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Bis(4-methoxyphenyl)chlorophosphine

CAS No.
13685-30-8
Chemical Name:
Bis(4-methoxyphenyl)chlorophosphine
Synonyms
Bis(4-methoxyphenyl)chlorophosphine;Chlorobis(4-methoxyphenyl)phosphine;chloro-bis(4-methoxyphenyl)phosphane;Bis(4-methoxyphenyl)phosphinouschloride;Chlorobis(4-methoxyphenyl)phosphine, 98+%;P,P-Bis(4-methoxyphenyl)phosphinous chloride;Phosphinous chloride, P,P-bis(4-methoxyphenyl)-
CBNumber:
CB8671109
Molecular Formula:
C14H14ClO2P
Molecular Weight:
280.69
MDL Number:
MFCD04972301
MOL File:
13685-30-8.mol
MSDS File:
SDS
Last updated:2026-09-12 18:55:49

Bis(4-methoxyphenyl)chlorophosphine Properties

Melting point 61-64℃
Boiling point 140°C/1.5mm
Flash point 140°C/1.5mm
form solid
Water Solubility Reacts with water.
Sensitive Moisture Sensitive
InChI 1S/C14H14ClO2P/c1-16-11-3-7-13(8-4-11)18(15)14-9-5-12(17-2)6-10-14/h3-10H,1-2H3
InChIKey YTFQUBRFOJIJOZ-UHFFFAOYSA-N
SMILES COc1ccc(cc1)P(Cl)c2ccc(OC)cc2
UNSPSC Code 12352112
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Corrosion (GHS05)
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363
PPE Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Hazard Codes  C
Risk Statements  34
Safety Statements  26-36/37/39-45
RIDADR  UN3265
WGK Germany  3
HazardClass  8
PackingGroup  III
Storage Class 8A - Combustible corrosive hazardous materials
Hazard Classifications Skin Corr. 1B
NFPA 704
1
3 0

Bis(4-methoxyphenyl)chlorophosphine price More Price(11)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 698474 Bis(4-methoxyphenyl)chlorophosphine 95% 13685-30-8 250mg $88.7 2023-06-20 Buy
Sigma-Aldrich 710377 Bis(4-methoxyphenyl)chlorophosphine 85% 13685-30-8 2g $211 2023-01-07 Buy
aablocks AA0012EC BIS(4-METHOXYPHENYL)CHLOROPHOSPHINE 98%;RG 13685-30-8 100mg $66 2026-05-27 Buy
aablocks AA0012EC BIS(4-METHOXYPHENYL)CHLOROPHOSPHINE 98% 13685-30-8 250mg $105 2026-05-27 Buy
aablocks AA0012EC BIS(4-METHOXYPHENYL)CHLOROPHOSPHINE 98% 13685-30-8 1g $315 2026-05-27 Buy
Product number Packaging Price Buy
698474 250mg $88.7 Buy
710377 2g $211 Buy
AA0012EC 100mg $66 Buy
AA0012EC 250mg $105 Buy
AA0012EC 1g $315 Buy

Bis(4-methoxyphenyl)chlorophosphine Chemical Properties, Uses, Production

Uses

Chlorobis(4-methoxyphenyl)phosphine is used an pharmaceutical intermediate.

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

Bis(4-methoxyphenyl)chlorophosphine Preparation Products And Raw materials

Raw materials

Preparation Products

Global Suppliers ( 39)
Supplier Tel Email Country ProdList Advantage
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84
Beijing HwrkChemical Technology Co., Ltd 89508211 18501085097 sales.bj@hwrkchemical.com China 9407 55
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Beijing VSciChem Technology Co., Ltd. 13811761079 vscichem@163.com China 271 64
Shanghai Hanhong Scientific Co.,Ltd. 021-54306202 13764082696 info@hanhongsci.com China 42917 64
Shandong Xiya Chemical Co., Ltd 13355009207 13355009207 3007715519@qq.com China 18722 57
Shanghai CanSpecsci Instrument Co., Ltd. 400-6087598 15021221957 order@canspecsci.com China 2001 56
Shanghai Macklin Biochemical Co.,Ltd. 15221275939 15221275939 shenlinxing@macklin.cn China 15775 55
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51389 80
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd. 0371-65511006 18625597674 info@kingorgchem.com;sales@kingorgchem.com China 806 55
Chlorobis(4-methoxyphenyl)phosphine, 98+% Chlorobis(4-methoxyphenyl)phosphine chloro-bis(4-methoxyphenyl)phosphane P,P-Bis(4-methoxyphenyl)phosphinous chloride Phosphinous chloride, P,P-bis(4-methoxyphenyl)- Bis(4-methoxyphenyl)phosphinouschloride Bis(4-methoxyphenyl)chlorophosphine 13685-30-8 C14H14ClO2P