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2-Bromo-4-methoxy-phenylamine

2-Bromo-4-methoxy-phenylamine Structure
2-Bromo-4-methoxy-phenylamine structure
CAS No.
32338-02-6
Chemical Name:
2-Bromo-4-methoxy-phenylamine
Synonyms
2-BROMO-4-METHOXYANILINE;SKL231;2-Bromo-p-anisidine;4-Amino-3-bromoanisole;2-Bromo-4-methoxyaniline 95%;2-Bromo-4-methoxy-phenylamine;BenzenaMine, 2-broMo-4-Methoxy-;4-Amino-3-bromoanisole, 2-Bromo-p-anisidine;4-AMino-3-broMoanisole[2-BroMo-4-Methoxyaniline];N2,N4-diethyl-6-ethylsulfanyl-1,3,5-triazine-2,4-diamine
CBNumber:
CB8840949
Molecular Formula:
C7H8BrNO
Molecular Weight:
202.05
MDL Number:
MFCD09029057
MOL File:
32338-02-6.mol
MSDS File:
SDS
Last updated:2026-09-12 18:55:53
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2-Bromo-4-methoxy-phenylamine Properties

Melting point 64 °C
Boiling point 76-98 °C(Press: 2 Torr)
Density 1.531±0.06 g/cm3(Predicted)
storage temp. 2-8°C(protect from light)
solubility Chloroform (Slightly), DMSO (Slightly)
pka 3.14±0.10(Predicted)
form liquid
color Clear, dark red
InChI 1S/C7H8BrNO/c1-10-5-2-3-7(9)6(8)4-5/h2-4H,9H2,1H3
InChIKey YBAGMTVKDRIMTB-UHFFFAOYSA-N
SMILES COC1=CC=C(C(Br)=C1)N
UNSPSC Code 12352200
NACRES NA.21

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H332-H335
Precautionary statements  P261-P280-P305+P351+P338
HazardClass  IRRITANT
HS Code  2922290090
Storage Class 11 - Combustible Solids
Hazard Classifications Acute Tox. 4 Oral

2-Bromo-4-methoxy-phenylamine price More Price(34)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical B6636 2-Bromo-4-methoxyaniline min. 97.0 % 32338-02-6 1G $78 2026-04-30 Buy
TCI Chemical B6636 2-Bromo-4-methoxyaniline min. 97.0 % 32338-02-6 5G $234 2026-04-30 Buy
Apolloscientific OR61502 2-Bromo-4-methoxyaniline 96% 32338-02-6 1g $21 2026-06-04 Buy
Activate Scientific AS33773 2-Bromo-4-methoxyaniline 98% 32338-02-6 5g $24 2026-06-04 Buy
Apolloscientific OR61502 2-Bromo-4-methoxyaniline 96% 32338-02-6 5g $33 2026-06-04 Buy
Product number Packaging Price Buy
B6636 1G $78 Buy
B6636 5G $234 Buy
OR61502 1g $21 Buy
AS33773 5g $24 Buy
OR61502 5g $33 Buy

2-Bromo-4-methoxy-phenylamine Chemical Properties,Uses,Production

Uses

2-Bromo-4-methoxyaniline is a useful reagent and reactant in organometallics, and organic reactions.

Synthesis

p-Anisidine

104-94-9

2-BROMO-4-METHOXY-PHENYLAMINE

32338-02-6

General procedure for the synthesis of 2-bromo-4-methoxyaniline from 4-methoxyaniline: N-bromosuccinimide (NBS, 152 g, 853 mmol) was added batchwise to a tetrahydrofuran (THF, 3 L) solution of 4-methoxyaniline (100 g, 812 mmol) at -10 °C, keeping the temperature constant and stirring continuously for 30 min. After completion of the reaction, the mixture was concentrated under reduced pressure. The residue was purified by column chromatography (eluent: petroleum ether/ethyl acetate, 15:1, v/v) to afford the target product 2-bromo-4-methoxyaniline as a red oil (30.58 g, 18.6% yield). The nuclear magnetic resonance hydrogen spectrum (1H NMR, 400 MHz, CDCl3) data were as follows: δ = 7.01 (d, J = 2.4 Hz, 1H), 6.74-6.70 (m, 2H), 3.85-3.74 (m, 2H), 3.73 (s, 3H).

