ChemicalBook >> CAS DataBase List >>2,4,6-Triformylphloroglucinol

2,4,6-Triformylphloroglucinol

CAS No.
34374-88-4
Chemical Name:
2,4,6-Triformylphloroglucinol
Synonyms
1,3,5-Triformylphloroglucinol;2,4,6-trihydroxybenzene-1,3,5-tricarbaldehyde;triformylPhloroglucinol;2,4,6-Triformylphloroglucinol;BZ500;1,3,5-Benzenetricarboxaldehyde, 2,4,6-trihydroxy-;2,4,6-Trihydroxy-1,3,5-benzenetricarbaldehyde, 95%;DK7335;JACS-34374-88-4;Trialdehyde Resorcinol
CBNumber:
CB82707907
Molecular Formula:
C9H6O6
Molecular Weight:
210.14
MDL Number:
MFCD24713435
MOL File:
34374-88-4.mol
MSDS File:
SDS
Last updated:2026-07-15 10:13:56

2,4,6-Triformylphloroglucinol Properties

Melting point 198-200 °C
Boiling point 233.8±40.0 °C(Predicted)
Density 1.755±0.06 g/cm3(Predicted)
storage temp. Inert atmosphere,Store in freezer, under -20°C
solubility DMSO (Slightly, Heated)
form Solid
pka 3.32±0.33(Predicted)
color Pale Orange
InChI InChI=1S/C9H6O6/c10-1-4-7(13)5(2-11)9(15)6(3-12)8(4)14/h1-3,13-15H
InChIKey KAPNIDMXEKQLMQ-UHFFFAOYSA-N
SMILES C1(C=O)=C(O)C(C=O)=C(O)C(C=O)=C1O
UNSPSC Code 41116107
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H319-H315
Precautionary statements  P264-P280-P305+P351+P338-P337+P313P-P264-P280-P302+P352-P321-P332+P313-P362
WGK Germany  WGK 3
HS Code  2912.49.6000
Storage Class 11 - Combustible Solids
NFPA 704
0
2 0

2,4,6-Triformylphloroglucinol price More Price(46)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical T3688 2,4,6-Triformylphloroglucinol min. 98.0 % 34374-88-4 200MG $52 2026-04-30 Buy
TCI Chemical T3688 2,4,6-Triformylphloroglucinol min. 98.0 % 34374-88-4 1G $156 2026-04-30 Buy
Usbiological 420387 2,4,6-Triformylphloroglucinol ≥97%(HPLC) 34374-88-4 250mg $489 2026-06-03 Buy
Usbiological 420387 2,4,6-Triformylphloroglucinol ≥97%(HPLC) 34374-88-4 500mg $779 2026-06-03 Buy
Usbiological 420387 2,4,6-Triformylphloroglucinol ≥97%(HPLC) 34374-88-4 1g $1097 2026-06-03 Buy
Product number Packaging Price Buy
T3688 200MG $52 Buy
T3688 1G $156 Buy
420387 250mg $489 Buy
420387 500mg $779 Buy
420387 1g $1097 Buy

2,4,6-Triformylphloroglucinol Chemical Properties, Uses, Production

Uses

MOP is a phenolic organic compound which can be used as intermediate of synthetic materials.

Description

2,4,6-Triformylphloroglucinol (MOP)is a highly functionalised and symmetrical building block.

Physical properties

Pale orange solid

Uses

2,4,6-Triformylphloroglucinol is a chemical reagent used in gelation landscape engineering with a hydrogelator system to control products. This prevents the formation of hydrogel materials with vastly different properties. In addition, it is used in the preparation of luminescent nanoporous hybrid material to be used as a drug delivery system for anti-cancer agents.

Definition

2,4,6-Triformylphloroglucinol is a highly functionalised and symmetrical building block. 2,4,6-Triformylphloroglucinol contains 3 aldehyde groups which can react with nucleophiles, such as amines or anilines, to make β-ketoenamines. When the nucleophile contains more than one amine group, microporous polymers can be formed. These microporous polymers find a wide range of applications, including carbon dioxide capture.

