Dimethyl 5-nitroisophthalate
- CAS No.
- 13290-96-5
- Chemical Name:
- Dimethyl 5-nitroisophthalate
- Synonyms
- 5-NITROISOPHTHALIC ACID DIMETHYL ESTER;Dimethyl- 5–Nitroisophathalate;5-NIPA-DME;Iohexol Impurity R;Dimethyl-5-nitrophthalate;DIMETHYLNITROISOPHTHALATE-5;Dimethyl-5itroisophathalate;DIMETHYL 5-NITROISOPHTHALATE;Dimethyl5-Nitromisophthalate;5-NITRO DIMETHYL ISOPHTHALATE
- CBNumber:
- CB9205602
- Molecular Formula:
- C10H9NO6
- Molecular Weight:
- 239.18
- MDL Number:
- MFCD00008429
- MOL File:
- 13290-96-5.mol
- MSDS File:
- SDS
| Melting point | 123-125 °C (lit.) |
|---|---|
| Boiling point | 381.83°C (rough estimate) |
| Density | 1.4504 (rough estimate) |
| refractive index | 1.5310 (estimate) |
| storage temp. | Sealed in dry,Room Temperature |
| solubility | soluble in Toluene |
| form | powder to crystal |
| color | White to Light yellow |
| BRN | 2140916 |
| InChI | InChI=1S/C10H9NO6/c1-16-9(12)6-3-7(10(13)17-2)5-8(4-6)11(14)15/h3-5H,1-2H3 |
| InChIKey | GGTSJKFPGKFLCZ-UHFFFAOYSA-N |
| SMILES | C1(C(OC)=O)=CC([N+]([O-])=O)=CC(C(OC)=O)=C1 |
| CAS DataBase Reference | 13290-96-5(CAS DataBase Reference) |
| FDA UNII | AM7XSW83FE |
| NIST Chemistry Reference | 1,3-Benzenedicarboxylic acid, 5-nitro-, dimethyl ester(13290-96-5) |
| EPA Substance Registry System | Dimethyl 5-nitroisophthalate (13290-96-5) |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H302-H315-H319-H332-H335 | |||||||||
| Precautionary statements | P261-P280-P305+P351+P338 | |||||||||
| PPE | Eyeshields, Gloves, type N95 (US) | |||||||||
| Hazard Codes | Xn | |||||||||
| Risk Statements | 20/21/22 | |||||||||
| Safety Statements | 22-24/25-36 | |||||||||
| RIDADR | UN 2811 | |||||||||
| WGK Germany | 2 | |||||||||
| RTECS | CZ4340000 | |||||||||
| TSCA | TSCA listed | |||||||||
| HS Code | 29173990 | |||||||||
| Storage Class | 11 - Combustible Solids | |||||||||
| REACH Registrations | Active | |||||||||
| NFPA 704 |
|
Dimethyl 5-nitroisophthalate price More Price(47)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 237361 | Dimethyl 5-nitroisophthalate 98% | 13290-96-5 | 25g | $34.6 | 2023-06-20 | Buy |
| TCI Chemical | N0567 | Dimethyl 5-Nitroisophthalate | 13290-96-5 | 25g | $22 | 2026-04-30 | Buy |
| TCI Chemical | N0567 | Dimethyl 5-Nitroisophthalate | 13290-96-5 | 500g | $145 | 2026-04-30 | Buy |
| TRC | TRC-D480553-5G | Dimethyl 5-Nitroisophthalate | 13290-96-5 | 5g | $59 | 2026-06-03 | Buy |
| TRC | TRC-D480553-50G | Dimethyl 5-Nitroisophthalate | 13290-96-5 | 50g | $96 | 2026-06-03 | Buy |
Dimethyl 5-nitroisophthalate Chemical Properties,Uses,Production
Uses
Dimethyl 5-Nitroisophthalate is a useful chemical in organic synthesis.
Chemical Properties
slightly yellow fine crystalline powder
Uses
Dimethyl 5-nitroisophthalate has been used as starting reagent in the synthesis of 5-nitro-1,3-bis(ethylenediamine) and 5-nitroisophthaldihydrazide.
Synthesis
67-56-1
618-88-2
13290-96-5
In a 100 mL three-necked round-bottomed flask equipped with a condenser tube, an electric stirrer and a thermometer, 5.0 g of 5-nitroisophthalic acid and 33.3 mL of methanol were added sequentially. The mixture was stirred under nitrogen protection at room temperature for about 3 minutes until the solid was completely dissolved to give a colorless transparent solution. Subsequently, 1.0 mL of concentrated sulfuric acid was slowly added dropwise and heated to reflux, and after the reaction for about 3 hours, white solid precipitation was observed. The progress of the reaction was monitored by thin layer chromatography (TLC, unfolding agent ratio of dichloromethane:methanol=10:1). Upon completion of the reaction, it was cooled to room temperature, crystals were precipitated and the solid product was collected by filtration. The filter cake was washed with deionized water and finally mixed with a small amount of water and dried to obtain dimethyl 5-nitroisophthalate. The product yield was 98%.
References
[1] Patent: CN105254521, 2016, A. Location in patent: Paragraph 0025
[2] Journal of the Chemical Society, 1905, vol. 87, p. 1265
[3] Journal fuer Praktische Chemie (Leipzig), 1882, vol. <2> 25, p. 491
[4] Patent: US2005/281746, 2005, A1. Location in patent: Page/Page column 15-16
Dimethyl 5-nitroisophthalate Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hangzhou Yaoruiyicheng Biological Medicine Co., Ltd | 18317105404 | marketing002@witofly.com | China | 1600 | 58 |
| Shaanxi Kebele Pharmaceutical R&D Co., Ltd | 13119135307 | 3866620171@qq.com | China | 2660 | 58 |
| Shanghai Qiao Chemical Science Co., Ltd | 021-58892003 | info@qiaochem.com | China | 6065 | 65 |
| Shanghai Boyle Chemical Co., Ltd. | 021-50182298 021-50180596 | sales@boylechem.com | China | 2202 | 55 |
| Nanbu County Chengxin Technology Co., Ltd. | 0838-5675166 15883665058 | nbcxkj@126.com | China | 956 | 55 |
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
View Lastest Price from Dimethyl 5-nitroisophthalate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2026-09-11 | Dimethyl 5-nitroisophthalate
13290-96-5
|
$13.95 | 25Kg/Drum | 99.00%HPLC | 10tons/month | Asia Chem I and E (Jiangsu) Co Ltd | |
 |
2026-09-02 | Dimethyl 5-nitroisophthalate
13290-96-5
|
$1.00-100.00 | 1KG | 99% | Henan Fengda Chemical Co., Ltd | ||
 |
2026-05-28 | Dimethyl 5-Nitroisophthalate
13290-96-5
|
$2.00-5.00 | 1KG | 99% | 10000kg | Hebei Chuanghai Biotechnology Co,.LTD |
-
- Dimethyl 5-nitroisophthalate
13290-96-5
- $13.95
- 99.00%HPLC
- Asia Chem I and E (Jiangsu) Co Ltd
-
- Dimethyl 5-nitroisophthalate
13290-96-5
- $1.00-100.00
- 99%
- Henan Fengda Chemical Co., Ltd
-
- Dimethyl 5-Nitroisophthalate
13290-96-5
- $2.00-5.00
- 99%
- Hebei Chuanghai Biotechnology Co,.LTD
