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(Dimethylsilylene)bis(2-methyl-4-phenylindenyl)zirconium dichloride manufacturers
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| | (Dimethylsilylene)bis(2-methyl-4-phenylindenyl)zirconium dichloride Basic information |
| Product Name: | (Dimethylsilylene)bis(2-methyl-4-phenylindenyl)zirconium dichloride | | Synonyms: | Rac-(Dimethylsilylene) Bis (2-Methyl-4-Phenylindenyl) Zirconium Dichloride;Dichloro[(dimethylsilylene)bis[(1,2,3,3a,7a-η)-2-methyl-4-phenyl-1H-inden-1-ylidene]]zirconium;ene) Bis (2-MethyL;Rac-(DimethyL;(Dimethylsilylene)bis(2-methyl-4-phenylindenyl)zircon;Dimethylsilylene)bis(2-methyl-4-phenylindenyl)zirconium dichloride | | CAS: | 158515-16-3 | | MF: | C34H30Cl2SiZr | | MW: | 628.82 | | EINECS: | | | Product Categories: | 1 | | Mol File: | 158515-16-3.mol |  |
| | (Dimethylsilylene)bis(2-methyl-4-phenylindenyl)zirconium dichloride Chemical Properties |
| InChI | InChI=1S/2C16H13.C2H6Si.2ClH.Zr/c2*1-12-10-14-8-5-9-15(16(14)11-12)13-6-3-2-4-7-13;1-3-2;;;/h2*2-11H,1H3;1-2H3;2*1H;/q2*-1;;;;+2/p-2 | | InChIKey | LKOFYLBQNPTWPS-UHFFFAOYSA-L |
| | (Dimethylsilylene)bis(2-methyl-4-phenylindenyl)zirconium dichloride Usage And Synthesis |
| Uses | Dimethylsilylene)bis(2-methyl-4-phenylindenyl)zirconium dichloride can be used as organic synthesis intermediate and pharmaceutical intermediate, mainly used in laboratory research and development process. | | Synthesis | To a solution of (2-methyl-4-phenylindenyl) silane ether / hexane = 1/1 (12.4 mmol) in 240 mL of n-butyllithium(2.5 M in hexane) was slowly added dropwise at -78 ° C. After that, the mixture was stirred at room temperature for one day, filtered and vacuum dried to obtain a pale yellow solid. A ligand salt synthesized in a glove box and bis (N, N'-diphenyl-1,3-propanediamido)Dichloro zirconium bis (tetrahydrofuran) was weighed in a Schlenk flask, ether was slowly added dropwise at -78 ° C, and the mixture was stirred at room temperature for one day.The red solution was separated by filtration, dried in vacuo, and a toluene / ether = 1/2 solution was added to obtain a clear red solution. 1.5-2 equivalents of HCl ether solution (1M) was slowly added dropwise at -78 ° C, followed by stirring at room temperature for 3 hours. After filtration and vacuum drying, (Dimethylsilylene)bis(2-methyl-4-phenylindenyl)zirconium dichloride was obtained in a yield of 70% (racemic only). | | storage | Pay attention to sealed storage, and the storage place should be cool and dry. Keep away from water. |
| | (Dimethylsilylene)bis(2-methyl-4-phenylindenyl)zirconium dichloride Preparation Products And Raw materials |
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