Silane

Silane, also known as silicon hydride, is a compound only contains silicon and hydrogen these two elements. There is the simplest representation of Silane such as Monosilane (SiH4), disilane (Si2H6), etc. And in the aspect of composition, structure and physical properties,there is a lot of similarities but also some differences. Silane is only containing homologues with a few silicon atoms. It is now known as a fact that the longest chain is Si6H14. Its chemical character is more active than alkane, for it’s easy for Si-H bond to break than the C-H bond. Because Si-H bond has not good heat-stability, it can be decomposed into silicon and hydrogen, and because of the big molecular weight, it lose its stability. SiH4 and Si2H6 are easy to spontaneous combustion in the air to produce water and SiO2, and also very easy to be hydrolyzed by alkali solution.

Alkyl-substituted silence possesses good thermal stability. For instance, (CH3)4Si not spontaneously ignite in air. At room temperature, the chemical reaction between silane and halogen would be processed by way of explosion. In the presence of a catalyst, silane is capable of generating hydrogen halide with a halogenating effect. However, it’s very difficult to synthesize silane, and it is still in the theoretical stage.

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Structure Chemical Name CAS MF
Triphenylsilyl chloride Triphenylsilyl chloride 76-86-8 C18H15ClSi
Allyltrimethylsilane Allyltrimethylsilane 762-72-1 C6H14Si
Iodotrimethylsilane Iodotrimethylsilane 16029-98-4 C3H9ISi
Chlorodimethylphenylsilane Chlorodimethylphenylsilane 768-33-2 C8H11ClSi
1,3-Dichloro-1,1,3,3-tetraisopropyldisiloxane 1,3-Dichloro-1,1,3,3-tetraisopropyldisiloxane 69304-37-6 C12H28Cl2OSi2
Vinyltrimethoxysilane Vinyltrimethoxysilane 2768-02-7 C5H12O3Si
(Trifluoromethyl)trimethylsilane (Trifluoromethyl)trimethylsilane 81290-20-2 C4H9F3Si
Trimethylsilyl cyanide Trimethylsilyl cyanide 7677-24-9 C4H9NSi
Diphenyldimethoxysilane Diphenyldimethoxysilane 6843-66-9 C14H16O2Si
Trimethylsilyl trifluoromethanesulfonate Trimethylsilyl trifluoromethanesulfonate 27607-77-8 C4H9F3O3SSi
N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine 93102-05-7 C13H23NOSi
N-[3-(Trimethoxysilyl)propyl]ethylenediamine N-[3-(Trimethoxysilyl)propyl]ethylenediamine 1760-24-3 C8H22N2O3Si
Trimethylsilylacetylene Trimethylsilylacetylene 1066-54-2 C5H10Si
Azidotrimethylsilane Azidotrimethylsilane 4648-54-8 C3H9N3Si
Triisopropylsilyl chloride Triisopropylsilyl chloride 13154-24-0 C9H21ClSi
2-(Trimethylsilyl)ethanol 2-(Trimethylsilyl)ethanol 2916-68-9 C5H14OSi
tert-Butyldimethylsilyl chloride tert-Butyldimethylsilyl chloride 18162-48-6 C6H15ClSi
Methyltriethoxysilane Methyltriethoxysilane 2031-67-6 C7H18O3Si
Chlorodimethylsilane Chlorodimethylsilane 1066-35-9 C2H7ClSi
Octyltrichlorosilane Octyltrichlorosilane 5283-66-9 C8H17Cl3Si
Trimethoxysilane Trimethoxysilane 2487-90-3 C3H10O3Si
Bis(trimethylsilyl)acetylene Bis(trimethylsilyl)acetylene 14630-40-1 C8H18Si2
Hexamethyldisilane Hexamethyldisilane 1450-14-2 C6H18Si2
