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2-bromo-3-hexylthiophene

2-bromo-3-hexylthiophene structure

CAS No.: 69249-61-2

Chemical Name:: 2-bromo-3-hexylthiophene

Synonyms: DK888;S1151;TH6-Bra;2-Bromo-3-hexyL;2-Bromo-3-nonylthiophene;2-bromo-3-hexylthiophene;Thiophene,2-broMo-3-hexyl-;2-Bromo-3-hexylthiophene 97%;2-Bromo-3-hexylthiophene >69249-61-2 2-bromo-3-hexylthiophene

CBNumber:: CB9950397

Molecular Formula:: C10H15BrS

Molecular Weight:: 247.2

MDL Number:: MFCD09907959

MOL File:: 69249-61-2.mol

MSDS File:: SDS

TDS File:: TDS

Last updated:2026-05-28 05:22:37

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2-bromo-3-hexylthiophene Properties

Boiling point	75°C/0.5mmHg(lit.)
Density	1.240 g/mL at 25 °C
refractive index	n20/D 1.529
Flash point	110 °C
storage temp.	Keep in dark place,Sealed in dry,Room Temperature
form	clear liquid
color	Colorless to Light yellow to Light orange
Water Solubility	Slightly miscible with water.
InChI	InChI=1S/C10H15BrS/c1-2-3-4-5-6-9-7-8-12-10(9)11/h7-8H,2-6H2,1H3
InChIKey	XQJNXCHDODCAJF-UHFFFAOYSA-N
SMILES	C1(Br)SC=CC=1CCCCCC
UNSPSC Code	12352103
NACRES	NA.23

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS06

Signal word

Danger

Hazard statements

H301-H413

Precautionary statements

P273-P301+P310+P330

PPE

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Hazard Codes

Risk Statements

Safety Statements

RIDADR

UN 2810 6.1/PG 3

WGK Germany

HazardClass

6.1

PackingGroup

Ⅲ

HS Code

29349990

Storage Class

6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects

Hazard Classifications

Acute Tox. 3 Oral
Aquatic Chronic 4

NFPA 704

	1
2		0

2-bromo-3-hexylthiophene price More Price(70)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	691925	2-Bromo-3-hexylthiophene 97%	69249-61-2	5g	$171	2026-04-30	Buy
Sigma-Aldrich	691925	2-Bromo-3-hexylthiophene 97%	69249-61-2	1g	$56.1	2023-06-20	Buy
TCI Chemical	B3507	2-Bromo-3-hexylthiophene >98.0%(GC)	69249-61-2	5g	$117	2026-04-30	Buy
TCI Chemical	B3507	2-Bromo-3-hexylthiophene >98.0%(GC)	69249-61-2	25g	$360	2026-04-30	Buy
Usbiological	262021	2-Bromo-3-hexylthiophene Asreported	69249-61-2	50g	$842	2026-06-03	Buy

Product number	Packaging	Price	Buy
691925	5g	$171	Buy
691925	1g	$56.1	Buy
B3507	5g	$117	Buy
B3507	25g	$360	Buy
262021	50g	$842	Buy

2-bromo-3-hexylthiophene Chemical Properties,Uses,Production

Chemical Properties

Colorless to yellow liquid

Uses

2-Bromo-3-hexylthiophene is used in the synthesis of End-capped Regioregular Poly(3-hexylthiophene). It is also used to synthesize well-defined head-to-tail-type oligothiophenes which are used in a number of high-technology applications including OLEDs.

General Description

2-Bromo-3-hexylthiophene is a monomeric precursor that forms bromo terminate polymers. It is synthesized by the bromination of hexylthiophene.

Synthesis

1693-86-3

69249-61-2

General procedure for the synthesis of 2-bromo-3-hexylthiophene from 3-hexylthiophene: A 1 M solution of 3-hexylthiophene (8a) in DMF was cooled to 0 °C under light-avoidance conditions, followed by the addition of N-bromosuccinimide (NBS, 1.0 equiv). The reaction mixture was slowly warmed to room temperature with continuous stirring overnight. After completion of the reaction, the reaction solution was diluted with dichloromethane (DCM). The organic phase was washed sequentially with water and brine, the aqueous phase was combined and back-extracted with DCM. All organic phases were combined, dried with anhydrous magnesium sulfate (MgSO4) and concentrated under reduced pressure to remove the solvent. The crude product was purified by silica gel column chromatography (eluent: petroleum ether) to afford 2-bromo-3-hexylthiophene (7a) as a colorless oil in 99% yield.1H NMR (300.13 MHz, CDCl3) δ (ppm): 7.18 (d, 3J = 5.5 Hz, 1H, H-9), 6.79 (d, 3J = 5.5 Hz, 1H, H-8). 2.56 (t, 3J = 7.7 Hz, 2H, H-6), 1.63-1.51 (m, 2H, H-5), 1.40-1.24 (m, 6H, H-4 to H-2), 0.89 (t, 3J = 6.8 Hz, 3H, H-1).

