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Phenylsilane

Phenylsilane Suppliers list
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Products Intro: Product Name:Phenylsilane
CAS:694-53-1
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CAS:694-53-1
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Products Intro: Product Name:Phenylsilane
CAS:694-53-1
Purity:98%(Min,HPLC) Package:100g;1kg;5kg,10kg,25kg,50kg

Phenylsilane manufacturers

  • Phenylsilane
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  • CAS:694-53-1
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Phenylsilane Basic information
Product Name:Phenylsilane
Synonyms:Phenylsilane, 98% 25ML;Phenylsilane, 98% 5ML;Phenylsilane,98%;Phenylsilane≥ 98% (GC);PHENYLSILANE;Benzene, silyl-;Fenylsilan;phenyl-silan
CAS:694-53-1
MF:C6H8Si
MW:108.21
EINECS:211-772-5
Product Categories:Silane compounds;Reduction;Si (Classes of Silicon Compounds);Si-H Compounds;Synthetic Organic Chemistry;Organometallic Reagents;Organosilicon;Others
Mol File:694-53-1.mol
Phenylsilane Structure
Phenylsilane Chemical Properties
Melting point -64 to -68°C
Boiling point 120 °C (lit.)
density 0.877 g/mL at 25 °C (lit.)
refractive index n20/D 1.510(lit.)
Fp 45 °F
storage temp. Flammables area
form clear liquid
color Colorless to Almost colorless
Specific Gravity0.868
Water Solubility Contact with water releases a flammable alcohol. Soluble in water (Contact with water releases flammable gases), and most common organic solvents.
Sensitive Air & Moisture Sensitive
Hydrolytic Sensitivity7: reacts slowly with moisture/water
BRN 2935169
InChI1S/C6H8Si/c7-6-4-2-1-3-5-6/h1-5H,7H3
InChIKeyPARWUHTVGZSQPD-UHFFFAOYSA-N
SMILES[SiH3]c1ccccc1
CAS DataBase Reference694-53-1(CAS DataBase Reference)
EPA Substance Registry SystemSilane, phenyl- (694-53-1)
Safety Information
Hazard Codes F,Xn
Risk Statements 11-14/15-20/22-36/37/38
Safety Statements 16-43
RIDADR UN 3399 4.3/PG 2
WGK Germany 1
RTECS VV4825000
10-21
TSCA TSCA listed
HazardClass 4.3
PackingGroup II
HS Code 29319090
Storage Class4.3 - Hazardous materials which set free flammable gases upon contact with water
Hazard ClassificationsAcute Tox. 4 Inhalation
Acute Tox. 4 Oral
Eye Irrit. 2
Flam. Liq. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
Phenylsilane Usage And Synthesis
Chemical Propertiesclear colorless liquid, boiling point 119~121°C, density 0.878 g/ml, easily soluble in organic solvents. Upon heating, it decomposes, producing pungent, dense fumes and irritating substances. It reacts vigorously with water.
UsesPhenylsilane (PhSiH3) may be used as a reducing agent for the partial reduction of phosphine oxide groups in poly(4,4′-diphenylphenylphosphine oxide) (PAPO) to phosphine. It can also undergo photopolymerization with methyl methacrylate(MMA) to form poly(MMA) containing SiH groups. PhSiH3 may be used as a silicon source to synthesize crystalline Si nanowires via Au-nanocrystal-seeded supercritical fluid-liquid-solid (SFLS) synthesis.
ApplicationEmployed in the reduction of esters to ethers. Reduces α,β-unsaturated ketones to saturated ketones in the presence of tri-n-butyltin hydride. Reduces tin amides to tin hydrides. Used in the tin-catalyzed reduction of nitroalkanes to alkanes. Reduces α-halo ketones in presence of Mo(0).
DefinitionChEBI: Phenylsilane is an organosilicon compound that is benzene in which a hydrogen is replaced by a silyl group. It has a role as a reducing agent. It is an organosilicon compound and a member of benzenes.
Synthesis The method for preparing phenyl silane comprises the following steps: adding trichlorophenylsilane in a tetrahydrofuran solution dissolved with a catalyst, carrying out a reaction at the temperature of -10-0 ℃, after the completion of the reaction is monitored by a TLC method, adding the product into an inorganic acid dilute solution under an ice bath condition, and extracting an organic layer, to obtain phenyl silane.
Tag:Phenylsilane(694-53-1) Related Product Information
Phenyltriethoxysilane Phenyltrichlorosilane TRIS(TRIMETHYLSILOXY)PHENYLSILANE 99%,TRIS(TRIMETHYLSILOXY)PHENYLSILANE,M3T(Ph):tris(trimethylsiloxy)phenylsilan PHENYLSELENENYL CHLORIDE Trimethoxyphenylsilane PHENYLTHIOACETONITRILE Dichloromethylphenylsilane Chlorodimethylphenylsilane DIMETHYL(PENTAFLUOROPHENYL)SILANE tert-Butylchlorodiphenylsilane Triphenylsilyl chloride Dimethoxymethylphenylsilane Chlorodimethylpentafluorophenylsilane Octaphenylcyclotetrasiloxane Diphenylsilane DIPHENYLMETHYLSILANE Triphenylsilane Diphenylsilanediol