| Company Name: |
Alfa Aesar |
| Tel: |
400-6106006 |
| Email: |
saleschina@alfa-asia.com |
- 2-Methylpiperidine
-
- $7.00
-
2020-02-13
- CAS: 109-05-7
- Min. Order: 1KG
- Purity: 99%
- Supply Ability: 100KG
|
| | 2-Methylpiperidine Basic information |
| | 2-Methylpiperidine Chemical Properties |
| Melting point | -4--5 °C | | Boiling point | 118-119 °C/753 mmHg (lit.) | | density | 0.844 g/mL at 25 °C (lit.) | | refractive index | n20/D 1.446(lit.) | | FEMA | 4244 | 2-METHYLPIPERIDINE | | Fp | 47 °F | | storage temp. | Flammables area | | form | Liquid | | pka | pK1:10.95(+1) (25°C) | | color | Clear yellow | | PH | 12-13 (111g/l, H2O) | | Odor | at 1.00 % in propylene glycol. amine fishy seafood taco corn chip | | Odor Type | ammoniacal | | biological source | synthetic | | Water Solubility | soluble | | JECFA Number | 1608 | | BRN | 79804 | | InChI | 1S/C6H13N/c1-6-4-2-3-5-7-6/h6-7H,2-5H2,1H3 | | InChIKey | NNWUEBIEOFQMSS-UHFFFAOYSA-N | | SMILES | CC1CCCCN1 | | LogP | 1.42 | | CAS DataBase Reference | 109-05-7(CAS DataBase Reference) | | NIST Chemistry Reference | 2-Methylpiperidine(109-05-7) | | EPA Substance Registry System | Piperidine, 2-methyl- (109-05-7) |
| Hazard Codes | F,Xn | | Risk Statements | 11-36/37/38-34-22-41-37/38 | | Safety Statements | 16-26-39-45-36/37/39 | | RIDADR | UN 1993 3/PG 2 | | WGK Germany | 3 | | RTECS | TN1240000 | | TSCA | TSCA listed | | HazardClass | 3 | | PackingGroup | II | | HS Code | 29333999 | | Storage Class | 3 - Flammable liquids | | Hazard Classifications | Acute Tox. 3 Dermal Acute Tox. 3 Inhalation Acute Tox. 4 Oral Eye Dam. 1 Flam. Liq. 2 Skin Corr. 1B |
| | 2-Methylpiperidine Usage And Synthesis |
| Chemical Properties | Colorless to yellow liquid; pepper-like aroma. | | Uses | 2-Methylpiperidine, is used for the oxidation of secondary amines to nitrones by means of H2O2 catalyzed by Sodium tungsten oxide dihydrate. | | Uses | Reactant for C-2 arylation of piperidines through directed transition metal-catalyzed sp3 C-H activation Reactant for synthesis of: Azepan-4-ones via two step [5+2] annulation 2-Aminobenzoxazoles Unsymmetrically substituted ureas Corticotropin-releasing factor receptor type 1 antagonists Gefitinib analogues with anti-tumor activity | | Definition | ChEBI: 2-Methylpiperidine is a member of piperidines. | | Aroma threshold values | High strength; ammoniacal type; recommend smelling in a 1.0% solution or less. | | Taste threshold values | Amine, creamy, taco, lettuce taste at 5 ppm in water. | | Synthesis Reference(s) | Journal of the American Chemical Society, 111, p. 4108, 1989 DOI: 10.1021/ja00193a056 |
| | 2-Methylpiperidine Preparation Products And Raw materials |
|