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Boc-Tyr-OtBu

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Company Name: Energy Chemical  
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Boc-Tyr-OtBu manufacturers

  • Boc-Tyr-Otbu
  • Boc-Tyr-Otbu pictures
  • 2026-09-11
  • CAS:18938-60-8
  • Min. Order: 1kg
  • Purity: 98%
  • Supply Ability: 1T
  • Boc-Tyr-OtBu
  • Boc-Tyr-OtBu pictures
  • $9.80
  • 2020-01-09
  • CAS:18938-60-8
  • Min. Order: 1g
  • Purity: ≥99%
  • Supply Ability: 100kg
Boc-Tyr-OtBu Basic information
Product Name:Boc-Tyr-OtBu
Synonyms:Boc-Tyr-OtBu;(S)-2-[(tert-Butoxycarbonyl)amino]-3-(4-hydroxyphenyl)propionic acid tert-butyl ester;Boc-L-tyrosine tert-butyl ester;N-[(1,1-Dimethylethoxy)carbonyl]-L-tyrosine 1,1-dimethylethyl ester;L-Tyrosine, N-[(1,1-dimethylethoxy)carbonyl]-, 1,1-dimethylethyl ester;(Tert-Butoxy)Carbonyl Tyr-OtBu;tert-butyl (2S)-2-{[(tert-butoxy)carbonyl]amino}-3-(4-hydroxyphenyl)propanoate;N-Boc-L-tyrosine tert-Butyl Ester
CAS:18938-60-8
MF:C18H27NO5
MW:337.41
EINECS:
Product Categories:
Mol File:18938-60-8.mol
Boc-Tyr-OtBu Structure
Boc-Tyr-OtBu Chemical Properties
Melting point 111-112 °C(Solv: ligroine (8032-32-4); ethyl acetate (141-78-6))
Boiling point 476.0±40.0 °C(Predicted)
density 1.117±0.06 g/cm3(Predicted)
storage temp. 2-8°C
form Solid
pka9.75±0.15(Predicted)
color White to off-white
Optical RotationConsistent with structure
Safety Information
MSDS Information
Boc-Tyr-OtBu Usage And Synthesis
UsesBoc-Tyr-OtBu is a tyrosine derivative[1].
Synthesis
Di-tert-butyl dicarbonate

24424-99-5

tert-Butyl L-tyrosinate

16874-12-7

Boc-Tyr-OtBu

18938-60-8

To a solution of 9.82 g (0.041 mol) tert-butyl L-tyrosinate in 150 mL of dichloromethane and 20 mL of DMF was added 5.2 g (0.04 mol) of triethylamine, followed by 9.03 g (0.04 mol) of di-tert-butyl dicarbonate. The reaction mixture was stirred at room temperature for 2 h. Upon completion of the reaction, it was washed sequentially with 1N HCl (3 × 50 mL), saturated NaHCO3 solution (1 × 50 mL), and brine (1 × 50 mL). The organic phase was dried with anhydrous magnesium sulfate, filtered and concentrated in vacuum to give 13.59 g (98% yield) of white solid product. The structure of the product was confirmed by 300 MHz 1H NMR (CDCl3): δ 1.42 (s, 18H), 2.95 (d, 2H), 4.39 (dd, 1H), 5.01 (d, 1H), 6.15 (s, 1H), 6.70 (d, 2H), 7.00 (d, 2H).

References[1] Luckose F, et al. Effects of amino acid derivatives on physical, mental, and physiological activities. Crit Rev Food Sci Nutr. 2015;55(13):1793-1144. DOI:10.1080/10408398.2012.708368
Boc-Tyr-OtBu Preparation Products And Raw materials
Raw materialsDi-tert-butyl dicarbonate-->tert-Butyl L-tyrosinate-->DMF ( N,N-DIMETHYLFORMAMIDE )-->Dichloromethane-->Triethylamine
Preparation ProductsBOC-L-Tyrosine
Tag:Boc-Tyr-OtBu(18938-60-8) Related Product Information
L(+)-Arginine L-Tryptophan 1-[[4-[(4-Fluoro-2-methyl-1H-indol-5-yl)oxy]-5-methylpyrrolo[2,1-f][1,2,4]triazin-6-yl]oxy]-2-propanol BOC-SER(TOS)-OCH3 BOC-D-TYR(TBU)-OH BOC-DL-PRO-OH Methyl N-(tert-butoxycarbonyl)-L-threoninate N-Boc-4-oxo-L-Proline methyl ester BOC-TRP(BOC)-OH Boc-D-Ser(tBu)-OH