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1,1'-Bis(di-tert-butylphosphino)ferrocene

1,1'-Bis(di-tert-butylphosphino)ferrocene Structure
1,1'-Bis(di-tert-butylphosphino)ferrocene structure
CAS No.
84680-95-5
Chemical Name:
1,1'-Bis(di-tert-butylphosphino)ferrocene
Synonyms
DTBPF;BIS[(DI-TERT-BUTYLPHOSPHINO)CYCLOPENTADIENYL]IRON;DBtPF;1,1'-Bis(di-t-butylphosphino)ferrocene;98% DtBPF;DTBPF ChemBeads;1,1'-Bis(di-t-butyL;1,1'-Bis(di-tert-butylphosphi;1,1'-Bis(di-tert-butylphosphin;1,1'-Bis(di-tert-butylphosphiNA)ferrocene
CBNumber:
CB3689138
Molecular Formula:
C26H44FeP210*
Molecular Weight:
474.42
MDL Number:
MFCD01630818
MOL File:
84680-95-5.mol
MSDS File:
SDS
Last updated:2026-05-28 04:27:11
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1,1'-Bis(di-tert-butylphosphino)ferrocene Properties

Melting point 181-182°C (dec.)
storage temp. Inert atmosphere,Room Temperature
form crystal
color orange to red
Water Solubility Insoluble in water.
InChI InChI=1S/2C13H22P.Fe/c2*1-12(2,3)14(13(4,5)6)11-9-7-8-10-11;/h2*7-10H,1-6H3;
InChIKey FPLSJBJGQLJLSV-UHFFFAOYSA-N
SMILES P(C(C)(C)C)(C(C)(C)C)[C]1[CH][CH][CH][CH]1.P(C(C)(C)C)(C(C)(C)C)[C]1[CH][CH][CH][CH]1.[Fe] |^1:9,10,11,12,13,23,24,25,26,27|
UNSPSC Code 12350000
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
target organs Respiratory system
PPE dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  22-24/25-36/37/39-26
WGK Germany  3
TSCA  No
HS Code  29319090
Storage Class 11 - Combustible Solids
Hazard Classifications Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
NFPA 704
1
2 0

1,1'-Bis(di-tert-butylphosphino)ferrocene price More Price(67)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 695149 1,1′-Bis(di-tert-butylphosphino)ferrocene 84680-95-5 1g $188 2026-04-30 Buy
Sigma-Aldrich 695149 1,1′-Bis(di-tert-butylphosphino)ferrocene 84680-95-5 250mg $93.8 2023-06-20 Buy
TCI Chemical B2711 1,1'-Bis(di-tert-butylphosphino)ferrocene >95.0%(T) 84680-95-5 1g $105 2026-04-30 Buy
TCI Chemical B2711 1,1'-Bis(di-tert-butylphosphino)ferrocene >95.0%(T) 84680-95-5 100mg $19 2026-04-30 Buy
Strem Chemicals 26-0150 1,1'-Bis(di-t-butylphosphino)ferrocene, min. 98% DTBPF min.98% 84680-95-5 500mg $52 2026-04-30 Buy
Product number Packaging Price Buy
695149 1g $188 Buy
695149 250mg $93.8 Buy
B2711 1g $105 Buy
B2711 100mg $19 Buy
26-0150 500mg $52 Buy

1,1'-Bis(di-tert-butylphosphino)ferrocene Chemical Properties, Uses, Production

Reaction

  1. Ligand for synthesis of polycyclic indoles via Pd-catalyzed intramolecular heteroannulation.
  2. Ligand for the palladium-catalyzed intramolecular arylation of aryl bromides under mild conditions.
  3. Ligand for cross-coupling reactions between bromoarenes and potassium allyltrifluoroborates promoted by a catalyst prepared from Pd(OAc)2 and DTBPF selectively providing γ-coupling products.
  4. Ligand for the copper-catalyzed system for the ß-boration of of a variety of α,ß-unsaturated amides.
  5. Ligand for the synthesis of Paucifloral F and related indanone analogues via palladium-catalyzed α-arylation.
  6. Ligand for the Pd-carbon monoxide complex catalyzed hydroxycarbonylation of aryl halides.
  7. Ligand for the palladium-catalyzed β-C-glycosylation by decarboxylative allylation to normal pyran systems,and cis-2,6-disubstituted tetrahydropyrans.
  8. Pd-catalyzed dearomative indole bisfunctionalization via a diastereoselective arylcyanation.
  9. Ligand for the copper- DTBPF catalyzed C–H activation and carboxylation of terminal alkynes.
Reactions of 84680-95-5_1
Reactions of 84680-95-5_2