References

[1] Organic and Biomolecular Chemistry, 2007, vol. 5, # 11, p. 1752 - 1763
[2] Patent: WO2015/15397, 2015, A1. Location in patent: Page/Page column 50
[3] Chemistry - A European Journal, 2014, vol. 20, # 49, p. 16128 - 16137
[4] Journal of Materials Chemistry, 2011, vol. 21, # 5, p. 1462 - 1469
[5] Journal of Polymer Science, Part A: Polymer Chemistry, 2011, vol. 49, # 9, p. 1933 - 1941

2-bromo-3-hexylthiophene Preparation Products And Raw materials

Raw materials

2,5-Dibromo-3-hexylthiophene N,N-Dimethylformamide 3-Hexylthiophene N-Bromosuccinimide

Preparation Products

2-bromo-3-hexylthiophene Suppliers

Global( 237)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Puyang Huicheng Electronic Material Co. Ltd.	0393-0393-8910800 15036113989	info@huichengchem.com	China	588	64
Shanghai Boyle Chemical Co., Ltd.		sales@boylechem.com	China	2915	55
J & K SCIENTIFIC LTD.	18210857532 18210857532	jkinfo@jkchemical.com	China	96815	76
Meryer (Shanghai) Chemical Technology Co., Ltd.	4006356688 18621169109	market03@meryer.com	China	40202	62
Alfa Aesar	400-6106006	saleschina@alfa-asia.com	China	30103	84
TCI (Shanghai) Development Co., Ltd.	021-67121386	Sales-CN@TCIchemicals.com	China	24512	81
Energy Chemical	400-0056266	sales8178@energy-chemical.com	China	44850	61
Accela ChemBio Co.,Ltd.	021-50795510 4000665055	marketing@accelachem.com	China	10972	64
Shanghai Hanhong Scientific Co.,Ltd.	021-54306202 13764082696	info@hanhongsci.com	China	42917	64
Beijing Isomersyn Technology CO;LTD	010-82954736 13391601435	sales@isomersyn.com	China	3294	57

Supplier	Advantage
Puyang Huicheng Electronic Material Co. Ltd.	64
Shanghai Boyle Chemical Co., Ltd.	55
J & K SCIENTIFIC LTD.	76
Meryer (Shanghai) Chemical Technology Co., Ltd.	62
Alfa Aesar	84
TCI (Shanghai) Development Co., Ltd.	81
Energy Chemical	61
Accela ChemBio Co.,Ltd.	64
Shanghai Hanhong Scientific Co.,Ltd.	64
Beijing Isomersyn Technology CO;LTD	57

View Lastest Price from 2-bromo-3-hexylthiophene manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2026-09-02	2-Bromo-3-hexylthiophene 69249-61-2	$1.00-200.00	1KG	99%, 99.5% Sublimated		Henan Fengda Chemical Co., Ltd
2026-08-20	2-bromo-3-hexylthiophene 69249-61-2	$1.10	1g	99.00%	100 Tons	Dideu Industries Group Limited
2021-10-16	2-bromo-3-hexylthiophene 69249-61-2	$10.00	1KG	99%	20 Tons	Hebei Zhanyao Biotechnology Co. Ltd

2-Bromo-3-hexylthiophene
69249-61-2
$1.00-200.00
99%, 99.5% Sublimated
Henan Fengda Chemical Co., Ltd

2-bromo-3-hexylthiophene
69249-61-2
$1.10
99.00%
Dideu Industries Group Limited

2-bromo-3-hexylthiophene
69249-61-2
$10.00
99%
Hebei Zhanyao Biotechnology Co. Ltd

2-bromo-3-hexylthiophene Spectrum

2-bromo-3-hexylthiophene(69249-61-2)¹HNMR

69249-61-2(2-bromo-3-hexylthiophene)Related Search:

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