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| | 3,5-Dimethoxybenzylamine Basic information |
| | 3,5-Dimethoxybenzylamine Chemical Properties |
| Melting point | 35-37 °C (lit.) | | Boiling point | 94-96 °C/0.1 mmHg (lit.) | | density | 1.106 g/mL at 25 °C (lit.) | | refractive index | n20/D 1.542(lit.) | | Fp | >230 °F | | storage temp. | Keep in dark place,Inert atmosphere,2-8°C | | pka | 9.01±0.10(Predicted) | | form | powder to lump | | color | White to Light yellow | | Water Solubility | Slightly soluble in water. | | λmax | 281nm(EtOH)(lit.) | | InChI | 1S/C9H13NO2/c1-11-8-3-7(6-10)4-9(5-8)12-2/h3-5H,6,10H2,1-2H3 | | InChIKey | YGZJTYCCONJJGZ-UHFFFAOYSA-N | | SMILES | COc1cc(CN)cc(OC)c1 | | CAS DataBase Reference | 34967-24-3(CAS DataBase Reference) |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26-37/39 | | RIDADR | 3259 | | WGK Germany | 3 | | HazardClass | 8 | | HazardClass | IRRITANT | | PackingGroup | III | | HS Code | 29222990 | | Storage Class | 11 - Combustible Solids | | Hazard Classifications | Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| | 3,5-Dimethoxybenzylamine Usage And Synthesis |
| Chemical Properties | Colorless to light yellow liqui | | Uses | 3,5-Dimethoxybenzylamine was used in the preparation of trisammonium tris(hexafluoro phosphate) salt. It was also used in the synthesis of well defined, homogeneous [n]rotaxanes (n up to 11) by a template-directed thermodynamic clipping approach. | | Synthesis Reference(s) | Tetrahedron Letters, 35, p. 6207, 1994 DOI: 10.1016/S0040-4039(00)73392-2 | | General Description | 3,5-Dimethoxybenzylamine was prepared by LiAlH4-reduction of 3,5-dimethoxybenzaldoxime. | | Synthesis | 7 mmol of 3,5-dimethoxybenzaldehyde, 70 mL of methanol solution of ammonia at a concentration of 2 mol/L, and 140 mg of murrayne-encapsulated nickel-nickel oxide catalyst were mixed and added to an autoclave reactor, and then hydrogen was passed in, and the hydrogen pressure of the system was controlled to be 2 MPa, the stirring rate was 800 rpm, and the reaction was carried out at 90 C for 4 h. 3,5-dimethoxybenzylamine was obtained (the yield was 95%). |
| | 3,5-Dimethoxybenzylamine Preparation Products And Raw materials |
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