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Lithium Bis(fluorosulfonyl)imide

CAS No.
171611-11-3
Chemical Name:
Lithium Bis(fluorosulfonyl)imide
Synonyms
LiFSI;LiFSA;Lithium Bis(fluorosulfonyl);Imidodisulfuryl fluoride lithium salt;Imidodisulfuryl fluoride lithium salt (LiFSI);LISFI;ithium Bis(fL;Li[(FSO2)2N]LiFSI;bis(fluorosulfonyl)azanide;Lithium bisfluorosulfonimide
CBNumber:
CB82604260
Molecular Formula:
F2NO4S2.Li
Molecular Weight:
188.08
MDL Number:
MFCD28126786
MOL File:
171611-11-3.mol
MSDS File:
SDS
Last updated:2026-06-17 16:47:17

Lithium Bis(fluorosulfonyl)imide Properties

Melting point 124-128℃
Density 1.052g/cm3 at 25℃
vapor pressure 27.198-31.064Pa at 20-25℃
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
Water Solubility Soluble in water
form Solid
color White to Almost white
Major Application battery manufacturing
InChI InChI=1S/F2NO4S2.Li/c1-8(4,5)3-9(2,6)7;/q-1;+1
InChIKey HOQSGMWVPMHPSZ-UHFFFAOYSA-N
SMILES [N-](S(=O)(F)=O)S(=O)(F)=O.[Li+]
LogP 3 at 20℃ and pH6
EPA Substance Registry System Imidodisulfuryl fluoride, lithium salt (1:1) (171611-11-3)
UNSPSC Code 12352104
NACRES NA.21

SAFETY

Risk and Safety Statements

Symbol(GHS)  Corrosion (GHS05)
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P260-P264-P280-P301+P330+P331+P310-P303+P361+P353+P310+P363-P304+P340+P310-P305+P351+P338+P310-P405-P501
RIDADR  1759
WGK Germany  WGK 3
TSCA  TSCA listed
HS Code  2826.19.9000
HazardClass  8
PackingGroup  II
Storage Class 11 - Combustible Solids
Hazard Classifications Acute Tox. 4 Oral
Eye Dam. 1
Muta. 2
Skin Irrit. 2
REACH Registrations Active
Limited Quantities 1 Kg (2.2 lbs) (solid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)

Lithium Bis(fluorosulfonyl)imide price More Price(21)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical L0281 Lithium Bis(fluorosulfonyl)imide >98.0%(T) 171611-11-3 5g $100 2026-04-30 Buy
TCI Chemical L0281 Lithium Bis(fluorosulfonyl)imide >98.0%(T) 171611-11-3 25g $328 2026-04-30 Buy
SynQuest Laboratories M016-2-00 Lithium bis(fluorosulfonyl)imide 98.0% 171611-11-3 100g $150 2026-05-22 Buy
aablocks AA00AKKF Lithium bis(fluorosulfonyl)amide 98% 171611-11-3 5g $8 2026-05-28 Buy
aablocks AA00AKKF Lithium bis(fluorosulfonyl)amide ≥98%(T) 171611-11-3 25g $15 2026-05-28 Buy
Product number Packaging Price Buy
L0281 5g $100 Buy
L0281 25g $328 Buy
M016-2-00 100g $150 Buy
AA00AKKF 5g $8 Buy
AA00AKKF 25g $15 Buy

Lithium Bis(fluorosulfonyl)imide Chemical Properties, Uses, Production

Chemical Properties

White to Almost white powder to crystal with Molecular Crystal Electrolytes with High Lithium Ion Conductivity.

Characteristics

Lithium bis(fluorosulfonyl)imide(LiFSI) is a important high-performance electrolyte material in new energy devices such as lithium-ion batteries and supercapacitors. It has the advantages of high stability (no decomposition below 200°C), excellent low temperature performance, good hydrolytic stability and environmental friendliness, etc., as the next generation of lithium hexafluorophosphate electrolyte lithium salt for secondary lithium ion batteries.

Uses

Lithium bis(fluorosulfonyl)imide is a promising new electrolyte additive for lithium ion batteries showing increased conductivity over LiPF6. Bis(fluorosulfonyl)imide has also been tested in next generation gel polymer electrolytes with improved safety properties.