Chemical Properties

1,1'-Bis(di-tert-butylphosphino)ferrocene has good stability and reactivity and can participate in a variety of organometallic catalytic reactions, such as diene complex formation, carbonyl insertion, addition, reduction and deoxygenation reactions.

Uses

1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE is an organophosphine compound and can be used as an organometallic ligand.

Uses

The rate of palladium-catalyzed amination of unactivated aryl chlorides is accelerated by sterically hindered chelating alkyl phosphines, ie, 1,1'-bis(di-tert-butylphosphino)ferrocene.

reaction suitability

reaction type: Cross Couplings
reagent type: ligand
reaction type: Arylations
reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reagent type: ligand
reaction type: Indole Forming Reactions
reagent type: ligand
reaction type: Suzuki-Miyaura Coupling

1,1'-Bis(di-tert-butylphosphino)ferrocene synthesis

65587-59-9
13716-10-4
84680-95-5
Synthesis of 1,1'-Bis(di-tert-butylphosphino)ferrocene from Ethanamine, N-[(3,5-dichlorophenyl)methylene]-2,2-diethoxy- and Di-tert-butylchlorophosphane

1,1'-Bis(di-tert-butylphosphino)ferrocene Preparation Products And Raw materials

Raw materials

Bromocyclohexane 2-Butanol Ferrocene Hexane Di-tert-butylchlorophosphane
N,N,N',N'-Tetramethylethylenediamine 2-Chloro-2-methylpropane 2,2'-Bipyridine Cinchonidine Phosphorus trichloride
Tetrahydrofuran Ethyl acetate Dichloromethane Magnesium n-Butyllithium

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Preparation Products

1,1'-Bis(di-tert-butylphosphino)ferrocene Suppliers

Global Suppliers ( 276)
Supplier Tel Email Country ProdList Advantage
Puyang Huicheng Electronic Material Co. Ltd. 0393-0393-8910800 15039333257 info@huichengchem.com China 588 64
Xinxiang Runyu Material Co., Ltd. 166-166-37336996 15690792173 chenxi.song@runvmat.com China 282 55
Henan Research New Material Co., Ltd. 86-18903931531 18903931628 sales036@researchvip.com China 180 58
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd. 0371-65511006 18625597674 info@kingorgchem.com;sales@kingorgchem.com China 806 55
BeiJing Greenchem Technology Co.,Ltd. 131-21959385 18804271668 chemrocking@bjgreenchem.com China 272 58
Sinocompound Catalysts Co., Ltd. 0512-67216630 67216634 sales@sinocompound.com China 252 64
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
Beijing Donghualituo Techonlogy Development Co.,Ltd. 010-88425576 sales@dhltchem.com China 793 59
INTATRADE GmbH +49 3493/605464 sales@intatrade.de Germany 3563 66
Supplier Advantage
Puyang Huicheng Electronic Material Co. Ltd. 64
Xinxiang Runyu Material Co., Ltd. 55
Henan Research New Material Co., Ltd. 58
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd. 55
BeiJing Greenchem Technology Co.,Ltd. 58
Sinocompound Catalysts Co., Ltd. 64
J & K SCIENTIFIC LTD. 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 62
Beijing Donghualituo Techonlogy Development Co.,Ltd. 59
INTATRADE GmbH 66

Related articles

Related Questions

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Q:What is the use of 1,1'-Bis(di-tert-butylphosphino)ferrocene?Annie - Oct 16,2025
A: 1,1'-Bis(di-tert-butylphosphino)ferrocene is an orange to red crystals, it is a useful reagents, catalysts, and precursor materials with applications in thin film deposition, industrial chemistry, pharmaceuticals, LED manufacturing, and others.