References

[1] Russian Journal of Applied Chemistry, 2009, vol. 82, # 9, p. 1570 - 1576
[2] Journal of the Chilean Chemical Society, 2011, vol. 56, # 4, p. 863 - 865
[3] Organic Letters, 2006, vol. 8, # 19, p. 4291 - 4293
[4] Journal of the Brazilian Chemical Society, 2010, vol. 21, # 3, p. 496 - 501
[5] Synthetic Communications, 2010, vol. 40, # 6, p. 868 - 876

2-Bromo-4-methoxy-phenylamine Preparation Products And Raw materials

Raw materials

p-Anisidine 3-Bromo-4-nitroanisole Tetrahydrofuran N-Bromosuccinimide

Preparation Products

Methyl 4-amino-2-bromobenzoate 2-bromo-1-iodo-4-methoxybenzene 2-Cyano-6-methoxybenzothiazole Benzenamine, 4-methoxy-2-(1-methylethenyl)- 4-Methoxy-2-(pyridin-3-yl)aniline

2-Bromo-4-methoxy-phenylamine Suppliers

Global( 157)Suppliers
Supplier Tel Email Country ProdList Advantage
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
ChemFuture PharmaTech (Jiangsu) Ltd 5108538618 suger.wang@chemfuture.com China 832 65
ShangHai DEMO Chemical Co.,Ltd 400-021-7337 2355568890 sales@demochem.com China 2569 57
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Capot Chemical Co., Ltd +86 (0) 571 85 58 67 18 China 18187 66
Beijing Ouhe Technology Co., Ltd 13552068683 13522913783 2355560935@qq.com China 11777 60
JinYan Chemicals(ShangHai) Co.,Ltd. 13817811078 sales@jingyan-chemical.com China 9963 60
Jia Xing Isenchem Co.,Ltd 0573-85285100 18627885956 isenchem@163.com China 9389 66
Accela ChemBio Co.,Ltd. 021-50795510 4000665055 marketing@accelachem.com China 10972 64
Nanjing Chemlin Chemical Co., Ltd 025-83697070 13770331960 info@chemlin.com.cn China 16305 64
Supplier Advantage
J & K SCIENTIFIC LTD. 76
ChemFuture PharmaTech (Jiangsu) Ltd 65
ShangHai DEMO Chemical Co.,Ltd 57
Energy Chemical 61
Capot Chemical Co., Ltd 66
Beijing Ouhe Technology Co., Ltd 60
JinYan Chemicals(ShangHai) Co.,Ltd. 60
Jia Xing Isenchem Co.,Ltd 66
Accela ChemBio Co.,Ltd. 64
Nanjing Chemlin Chemical Co., Ltd 64

View Lastest Price from 2-Bromo-4-methoxy-phenylamine manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-broMo-4-Methoxyaniline pictures 2026-08-07 2-broMo-4-Methoxyaniline
32338-02-6
 $1.00 1KG 99% 10000KG Shaanxi Dideu Medichem Co. Ltd
2-Bromo-4-methoxyaniline pictures 2020-02-26 2-Bromo-4-methoxyaniline
32338-02-6
 $1.00 1KG 99%+ 100 tons Shaanxi Dideu Medichem Co. Ltd
2-BROMO-4-METHOXY-PHENYLAMINE pictures 2019-07-12 2-BROMO-4-METHOXY-PHENYLAMINE
32338-02-6
 $1.00 1KG 99% 100kg Career Henan Chemical Co

2-Bromo-4-methoxy-phenylamine Spectrum

2-BROMO-4-METHOXY-PHENYLAMINE(32338-02-6)1HNMR2-BROMO-4-METHOXY-PHENYLAMINE(32338-02-6)FT-IR

32338-02-6(2-Bromo-4-methoxy-phenylamine)Related Search:

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6-Bromo-7-nitro-2,3-dihydro-1,4-benzodioxine 1-[2-Bromo-4-(trifluoromethoxy)phenyl]-2,5-dimethyl-1H-pyrrole 5-Bromo-6-nitrobenzo(1,3)dioxole 1-Bromo-4,5-dimethoxy-2-nitrobenzene 2-Bromo-6-nitro-4-trifluoromethoxyaniline
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1of4

2-Bromo-p-anisidine 2-N,4-N-diethyl-6-ethylsulfanyl-1,3,5-triazine-2,4-diamine ethyl-[4-(ethylamino)-6-(ethylthio)-s-triazin-2-yl]amine N2,N4-diethyl-6-ethylsulfanyl-1,3,5-triazine-2,4-diamine 2-Bromo-4-methoxyaniline 95% 4-Amino-3-bromoanisole, 2-Bromo-p-anisidine 4-AMino-3-broMoanisole[2-BroMo-4-Methoxyaniline] BenzenaMine, 2-broMo-4-Methoxy- SKL231 4-Amino-3-bromoanisole 2-BROMO-4-METHOXYANILINE 2-Bromo-4-methoxy-phenylamine 32338-02-6 Anilines, Aromatic Amines and Nitro Compounds