Preparation

Lithium bis(fluorosulfonyl)imide (LiFSI) was synthesized by a metathesis reaction between KFSI and LiBF4 in DMC in nearly quantitative yield, similar to the preparation of its analogue, lithium (fluorosulfonyl) (pentafluoroethanesulfonyl)imide (LiFPFSI).
DOI: https://doi.org/10.1016/j.jpowsour.2010.12.040

Battery Materials

The conventional electrolytes for Li-ion batteries are based on the LiPF6 salt and carbonate solvents, lithium bis(fluorosulfonyl)imide (LiFSI) is an interesting candidate. LiFSI has an excellent solubility, and by use of concentrated electrolytes, corrosion of the aluminium current collector on the cathode side can be avoided[1].

References

[1] Asheim, K., Wagner, N. P., Vullum, P. E., Foss, C. E. L., Mæhlen, J. P., & Svensson, A. M. (2025). Effect of Concentration of Lithium Bis(fluorosulfonyl)imide on the Performance of Silicon Anodes for Li-Ion Batteries. Electrochemical Science Advances, 6 1. https://doi.org/10.1002/elsa.70009

Lithium Bis(fluorosulfonyl)imide Preparation Products And Raw materials

Global Suppliers ( 323)
Supplier Tel Email Country ProdList Advantage
Huaihua Yuanyanda Biotechnology Co., Ltd 18711085600 1652923704@qq.com China 4626 58
Aikon International Limited 025-58851090 13913916777 sales01@aikonchem.com China 15947 58
East Star Biotech (Suzhou) Co., Ltd. 0512-62620298 17520198886 18636423@qq.com China 29 58
Shijiazhuang Jianxin Biotechnology Co., LTD 0311-1906231-3169 19062313169 19062313169@163.com China 397 58
Hubei SVETO New Material Technology Co., Ltd 13277095679 1375175909@qq.com China 641 58
Shandong Hemao New Material Co., Ltd. 13061243681 hemiao66@163.com China 182 58
Shanghai Daolian Reagent Co., Ltd 13122339260 dowrian@outlook.com China 354 58
HuBei ShengWei New Material Co., Ltd. 15207170057 15207170057 3605285405@qq.com China 172 58
Shanghai Haomuren New Materials Co., Ltd. 15317828837 3759584103@qq.com China 43 58
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24512 81

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View Latest Price from Lithium Bis(fluorosulfonyl)imide manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Lithium Bis(fluorosulfonyl)imide pictures 2026-09-18 Lithium Bis(fluorosulfonyl)imide
171611-11-3
1kg 99%min 1000kg WUHAN FORTUNA CHEMICAL CO., LTD
Lithium Bis(fluorosulfonyl)imide pictures 2026-06-30 Lithium Bis(fluorosulfonyl)imide
171611-11-3
1KG 98% 1000kgs Shaanxi Dideu New Materials Co. Ltd
Lithium Bis(fluorosulfonyl)imide pictures 2025-12-29 Lithium Bis(fluorosulfonyl)imide
171611-11-3
1kg 99.5% Changzhou waston chemical technology Co.,Ltd
Imidodisulfuryl fluoride lithium salt Lithium bis(fluorosulfonyl)imide LithiuM bis(fluorosulfony)iMide LiFSI Lithium Bis(fluorosulfonyl)imide Bis(fluorosulfonyl)imide Lithium Lithium bisfluorosulfonimide Li[(FSO2)2N]LiFSI bis (fluorosulfonyl) imine lithium ithium Bis(fL LITHIUM BIS (FLUOROSULFONYL) IMIDE/LiFSi Lithium Bis(fluorosulfonyl)imide ISO 9001:2015 REACH LiFSI, Lithium bis(fluorosulfonyl)imede bis(fluorosulfonyl)azanide Lithium difluorosulfonamide salt Difluorosulfonylimide lithium salt Lithium Bis(fluorosulfonyl)imide 686-526-7 Bis(Fluorosulfonyl)imide Lithium Salt LISFI bisfluorosulfonylacylisoaminesalt Imidodisulfuryl fluoride lithium salt (LiFSI) LiFSA LiFSI Lithium Bis(fluorosulfonyl) Lithium Bis(fluorosulfonyl)imide ≥99.9% 171611-11-3 F2NO4S2Li F2LiNO4S2 Lithium battery electrolyte Battery materia