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Bis(3,5-di-tert-butyl-4-methoxyphenyl)chlorophosphine

CAS No.
212713-08-1
Chemical Name:
Bis(3,5-di-tert-butyl-4-methoxyphenyl)chlorophosphine
Synonyms
Bis(3,5-di-t-butyl-4-methoxyphenyl)chlorophosphine,;chloro-bis(3,5-ditert-butyl-4-methoxyphenyl)phosphane;Bis(3,5-di-tert-butyl-4-methoxyphenyl)chlorophosphine;Bis(3,5-di-t-butyl-4-methoxyphenyl)chlorophosphine,93%;BIS(3,5-DI-TERT-BUTYL-4-METHOXYPHENYL)PHOSPHINOUS CHLORIDE;Bis(3,5-di-tert-butyl-4-methoxyphenyl)chlorophosphine;Bis[3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl]phosphinous chloride;Phosphinous chloride, P,P-bis[3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl]-
CBNumber:
CB8772675
Molecular Formula:
C30H46ClO2P
Molecular Weight:
505.11
MDL Number:
MFCD08458881
MOL File:
212713-08-1.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-09-12 18:55:52

Bis(3,5-di-tert-butyl-4-methoxyphenyl)chlorophosphine Properties

Melting point 116-120 °C
Boiling point 552.5±50.0 °C(Predicted)
form solid
Water Solubility Reacts with water.
Sensitive Air & Moisture Sensitive
InChI 1S/C30H46ClO2P/c1-27(2,3)21-15-19(16-22(25(21)32-13)28(4,5)6)34(31)20-17-23(29(7,8)9)26(33-14)24(18-20)30(10,11)12/h15-18H,1-14H3
InChIKey VOGHMZHRQUWLRE-UHFFFAOYSA-N
SMILES COc1c(cc(cc1C(C)(C)C)P(Cl)c2cc(c(OC)c(c2)C(C)(C)C)C(C)(C)C)C(C)(C)C
UNSPSC Code 12352112
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Flame (GHS02)
GHS02
Signal word  Warning
Hazard statements  H228
Precautionary statements  P210
PPE Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
Hazard Codes  F
Risk Statements  11
RIDADR  UN3261
WGK Germany  3
HazardClass  8
PackingGroup  II
Storage Class 4.1B - Flammable solid hazardous materials
Hazard Classifications Flam. Sol. 2
NFPA 704
1
3 0

Bis(3,5-di-tert-butyl-4-methoxyphenyl)chlorophosphine price More Price(7)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 694703 Bis(3,5-di-tert-butyl-4-methoxyphenyl)chlorophosphine 212713-08-1 100mg $79.8 2023-06-20 Buy
Sigma-Aldrich 694703 Bis(3,5-di-tert-butyl-4-methoxyphenyl)chlorophosphine 212713-08-1 500mg $285 2023-01-07 Buy
aablocks AA003O6D Bis(3,5-Di-Tert-Butyl-4-Methoxyphenyl)Chlorophosphine 212713-08-1 250mg $238 2026-05-28 Buy
aablocks AA003O6D Bis(3,5-Di-Tert-Butyl-4-Methoxyphenyl)Chlorophosphine 212713-08-1 1g $773 2026-05-28 Buy
American Custom Chemicals Corporation ING0005846 BIS(3,5-DI-TERT-BUTYL-4-METHOXYPHENYL)CHLOROPHOSPHINE 95.00% 212713-08-1 1G $268.8 2021-12-16 Buy
Product number Packaging Price Buy
694703 100mg $79.8 Buy
694703 500mg $285 Buy
AA003O6D 250mg $238 Buy
AA003O6D 1g $773 Buy
ING0005846 1G $268.8 Buy

Bis(3,5-di-tert-butyl-4-methoxyphenyl)chlorophosphine Chemical Properties,Uses,Production

Uses

It is used as a reactant for asymmetric hydrogenation with iridium catalysts, chemo selective reaction with deprotonated 2-hydoxy-3,3,N-trimethylbutanamide. It is also used as a reactant for synthesis of phosphine- containing amino acids and peptide-based catalyst ligands, nonracemic phosphine-containing amino acids for palladium- catalyzed asymmetric allylic substitution reactions.

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

Bis(3,5-di-tert-butyl-4-methoxyphenyl)chlorophosphine Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 32)Suppliers
Supplier Tel Email Country ProdList Advantage
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Shanghai Hanhong Scientific Co.,Ltd. 021-54306202 13764082696 info@hanhongsci.com China 42917 64
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51389 80
Shandong Ono Chemical Co., Ltd. 0539-6362799 20) China 10007 58
Henan Lien Chemical Products Co., Ltd. 0371-63357898 15378766539 535046669@qq.com China 5735 58
SHAOXING ZHIJUN PHARMACEUTICAL TECHNOLOGY CO.,LTD 0575-82126188 15395856318 service@zejunpharma.com China 487 58
Shaanxi Dideu Medichem Co. Ltd +86-29-81139210 17389186172 1077@dideu.com China 3999 58
Beijing Aomi Jiade Pharmaceutical Technology Co., Ltd +86-13522808617 omichem@126.com China 6401 58
Shaanxi Dideu Medichem Co. Ltd 029-81154043 17391733319 1086@dideu.com China 9970 58

View Lastest Price from Bis(3,5-di-tert-butyl-4-methoxyphenyl)chlorophosphine manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Bis(3,5-di-tert-butyl-4-methoxyphenyl)chlorophosphine  pictures 2026-08-07 Bis(3,5-di-tert-butyl-4-methoxyphenyl)chlorophosphine
212713-08-1
$1.00 1KG 99% 20 tons Shaanxi Dideu Medichem Co. Ltd
BIS(3,5-DI-TERT-BUTYL-4-METHOXYPHENYL)PHOSPHINOUS CHLORIDE Bis(3,5-di-t-butyl-4-methoxyphenyl)chlorophosphine, Bis(3,5-di-t-butyl-4-methoxyphenyl)chlorophosphine,93% Bis[3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl]phosphinous chloride chloro-bis(3,5-ditert-butyl-4-methoxyphenyl)phosphane Phosphinous chloride, P,P-bis[3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl]- Bis(3,5-di-tert-butyl-4-methoxyphenyl)chlorophosphine Bis(3,5-di-tert-butyl-4-methoxyphenyl)chlorophosphine 212713-08-1 C30H46ClO2P Catalysis and Inorganic Chemistry Phosphorus Compounds Phosphorus Precursors