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Diethyl chloromalonate

CAS No.
14064-10-9
Chemical Name:
Diethyl chloromalonate
Synonyms
Nsc 227952;Einecs 237-913-0;RARECHEM AL BI 0643;Diethyl chloromalote;Ethyl chloromalonate;Bosentan Impurity 16;Chloro di-Ethyl ester;DIETHYL CHLOROMALONATE;α-Chlorodiethylmalonate;Ethylmonochloromalonate
CBNumber:
CB7686706
Molecular Formula:
C7H11ClO4
Molecular Weight:
194.61
MDL Number:
MFCD00009140
MOL File:
14064-10-9.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-28 02:30:59
Product description Number Pack Size Price
Diethyl chloromalonate 95% 437786 5ml $113
Diethyl chloromalonate 95% 437786 25ml $275
Diethyl 2-Chloromalonate min. 95.0 % D3395 5G $46
Diethyl 2-Chloromalonate min. 95.0 % D3395 25G $137
Diethyl Chloromalonate TRC-D444060-5G 5g $179
More product size

Diethyl chloromalonate Properties

Boiling point 279.11°C (rough estimate)
Density 1.204 g/mL at 25 °C (lit.)
refractive index n20/D 1.432(lit.)
Flash point >230 °F
storage temp. Inert atmosphere,2-8°C
solubility Chloroform (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly)
form Liquid
pka 9.07±0.46(Predicted)
color Clear colorless
Specific Gravity 1.204
InChI InChI=1S/C7H11ClO4/c1-3-11-6(9)5(8)7(10)12-4-2/h5H,3-4H2,1-2H3
InChIKey WLWCQKMQYZFTDR-UHFFFAOYSA-N
SMILES C(OCC)(=O)C(Cl)C(OCC)=O
LogP 2.23 at 40℃ and pH4-9
CAS DataBase Reference 14064-10-9(CAS DataBase Reference)
FDA UNII 8Y5J45M964
EPA Substance Registry System Propanedioic acid, 2-chloro-, 1,3-diethyl ester (14064-10-9)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Corrosion (GHS05)Exclamation Mark (GHS07)Environment (GHS09)
GHS05,GHS07,GHS09
Signal word  Danger
Hazard statements  H314-H335-H400
Precautionary statements  P261-P271-P273-P280-P303+P361+P353-P305+P351+P338
target organs Respiratory system
PPE Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hazard Codes  C
Risk Statements  34-36/37
Safety Statements  26-27-28-36/37/39-45
RIDADR  UN 3265 8/PG 2
WGK Germany  3
TSCA  TSCA listed
HazardClass  8
PackingGroup  III
HS Code  29171990
Storage Class 8A - Combustible corrosive hazardous materials
Hazard Classifications Aquatic Acute 1
Eye Dam. 1
Skin Corr. 1B
STOT SE 3
REACH Registrations Inactive
Limited Quantities 1.0 L (0.3 gallons) (liquid) or 1 Kg (2.2 lbs) (solid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)

Diethyl chloromalonate price More Price(48)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 437786 Diethyl chloromalonate 95% 14064-10-9 5ml $113 2026-04-30 Buy
Sigma-Aldrich 437786 Diethyl chloromalonate 95% 14064-10-9 25ml $275 2026-04-30 Buy
TCI Chemical D3395 Diethyl 2-Chloromalonate min. 95.0 % 14064-10-9 5G $46 2026-04-30 Buy
TCI Chemical D3395 Diethyl 2-Chloromalonate min. 95.0 % 14064-10-9 25G $137 2026-04-30 Buy
TRC TRC-D444060-5G Diethyl Chloromalonate 14064-10-9 5g $179 2026-06-03 Buy
Product number Packaging Price Buy
437786 5ml $113 Buy
437786 25ml $275 Buy
D3395 5G $46 Buy
D3395 25G $137 Buy
TRC-D444060-5G 5g $179 Buy

Diethyl chloromalonate Chemical Properties,Uses,Production

Chemical Properties

Clear Colourless Liquid

Uses

Diethyl chloromalonate is a compound used in the models of aquatic toxicity developed

Uses

A compound used in the models of aquatic toxicity developed (QSAR). Combinatorial QSAR modeling of chemical toxicants tested against Tetrahymena pyriformis.

General Description

Diethyl chloromalonate (Diethyl α-chloromalonate) is a 2-halo-1,3-dicarbonyl compound. It participates in K2CO3-catalyzed domino reactions (Michael alkylation, Mannich alkylation, and aldol alkylation) of salicylic aldehyde derivatives to afford functionalized 2,3-dihydrobenzofurans. It reacts with Cs2CO3 in the presence of elemental S8 or Sen to afford the corresponding diethyl thioxo- or selenoxomalonates, which can be trapped in situ with various 1,3-dienes.

685-87-0
14064-10-9
Synthesis of Diethyl chloromalonate from DIETHYL BROMOMALONATE
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View Lastest Price from Diethyl chloromalonate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
diethyl chloromalonate pictures 2026-05-28 diethyl chloromalonate
14064-10-9
$2.00-5.00 1KG 99% 10000kg Hebei Chuanghai Biotechnology Co,.LTD
Diethyl chloromalonate pictures 2026-03-20 Diethyl chloromalonate
14064-10-9
$10.00 1KG 99% 10 mt Hebei Chuanghai Biotechnology Co., Ltd
Diethyl chloromalonate pictures 2025-06-20 Diethyl chloromalonate
14064-10-9
1kg 99.00% 100tons Hebei Yanxi Chemical Co., Ltd.
2-Chloropropanedioic Acid 1,3-Diethyl Ester Chloropropanedioic Acid Ethyl Ester Diethyl MonochloroMalonate Chlorinated diethylMalonate DIETHYL CHLOROMALONATE FOR SYNTHESIS Diethyl chloroMalonate 95% 2-Chloro-malonic acid 1,3-diethyl ester Chloropropanedioicaciddiethylester chloro-propanedioicacidiethylester RARECHEM AL BI 0643 Diethyl chloromalote Propanedioic acid, chloro-, diethyl ester 2-chloro-malonic acid diethyl ester α-Chlorodiethylmalonate Ethyl chloromalonate Diethyl chloromalonate ,98% Diethyl chloromalonate ,90% 2-Chloromalonic acid diethyl Chloromalonic acid diethyl Einecs 237-913-0 Ethylmonochloromalonate Malonic acid, chloro-, diethyl ester Nsc 227952 Propanedioic acid, 2-chloro-, 1,3-diethyl ester Diethyl chloromalonate ,95% DIETHYL CHLOROMALONATE CHLOROMALONIC ACID DIETHYL ESTER Bosentan Impurity 16 1,3-diethyl 2-chloropropanedioate Diethyl 2-chloropropanedioate Chloro di-Ethyl ester 14064-10-9 C7H11ClO4 ClCHCO2C2H52 Carbonyl Compounds C6 to C7 Building Blocks Organic Building Blocks Esters ester series Aliphatics Pharmaceutical Intermediates TheMalonateRamificationProducts C6 to C7 Carbonyl Compounds Esters