material Co., Ltd 18560028598 2584792069@qq.com China 77 58
Jinan Hongtai Weiye Trading Co., Ltd 15954911888 2660943764@qq.com China 30 58
Jinan Hexin Chemical Co., Ltd 18764033565 18764033565; JINANHEXIN888@QQ.COM China 102 58
Hubei Guangao Biotechnology Co., Ltd 027-02702759223056 18162699093 1208480011@qq.com China 9500 58
Tianjin Zhongxin Chemtech Co., Ltd. 022-66880623 sales@tjzxchem.com China 612 60
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Shanghai Hanhong Scientific Co.,Ltd. 021-54306202 13764082696 info@hanhongsci.com China 42917 64
Shandong Xiya Chemical Co., Ltd 13355009207 13355009207 3007715519@qq.com China 18722 57
Syntechem Co.,Ltd info@syntechem.com China 12973 57

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Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-Ethylhexyl nitrate pictures 2026-09-25 2-Ethylhexyl nitrate
27247-96-7
0.99 RongNa Biotechnology Co.,Ltd
2-Ethylhexyl nitrate   pictures 2026-08-07 2-Ethylhexyl nitrate
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$1.00 1KG 99% 200000KG Shaanxi Dideu Medichem Co. Ltd
2-Ethylhexyl nitrate pictures 2026-06-30 2-Ethylhexyl nitrate
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1KG 99.0% 10000KGS Shaanxi Dideu New Materials Co. Ltd
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