View Latest Price from 1,1'-Bis(di-tert-butylphosphino)ferrocene manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
1,1'-Bis(di-tert-butylphosphino)ferrocene pictures 2026-08-07 1,1'-Bis(di-tert-butylphosphino)ferrocene
84680-95-5
 $1.00 1KG 99% 20 Tons Shaanxi Dideu Medichem Co. Ltd
1,1'-Bis(di-tert-butylphosphino)ferrocene pictures 2026-06-30 1,1'-Bis(di-tert-butylphosphino)ferrocene
84680-95-5
 1kg 99% 10000KGS Shaanxi Dideu New Materials Co. Ltd
1,1'-Bis(di-tert-butylphosphino)ferrocene pictures 2026-06-04 1,1'-Bis(di-tert-butylphosphino)ferrocene
84680-95-5
 500g 98％ 10 Henan Research New Materials Co., Ltd.

1,1'-Bis(di-tert-butylphosphino)ferrocene Spectrum

1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE(84680-95-5)1HNMR1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE(84680-95-5)31PNMR

84680-95-5 (1,1'-Bis(di-tert-butylphosphino)ferrocene) Related Search:

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Ferrocene 1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride, Di-tert-butylphosphine Di-t-butyl(I-propyl)phosphine Triisopropylphosphine
1,1''-Bis(di-tert-butylphosphino)ferrocene palladium dichlori 1,1'-Bis(di-tert-butylphosphino)ferrocene palladium dichloride tert-Butyldiisopropylphosphine t-Butylphosphine

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1,1'-Bis(di-t-butylphosphino)ferrocene,min.98% 1,1'-Bis(di-tert-butylphosphino)ferrocene,min. 98% 1,1'-Bis(di-tert-butylphosphino)ferrocene ,98% 1,1'-Bis(di-tert-butylphosphin 98% DtBPF 1,1'-Bis(di-tert-butylphosphiNA)ferrocene 1,1'-Bis(di-t-butylphosphino)ferrocene, min. 98% 1,1'-Bis(di-t-butylphosphino)ferrocene,98% DtBPF 1,1'-Bis(di-t-butylphosphino)ferrocene, min. 98% DTBPF 1,1'-Bis(di-tert-butylphosphi 1,1'-Bis(di-t-butylphosphino)ferrocene,DtBPF DTBPF / 1,1'-Bis(di-tert-butylphosphino)ferrocene 1,1'-Bis(di-tert-butylphosphino)ferrocene 98% 1,1'-Bis(di-tert-butylphosphino)ferrocene > 1,1'-Bis(di-t-butyL Dehch（bis(2-ethylhexyl) cyclohexane -1,2-dicarboxylate） 1,1'-Bis(di-tert-butylphosphino)ferrocene 1,1'-Bis[bis(1,1-dimethylethyl)phosphino]ferrocene DTBPF ChemBeads 1,1'-Bis(di-tert-butylphosphino)ferrocene 1,1'-Bis[bis(1,1-dimethylethyl)phosphino]ferrocene 1,1'-Bis(di-t-butylphosphino)ferrocene BIS[(DI-TERT-BUTYLPHOSPHINO)CYCLOPENTADIENYL]IRON DBtPF DTBPF 84680-95-5 94680-95-5 C26H42FeP2 C26H44FeP2 C4H92PC5H42Fe 2C13H22PFe C26H44FeP210 2C13H23PFe Metallocenes Transition Metal Compounds Phosphine Ligands Classes of Metal Compounds Ferrocenes Fe (Iron) Compounds Achiral Phosphine Aryl Phosphine Classes of Metal Compounds Fe (Iron) Compounds Ferrocenes Metallocenes Phosphine Ligands Synthetic Organic Chemistry Transition Metal Compounds Catalysis and Inorganic Chemistry Phosphorus Compounds Polydentate Phosphine Ligands