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2-Methylpiperidine

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2-Methylpiperidine manufacturers

  • 2-Methylpiperidine
  • 2-Methylpiperidine pictures
  • $7.00
  • 2020-02-13
  • CAS: 109-05-7
  • Min. Order: 1KG
  • Purity: 99%
  • Supply Ability: 100KG
2-Methylpiperidine Basic information
Product Name:2-Methylpiperidine
Synonyms:2-PIPECOLINE 99.5%;2-PIPECOLINE 2-METHYL PIPERIDINE;α-Pipecoline, 2-Pipecoline;DL-2-Methylpiperidine;2-METHYL-PERIDINE;2-Methylpiperidine, 99% 100ML;2-Methylpiperidine, 99% 5ML;D-A-PIPECOLINE
CAS:109-05-7
MF:C6H13N
MW:99.17
EINECS:203-642-1
Product Categories:Building Blocks;C5 to C7;Chemical Synthesis;Heterocyclic Building Blocks;Piperidines;Piperidine;K00001
Mol File:109-05-7.mol
2-Methylpiperidine Structure
2-Methylpiperidine Chemical Properties
Melting point -4--5 °C
Boiling point 118-119 °C/753 mmHg (lit.)
density 0.844 g/mL at 25 °C (lit.)
refractive index n20/D 1.446(lit.)
FEMA 4244 | 2-METHYLPIPERIDINE
Fp 47 °F
storage temp. Flammables area
form Liquid
pkapK1:10.95(+1) (25°C)
color Clear yellow
PH12-13 (111g/l, H2O)
Odorat 1.00 % in propylene glycol. amine fishy seafood taco corn chip
Odor Typeammoniacal
biological sourcesynthetic
Water Solubility soluble
JECFA Number1608
BRN 79804
InChI1S/C6H13N/c1-6-4-2-3-5-7-6/h6-7H,2-5H2,1H3
InChIKeyNNWUEBIEOFQMSS-UHFFFAOYSA-N
SMILESCC1CCCCN1
LogP1.42
CAS DataBase Reference109-05-7(CAS DataBase Reference)
NIST Chemistry Reference2-Methylpiperidine(109-05-7)
EPA Substance Registry SystemPiperidine, 2-methyl- (109-05-7)
Safety Information
Hazard Codes F,Xn
Risk Statements 11-36/37/38-34-22-41-37/38
Safety Statements 16-26-39-45-36/37/39
RIDADR UN 1993 3/PG 2
WGK Germany 3
RTECS TN1240000
TSCA TSCA listed
HazardClass 3
PackingGroup II
HS Code 29333999
Storage Class3 - Flammable liquids
Hazard ClassificationsAcute Tox. 3 Dermal
Acute Tox. 3 Inhalation
Acute Tox. 4 Oral
Eye Dam. 1
Flam. Liq. 2
Skin Corr. 1B
MSDS Information
ProviderLanguage
2-Pipecoline English
SigmaAldrich English
ACROS English
ALFA English
2-Methylpiperidine Usage And Synthesis
Chemical PropertiesColorless to yellow liquid; pepper-like aroma.
Uses2-Methylpiperidine, is used for the oxidation of secondary amines to nitrones by means of H2O2 catalyzed by Sodium tungsten oxide dihydrate.
UsesReactant for C-2 arylation of piperidines through directed transition metal-catalyzed sp3 C-H activation
Reactant for synthesis of:
Azepan-4-ones via two step [5+2] annulation
2-Aminobenzoxazoles
Unsymmetrically substituted ureas
Corticotropin-releasing factor receptor type 1 antagonists
Gefitinib analogues with anti-tumor activity
DefinitionChEBI: 2-Methylpiperidine is a member of piperidines.
Aroma threshold valuesHigh strength; ammoniacal type; recommend smelling in a 1.0% solution or less.
Taste threshold valuesAmine, creamy, taco, lettuce taste at 5 ppm in water.
Synthesis Reference(s)Journal of the American Chemical Society, 111, p. 4108, 1989 DOI: 10.1021/ja00193a056
2-Methylpiperidine Preparation Products And Raw materials
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