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| | 4,4',4''-Tris(carbazol-9-yl)-triphenylamine Basic information | | Applications |
| Product Name: | 4,4',4''-Tris(carbazol-9-yl)-triphenylamine | | Synonyms: | 4,4',4''-TRIS(CARBAZOL-9-YL)TRIPHENYLAMINE;TCATA;Tris[4-(carbazol-9-yl)phenyl]amine;Tris(4-carbazoyl-9-ylphenyl)amine;4,4',4''-Tri-9-carbazolyltriphenylamine;TCTA,4,4',4''-Tris(carbazol-9-yl)-triphenylaMine;tris(4-(9H-carbazol-9-yl)phenyl)amine;4,4',4''-Tris(carbaz | | CAS: | 139092-78-7 | | MF: | C54H36N4 | | MW: | 740.89 | | EINECS: | 625-738-6 | | Product Categories: | OLED materials,pharm chemical,electronic;oled materials;electronic;Electronic Chemicals;White powder;OLED | | Mol File: | 139092-78-7.mol |  |
| | 4,4',4''-Tris(carbazol-9-yl)-triphenylamine Chemical Properties |
| Melting point | 298~300°C | | density | 1.23±0.1 g/cm3(Predicted) | | storage temp. | Inert atmosphere,Room Temperature | | solubility | THF: soluble
chloroform: soluble
dichloromethane: soluble | | form | powder to crystal | | pka | -5.97±0.60(Predicted) | | color | White to Orange to Green | | λmax | 326nm(CH2Cl2)(lit.) | | InChIKey | AWXGSYPUMWKTBR-UHFFFAOYSA-N | | SMILES | C1(N(C2=CC=C(N3C4=C(C=CC=C4)C4=C3C=CC=C4)C=C2)C2=CC=C(N3C4=C(C=CC=C4)C4=C3C=CC=C4)C=C2)=CC=C(N2C3=C(C=CC=C3)C3=C2C=CC=C3)C=C1 | | CAS DataBase Reference | 139092-78-7 | | Absorption | λmax293and326 nm (THF) |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26-36/37-36 | | WGK Germany | 3 | | HS Code | 29339900 | | Storage Class | 11 - Combustible Solids | | Hazard Classifications | Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| | 4,4',4''-Tris(carbazol-9-yl)-triphenylamine Usage And Synthesis |
| Applications | Having three carbazole units as the pendants and triarylamine at the core, tris(4-carbazoyl-9-ylphenyl)amine (TCTA) is electron-rich. As a result, it is widely used as a hole-transport and hole-injection material in light-emitting diodes and perovskite solar cells. With low electron mobility, TCTA has also been used as exciton/electron blocking layer materials because of its high lying LUMO energy level (LUMO = 2.4 eV).
TCTA is also a very popular phosphorescent host material due to its large band gap (Eg = 3.4 eV) for green, red and white phosphorescent organic light-emitting diodes (PhOLEDs).
| | Description | Having three carbazole units as the pendants and triarylamine at the core,tris(4-carbazoyl-9-ylphenyl)amine (TCTA) is electron-rich. As a result, it is widely used as a hole-transport and hole-injection material in light-emitting diodes and perovskite solar cells. With low electron mobility, TCTA has also been used as exciton/electron blocking layer materials because of its high lying LUMO energy level (LUMO = 2.4 eV). | | Chemical Properties | Light yellow solid | | Uses | 4,4'',4''''-Tris(carbazol-9-yl)-triphenylamine has been patented for use in the preparation of light-emitting materials for organic electroluminescent devices. |
| | 4,4',4''-Tris(carbazol-9-yl)-triphenylamine Preparation Products And Raw materials |
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