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Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium (II) dichloride

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Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium (II) dichloride manufacturers

Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium (II) dichloride Basic information
Uses
Product Name:Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium (II) dichloride
Synonyms:BATHOPHENANTHROLINE RUTHENIUM CHLORIDE;BATHOPHENANTHROLINE RUTHENIUM DICHLORIDE;TRIS(4,7-DIPHENYLPHENANTHROLIN)RUTHENIUM(II) CL2 COMPLEX*;TRIS-(BATHOPHENANTHROLINE) RUTHENIUM (II) CHLORIDE;TRIS(4,7-DIPHENYL-1,10-PHENANTHROLINE) RUTHENIUM (II) CHLORIDE;TRIS(4,7-DIPHENYL-1,10-PHENANTHROLIN)RUTHENIUM DICHLORIDE COMPLEX;TRIS(4,7-DIPHENYL-1,10-PHENANTHROLIN)RUTHENIUM(II) DICHLORIDE COMPLEX;Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium(II) dichloride complex
CAS:36309-88-3
MF:C72H48Cl2N6Ru
MW:1169.17
EINECS:
Product Categories:electronic
Mol File:36309-88-3.mol
Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium (II) dichloride Structure
Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium (II) dichloride Chemical Properties
Melting point 275-279°C (dec.)
Fp >110°C
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
solubility DMF: soluble
form Powder
color Light yellow to orange
Water Solubility Soluble in alcohol and dimethylformamide. Insoluble in water.
InChIInChI=1S/3C24H16N2.2ClH.Ru/c3*1-3-7-17(8-4-1)19-13-15-25-23-21(19)11-12-22-20(14-16-26-24(22)23)18-9-5-2-6-10-18;;;/h3*1-16H;2*1H;/q;;;;;+2/p-2
InChIKeySKZWFYFFTOHWQP-UHFFFAOYSA-L
CAS DataBase Reference36309-88-3(CAS DataBase Reference)
Safety Information
Risk Statements 34
Safety Statements 24/25
RIDADR 3261
WGK Germany 3
F 8-10
TSCA No
HS Code 29339900
Storage Class13 - Non Combustible Solids
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium (II) dichloride Usage And Synthesis
UsesTris(4,7-diphenyl-1,10-phenanthroline)ruthenium(II) dichloride complex is a luminescent oxygen probe.
DescriptionTris(4,7-diphenyl-1,10-phenanthroline)ruthenium II dichloride complex is a luminescent probe (absorption λmax: 455 nm, luminescence λmax: 613 nm) widely used for detection and quantitation of oxygen. The dye is strongly reduced by molecular oxygen as a result of dynamic quenching; thus oxygen detection can be based on either measurement of intensity or decay time. This oxygen probe has been used to optimize optical oxygen sensors, to measure oxygen flux through tissues and in skin tumors, and for oxygen imaging.
UsesTris(4,7-diphenyl-1,10-phenanthroline)ruthenium(II) dichloride complex is a luminescent oxygen probe.
References[1] H. . KIM. Synthesis of tris (4,7 -diphenyl -1,10 -phenanthroline )ruthenium (II) complexes possessing a linker arm for use in sol-gel-based optical oxygen sensor[J]. Bulletin of The Korean Chemical Society, 2006, 3 1: 2084-2086. DOI: 10.5012/bkcs.2006.27.12.2084
[2] PAUL. HARTMANN  Max E L  Marc J P Leiner. Luminescence Quenching Behavior of an Oxygen Sensor Based on a Ru(II) Complex Dissolved in Polystyrene[J]. Analytical Chemistry, 1995, 67 1: 88-93. DOI: 10.1021/ac00097a015
[3] WL RUMSEY  DF W  JM Vanderkooi. Imaging of phosphorescence: a novel method for measuring oxygen distribution in perfused tissue[J]. Science, 1988, 241 4873. DOI: 10.1126/science.241.4873.1649
[4] G. LIEBSCH. Luminescence Lifetime Imaging of Oxygen, pH, and Carbon Dioxide Distribution Using Optical Sensors[J]. Applied Spectroscopy, 2000, 1 1: 548-559. DOI: 10.1366/0003702001949726
[5] J. R. BACON  J. N D. Determination of oxygen concentrations by luminescence quenching of a polymer-immobilized transition-metal complex[J]. Analytical Chemistry, 1987, 59 23: 2780-2785. DOI: 10.1021/ac00150a012
[6] INGO. KLIMANT  Otto S W. Oxygen-Sensitive Luminescent Materials Based on Silicone-Soluble Ruthenium Diimine Complexes[J]. Analytical Chemistry, 1995, 67 18: 3160-3166. DOI: 10.1021/ac00114a010
Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium (II) dichloride Preparation Products And Raw materials
Tag:Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium (II) dichloride(36309-88-3) Related Product Information
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