Synthesis

Phloroglucinol

108-73-6

Hexamethylenetetramine

100-97-0

2,4,6-Triformylphloroglucinol

34374-88-4

In a 50 mL xylene vial, accurately weigh 2 g of hexamethylenetetramine (urotropine) and slowly add 10 mL of fresh trifluoroacetic acid. The reaction vial needs to be cooled in an ice water bath due to the exothermic nature of the reaction which may lead to loss of trifluoroacetic acid by evaporation. Under nitrogen protection, 0.67 g of resorcinol was added to the reaction system and 50 mL of glycerol was added as solvent. Subsequently, the reaction was carried out at 120°C for 1.5 h under microwave radiation conditions. Upon completion of the reaction, the reaction mixture was cooled to room temperature and extracted by adding 30 mL of dichloromethane to isolate trifluoroacetic acid. The supernatant was subjected to a simple secondary distillation (first at 40°C and atmospheric pressure, followed by raising the temperature of the distillate to 72°C) and 7 mL of the fraction was collected. The recovered concentration of trifluoroacetic acid was measured to be 98.6% and the calculated recovery was 70% by gas chromatography analysis. The solution was filtered, the filtrate was extracted with chloroform, the mixture was treated with sulfuric acid and filtered again. The filtrate was dried under vacuum to give a light pink solid. The solid was confirmed to be 1,3,5-traldehyde mesitylene trisphenol (target product) by 1H-NMR (Figure 1) analysis in a yield of 0.085 g. The solid was analyzed by 1H-NMR (Figure 1).

References

[1] Chemistry - A European Journal, 2016, vol. 22, # 47, p. 17029 - 17036
[2] Dyes and Pigments, 2016, vol. 132, p. 291 - 305
[3] Journal of Polymer Science, Part A: Polymer Chemistry, 2018, vol. 56, # 20, p. 2344 - 2353
[4] Journal of Organic Chemistry, 2009, vol. 74, # 8, p. 3168 - 3171
[5] Journal of the American Chemical Society, 2015, vol. 137, # 45, p. 14236 - 14239

2,4,6-Triformylphloroglucinol Preparation Products And Raw materials

Global Suppliers ( 172)
Supplier Tel Email Country ProdList Advantage
Xi'an duokai Trading Co., Ltd 029-82283472 15091869467 1055507341@qq.com China 298 58
Jilin Chinese Academy of Sciences-yanshen Technology 18143011203 ET-market@chemextension.com China 38900 58
Shanghai TenSus Biotechnology Co., Ltd. 021-50895067 18616507272;13681616114;15020344067 tensus@163.com China 8029 58
Henan Alfachem Co.,Ltd. 0371-55051623 18137891487 3983243027@qq.com China 9970 58
Meryer (Shanghai) Chemical Technology Co., Ltd. 18621169109 market03@meryer.com China 27963 58
Shaanxi PharmaGHS Science Co., LTD 029-13279368192 13279368192 pharmaghs@126.com China 2913 58
Pushan Industry (Shaanxi) Co., Ltd. 029-81310890 18165209495 2929288192@qq.com China 9949 58
Jinan Yaode Biotechnology Co., Ltd 17805033575; 17805033575 baiyu1.618@163.com China 391 58
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24512 81
Beijing HwrkChemical Technology Co., Ltd 89508211 18501085097 sales.bj@hwrkchemical.com China 9407 55

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View Latest Price from 2,4,6-Triformylphloroglucinol manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
	2,4,6-Triformylphloroglucinol pictures 2026-09-02 2,4,6-Triformylphloroglucinol
34374-88-4
$30.00 1kg 99% Henan Fengda Chemical Co., Ltd
	2,4,6-Triformylphloroglucinol pictures 2026-09-02 2,4,6-Triformylphloroglucinol
34374-88-4
$30.00 1kg 99% Henan Fengda Chemical Co., Ltd
	2,4,6-Triformylphloroglucinol pictures 2026-09-02 2,4,6-Triformylphloroglucinol
34374-88-4
$30.00 1kg 99% Henan Fengda Chemical Co., Ltd

2,4,6-Triformylphloroglucinol Spectrum

1,3,5-Benzenetricarboxaldehyde, 2,4,6-trihydroxy- 2,4,6-Trihydroxy-1,3,5-benzenetricarbaldehyde, 95% 2,4,6-Triformylphloroglucinol Phloroglucinol Impurity 20 JACS-34374-88-4 Trialdehyde Resorcinol Phloroglucinol Triformyl BZ500 DK7335 2,4,6-triformylmetabenzenetriphenol 1,3,5-Triformylphloroglucinol 2,4,6-trihydroxybenzene-1,3,5-tricarbaldehyde triformylPhloroglucinol 2,4,6-trihydroxy-1,3,5-benzenetricarbaldehyde 34374-88-4 COF