ChemicalBook > Product Catalog >Chemical Reagents >Organic reagents >Phosphine ligand >(S)-(-)-7,7'-BIS[DI(3,5-DIMETHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE

(S)-(-)-7,7'-BIS[DI(3,5-DIMETHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE

(S)-(-)-7,7'-BIS[DI(3,5-DIMETHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE Suppliers list
Company Name: Dayang Chem (Hangzhou) Co.,Ltd.
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Products Intro: Product Name:(S)-(-)-7,7'-BIS[DI(3,5-DIMETHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE
CAS:528521-89-3
Purity:0.95&0.99 Package:0.1KG;1KG;1000KG Remarks:Wholesale price
Company Name: PT CHEM GROUP LIMITED
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Products Intro: Product Name:(S)-(-)-7,7'-BIS[DI(3,5-DIMETHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE
CAS:528521-89-3
Purity:0.95&0.99 Package:0.1KG;1KG;1000KG Remarks:Wholesale price
Company Name: GIHI CHEMICALS CO.,LIMITED
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Products Intro: Product Name:(S)-(-)-7,7'-BIS[DI(3,5-DIMETHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE
CAS:528521-89-3
Purity:99 Package:5KG;1KG,25kg
Company Name: Aladdin Scientific
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Products Intro: Product Name:(S)-Xyl-SDP
CAS:528521-89-3
Purity:97%,98%ee Package:$65.9/25mg;$196.9/100mg;Bulk package Remarks:97%,98%ee
Company Name: Shanghai Anyinuo Biomedical Technology Co., Ltd.  Gold
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Products Intro: Product Name:(S)-Xyl-SDP
CAS:528521-89-3
Purity:>=98% Package:100mg;250mg;500mg;1g;10g;100g;1kg
(S)-(-)-7,7'-BIS[DI(3,5-DIMETHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE Basic information
Reaction
Product Name:(S)-(-)-7,7'-BIS[DI(3,5-DIMETHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE
Synonyms:(S)-7,7-BIS[DI(3,5-DIMETHYLPHENYL)PHOSPHINO]-1,1-SPIROBIINDANE;(S)-7,7'-Bis[di(3,5-dimethylphenyl)phosphino]-1,1'-spirobiindane ,97%;(S)-()-7,7′-Bis[di(3,5-dimethylphenyl)phosphino]-2,2′,3,3′-tetrahydro-1,1′-spirobiindene;(S)–7,7′-Bis[di(3,5-dimethylphenyl)phosphino]-1,1′-spirobiindan;1,1'-[(1S)-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBI[1H-INDENE]-7,7'-DIYL]BIS[1,1-BIS(3,5-DIMETHYLPHENYL)PHOSPHINE];1,1'-[(1S)-2,2',3,3'-Tetrahydro-1,1'-spirobi[1H-indene]-7,7'-diyl]bis[1,1-bis(3,5-dimethylphenyl)phosphine],99%e.e.;(R)-7,7'-BIS[DI(3,5-DIMETHYLPHENYL)PHOSPHINO]-1,1'-SPIROBIINDANE;(R)-(+)-7,7'-BIS[DI(3,5-DIMETHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE
CAS:528521-89-3
MF:C49H50P2
MW:700.87
EINECS:
Product Categories:BINAP Series;Chiral Phosphine;Chiral Spiro Ligand
Mol File:528521-89-3.mol
(S)-(-)-7,7'-BIS[DI(3,5-DIMETHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE Structure
(S)-(-)-7,7'-BIS[DI(3,5-DIMETHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE Chemical Properties
Melting point >300°C
Boiling point 794.8±60.0 °C(Predicted)
alpha -83° (c 0.53, CH2Cl2)
storage temp. -20°C
form solid
color off-white to pale yellow
Optical Rotation[α]22/D 62.0°, c = 1 in chloroform
Sensitive air sensitive
InChIKeyAZSBNBQMIMQOPG-UHFFFAOYSA-N
SMILESC12(CCC3C=CC=C(C1=3)P(C1=CC(C)=CC(C)=C1)C1=CC(C)=CC(C)=C1)CCC1C=CC=C(C2=1)P(C1C=C(C)C=C(C)C=1)C1C=C(C)C=C(C)C=1
CAS DataBase Reference528521-89-3
Safety Information
WGK Germany 3
HS Code 29319090
MSDS Information
(S)-(-)-7,7'-BIS[DI(3,5-DIMETHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE Usage And Synthesis
Reaction
  1. Chiral ligands for ruthenium-catalyzed asymmetric hydrogenation of simple ketones.
  2. Chiral ligands for ruthenium-catalyzed asymmetric hydrogenation of racemic α-aryl cyclic ketones via dynamic kinetic resolution. 
Reactions of 528521-89-3
Chemical PropertiesColorless oil
reaction suitabilityreagent type: ligand
Tag:(S)-(-)-7,7'-BIS[DI(3,5-DIMETHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE(528521-89-3) Related Product Information
Indene (S)-(-)-7,7'-BIS[DI(3,5-DIMETHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE TRI-M-TOLYLPHOSPHINE (R)-(+)-7,7'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE (R)-(+)-7,7′-Bis[di(3,5-dimethylphenyl)phosphino]-2,2′,3,3′-tetrahydro-1,1′-spirobiindene

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