Vinyl tris(2-methoxyethoxy) silane Vinyl tris(2-methoxyethoxy) silane 1067-53-4 C11H24O6Si
Triphenylsilane Triphenylsilane 789-25-3 C18H16Si
1-(Trimethylsilyl)-1-propyne 1-(Trimethylsilyl)-1-propyne 6224-91-5 C6H12Si
Vinyltrimethylsilane Vinyltrimethylsilane 754-05-2 C5H12Si
(IODOMETHYL)TRIMETHYLSILANE (IODOMETHYL)TRIMETHYLSILANE 4206-67-1 C4H11ISi
Phenyltriethoxysilane Phenyltriethoxysilane 780-69-8 C12H20O3Si
Diphenylsilane Diphenylsilane 775-12-2 C12H12Si
Tetramethylsilane Tetramethylsilane 75-76-3 C4H12Si
1,2-Bis(chlorodimethylsilyl)ethane 1,2-Bis(chlorodimethylsilyl)ethane 13528-93-3 C6H16Cl2Si2
Trimethoxysilylpropanethiol Trimethoxysilylpropanethiol 4420-74-0 C6H16O3SSi
Tetramethyl orthosilicate Tetramethyl orthosilicate 681-84-5 C4H12O4Si
N-OCTADECYLTRICHLOROSILANE N-OCTADECYLTRICHLOROSILANE 112-04-9 C18H37Cl3Si
(TRIETHYLSILYL)ACETYLENE (TRIETHYLSILYL)ACETYLENE 1777-03-3 C8H16Si
Ethoxytrimethylsilane Ethoxytrimethylsilane 1825-62-3 C5H14OSi
Chloromethyltrimethylsilane Chloromethyltrimethylsilane 2344-80-1 C4H11ClSi
Triisopropylsilane Triisopropylsilane 6485-79-6 C9H22Si
Ethyl (trimethylsilyl)acetate Ethyl (trimethylsilyl)acetate 4071-88-9 C7H16O2Si
Triethoxyoctylsilane Triethoxyoctylsilane 2943-75-1 C14H32O3Si
Trichlorovinylsilane Trichlorovinylsilane 75-94-5 C2H3Cl3Si
3-Aminopropyltrimethoxysilane 3-Aminopropyltrimethoxysilane 13822-56-5 C6H17NO3Si
N-(Trimethylsilyl)acetamide N-(Trimethylsilyl)acetamide 13435-12-6 C5H13NOSi
Diethoxydimethylsilane Diethoxydimethylsilane 78-62-6 C6H16O2Si
Sodium bis(trimethylsilyl)amide Sodium bis(trimethylsilyl)amide 1070-89-9 C6H18NNaSi2
Triethylsilane Triethylsilane 617-86-7 C6H16Si
3-Aminopropyltriethoxysilane 3-Aminopropyltriethoxysilane 919-30-2 C9H23NO3Si
3-Isocyanatopropyltriethoxysilane 3-Isocyanatopropyltriethoxysilane 24801-88-5 C10H21NO4Si
3-Chloropropyltrimethoxysilane 3-Chloropropyltrimethoxysilane 2530-87-2 C6H15ClO3Si
Divinyltetramethyldisiloxane Divinyltetramethyldisiloxane 2627-95-4 C8H18OSi2
tert-Butylchlorodiphenylsilane tert-Butylchlorodiphenylsilane 58479-61-1 C16H19ClSi
3-Mercaptopropyltriethoxysilane 3-Mercaptopropyltriethoxysilane 14814-09-6 C9H22O3SSi
Bromotrimethylsilane Bromotrimethylsilane 2857-97-8 C3H9BrSi
Trimethoxypropylsilane Trimethoxypropylsilane 1067-25-0 C6H16O3Si
(Triisopropylsilyl)acetylene (Triisopropylsilyl)acetylene 89343-06-6 C11H22Si
3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE 3-BROMO-1-(TRIMETHYLSILYL)-1-PROPYNE 38002-45-8 C6H11BrSi
Mono- and dihydroxysilanes Mono- and dihydroxysilanes
Chloro(chloromethyl)dimethylsilane Chloro(chloromethyl)dimethylsilane 1719-57-9 C3H8Cl2Si
N,N-Dimethyltrimethylsilylamine N,N-Dimethyltrimethylsilylamine 2083-91-2 C5H15NSi
T-BUTYLDICHLOROSILANE T-BUTYLDICHLOROSILANE 85121-42-2 C4H10Cl2Si
N-TRIMETHOXYSILYLPROPYL-N,N,N-TRIMETHYLAMMONIUM CHLORIDE N-TRIMETHOXYSILYLPROPYL-N,N,N-TRIMETHYLAMMONIUM CHLORIDE 35141-36-7 C9H24ClNO3Si
Phenylsilane Phenylsilane 694-53-1 C6H8Si
Dimethoxymethylphenylsilane Dimethoxymethylphenylsilane 3027-21-2 C9H14O2Si
hexamethyl diorthosilicate hexamethyl diorthosilicate 4371-91-9 C6H18O7Si2
