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2-BROMO-4-METHOXY-PHENYLAMINE

CAS No.
32338-02-6
Chemical Name:
2-BROMO-4-METHOXY-PHENYLAMINE
Synonyms
SKL231;2-Bromo-p-anisidine;4-Amino-3-bromoanisole;2-BROMO-4-METHOXYANILINE;2-Bromo-4-methoxyaniline 95%;2-BROMO-4-METHOXY-PHENYLAMINE;BenzenaMine, 2-broMo-4-Methoxy-;4-Amino-3-bromoanisole, 2-Bromo-p-anisidine;4-AMino-3-broMoanisole[2-BroMo-4-Methoxyaniline];N2,N4-diethyl-6-ethylsulfanyl-1,3,5-triazine-2,4-diamine
CBNumber:
CB8840949
Molecular Formula:
C7H8BrNO
Molecular Weight:
202.05
MDL Number:
MFCD09029057
MOL File:
32338-02-6.mol
MSDS File:
SDS
Last updated:2025-07-24 18:13:50

2-BROMO-4-METHOXY-PHENYLAMINE Properties

Melting point 64 °C
Boiling point 76-98 °C(Press: 2 Torr)
Density 1.531±0.06 g/cm3(Predicted)
storage temp. 2-8°C(protect from light)
solubility Chloroform (Slightly), DMSO (Slightly)
pka 3.14±0.10(Predicted)
form liquid
color Clear, dark red
UNSPSC Code 12352200

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H332-H335
Precautionary statements  P261-P280-P305+P351+P338
HazardClass  IRRITANT
HS Code  2922290090

2-BROMO-4-METHOXY-PHENYLAMINE price More Price(19)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TRC B699470 2-Bromo-4-methoxyaniline 32338-02-6 10g $250 2021-12-16 Buy
TRC B699470 2-Bromo-4-methoxyaniline 32338-02-6 25g $530 2021-12-16 Buy
American Custom Chemicals Corporation HCH0049713 2-BROMO-4-METHOXY-PHENYLAMINE 95.00% 32338-02-6 1G $733.43 2021-12-16 Buy
American Custom Chemicals Corporation HCH0049713 2-BROMO-4-METHOXY-PHENYLAMINE 95.00% 32338-02-6 5G $1241.63 2021-12-16 Buy
Apolloscientific OR61502 2-Bromo-4-methoxyaniline 96% 32338-02-6 25g $186 2021-12-16 Buy
Product number Packaging Price Buy
B699470 10g $250 Buy
B699470 25g $530 Buy
HCH0049713 1G $733.43 Buy
HCH0049713 5G $1241.63 Buy
OR61502 25g $186 Buy

2-BROMO-4-METHOXY-PHENYLAMINE Chemical Properties,Uses,Production

Uses

2-Bromo-4-methoxyaniline is a useful reagent and reactant in organometallics, and organic reactions.

Synthesis

p-Anisidine

104-94-9

2-BROMO-4-METHOXY-PHENYLAMINE

32338-02-6

General procedure for the synthesis of 2-bromo-4-methoxyaniline from 4-methoxyaniline: N-bromosuccinimide (NBS, 152 g, 853 mmol) was added batchwise to a tetrahydrofuran (THF, 3 L) solution of 4-methoxyaniline (100 g, 812 mmol) at -10 °C, keeping the temperature constant and stirring continuously for 30 min. After completion of the reaction, the mixture was concentrated under reduced pressure. The residue was purified by column chromatography (eluent: petroleum ether/ethyl acetate, 15:1, v/v) to afford the target product 2-bromo-4-methoxyaniline as a red oil (30.58 g, 18.6% yield). The nuclear magnetic resonance hydrogen spectrum (1H NMR, 400 MHz, CDCl3) data were as follows: δ = 7.01 (d, J = 2.4 Hz, 1H), 6.74-6.70 (m, 2H), 3.85-3.74 (m, 2H), 3.73 (s, 3H).

References

[1] Russian Journal of Applied Chemistry, 2009, vol. 82, # 9, p. 1570 - 1576
[2] Journal of the Chilean Chemical Society, 2011, vol. 56, # 4, p. 863 - 865
[3] Organic Letters, 2006, vol. 8, # 19, p. 4291 - 4293
[4] Journal of the Brazilian Chemical Society, 2010, vol. 21, # 3, p. 496 - 501
[5] Synthetic Communications, 2010, vol. 40, # 6, p. 868 - 876

Global( 149)Suppliers
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View Lastest Price from 2-BROMO-4-METHOXY-PHENYLAMINE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-broMo-4-Methoxyaniline pictures 2020-03-16 2-broMo-4-Methoxyaniline
32338-02-6
US $0.01-1.00 / KG 1KG 99% 10000KG Shaanxi Dideu Medichem Co. Ltd
2-Bromo-4-methoxyaniline  pictures 2020-02-26 2-Bromo-4-methoxyaniline
32338-02-6
US $1.00-1.00 / KG 1KG 99%+ 100 tons Shaanxi Dideu Medichem Co. Ltd
2-BROMO-4-METHOXY-PHENYLAMINE pictures 2019-07-12 2-BROMO-4-METHOXY-PHENYLAMINE
32338-02-6
US $1.00 / KG 1KG 99% 100kg Career Henan Chemical Co
2-BROMO-4-METHOXY-PHENYLAMINE 2-Bromo-p-anisidine 2-N,4-N-diethyl-6-ethylsulfanyl-1,3,5-triazine-2,4-diamine ethyl-[4-(ethylamino)-6-(ethylthio)-s-triazin-2-yl]amine N2,N4-diethyl-6-ethylsulfanyl-1,3,5-triazine-2,4-diamine 2-Bromo-4-methoxyaniline 95% 4-Amino-3-bromoanisole, 2-Bromo-p-anisidine 4-AMino-3-broMoanisole[2-BroMo-4-Methoxyaniline] 2-BROMO-4-METHOXYANILINE BenzenaMine, 2-broMo-4-Methoxy- SKL231 4-Amino-3-bromoanisole 32338-02-6 Anilines, Aromatic Amines and Nitro Compounds