Triphenylsilanol Triphenylsilanol 791-31-1 C18H16OSi
Dimethyldimethoxysilane Dimethyldimethoxysilane 1112-39-6 C4H12O2Si
1,1'-(11aS)-dibenzo[d,f][1,3]dioxepin-1,11-diylbis[1,1-diphenylPhosphine 1,1'-(11aS)-dibenzo[d,f][1,3]dioxepin-1,11-diylbis[1,1-diphenylPhosphine 486429-92-9 C37H28O2P2
Octadecyltrimethoxysilane Octadecyltrimethoxysilane 3069-42-9 C21H46O3Si
3-(METHACRYLOYLOXY)PROPYLTRIS(TRIMETHYLSILOXY)SILANE 3-(METHACRYLOYLOXY)PROPYLTRIS(TRIMETHYLSILOXY)SILANE 17096-07-0 C16H38O5Si4
1-(2-pyridinyl)[1,3]thiazolo[5,4-b]pyridine-2(1H)-thione 1-(2-pyridinyl)[1,3]thiazolo[5,4-b]pyridine-2(1H)-thione 85877-80-1 C11H7N3S2
Chloromethyldichloromethylsilane Chloromethyldichloromethylsilane 1558-33-4 C2H5Cl3Si
N-BUTYLDIMETHYLCHLOROSILANE N-BUTYLDIMETHYLCHLOROSILANE 1000-50-6 C6H15ClSi
(3S)-4-Chloro-3-[(triMethylsilyl)oxy]butanenitrile (3S)-4-Chloro-3-[(triMethylsilyl)oxy]butanenitrile 727382-14-1 C7H14ClNOSi
TRIMETHYLSILYL TRIFLUOROACETATE TRIMETHYLSILYL TRIFLUOROACETATE 400-53-3 C5H9F3O2Si
1,3-Bis(chloromethyl)-1,1,3,3-tetramethyldisiloxane 1,3-Bis(chloromethyl)-1,1,3,3-tetramethyldisiloxane 2362-10-9 C6H16Cl2OSi2
(Dichlorofluoromethyl)trimethylsilane (Dichlorofluoromethyl)trimethylsilane 90503-30-3 C4H9Cl2FSi
Methylphenyldiethoxysilane Methylphenyldiethoxysilane 775-56-4 C11H18O2Si
Diethoxymethylsilane Diethoxymethylsilane 2031-62-1 C5H14O2Si
Triethylvinylsilane Triethylvinylsilane 1112-54-5 C8H18Si
3-(Triethoxysilyl)propyl methacrylate 3-(Triethoxysilyl)propyl methacrylate 21142-29-0 C13H26O5Si
1-TRIMETHYLSILYLMETHANOL 1-TRIMETHYLSILYLMETHANOL 3219-63-4 C4H12OSi
DIMETHYLKETENE METHYL TRIMETHYLSILYL ACETAL DIMETHYLKETENE METHYL TRIMETHYLSILYL ACETAL 31469-15-5 C8H18O2Si
Trimethylsilyl Isocyanate Trimethylsilyl Isocyanate 1118-02-1 C4H9NOSi
PHENYLTHIOTRIMETHYLSILANE PHENYLTHIOTRIMETHYLSILANE 4551-15-9 C9H14SSi
TRIPHENYLVINYLSILANE TRIPHENYLVINYLSILANE 18666-68-7 C20H18Si
DODECYLTRICHLOROSILANE DODECYLTRICHLOROSILANE 4484-72-4 C12H25Cl3Si
3-Mercaptopropylmethyldimethoxysilane 3-Mercaptopropylmethyldimethoxysilane 31001-77-1 C6H16O2SSi
(1-BROMOVINYL)TRIMETHYLSILANE (1-BROMOVINYL)TRIMETHYLSILANE 13683-41-5 C5H11BrSi
DIETHYLSILANE DIETHYLSILANE 542-91-6 C4H12Si
(Triacetoxy)ethylsilane (Triacetoxy)ethylsilane 17689-77-9 C8H14O6Si
(TRIMETHYLSILYL)METHYL TRIFLUOROMETHANESULFONATE (TRIMETHYLSILYL)METHYL TRIFLUOROMETHANESULFONATE 64035-64-9 C5H11F3O3SSi
N-DECYLDIMETHYLCHLOROSILANE N-DECYLDIMETHYLCHLOROSILANE 38051-57-9 C12H27ClSi
N-OCTADECYLTRIETHOXYSILANE N-OCTADECYLTRIETHOXYSILANE 7399-00-0 C24H52O3Si
4-(Trimethylsilyl)-3-butyn-2-one 4-(Trimethylsilyl)-3-butyn-2-one 5930-98-3 C7H12OSi
ALLYLTRICHLOROSILANE ALLYLTRICHLOROSILANE 107-37-9 C3H5Cl3Si
DIISOPROPYLDICHLOROSILANE DIISOPROPYLDICHLOROSILANE 7751-38-4 C6H14Cl2Si
DIPHENYLMETHYLSILANE DIPHENYLMETHYLSILANE 776-76-1 C13H14Si
n-Octyldimethylchlorosilane n-Octyldimethylchlorosilane 18162-84-0 C10H23ClSi
(2-BROMOETHOXY)-TERT-BUTYLDIMETHYLSILANE (2-BROMOETHOXY)-TERT-BUTYLDIMETHYLSILANE 86864-60-0 C8H19BrOSi
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