| Company Name: |
Ark Pharm, Inc. |
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847-367-3680 |
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sales@arkpharminc.com |
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| | 4,6-Dimethoxy-2-(phenoxycarbonyl)aminopyrimidine Basic information |
| Product Name: | 4,6-Dimethoxy-2-(phenoxycarbonyl)aminopyrimidine | | Synonyms: | PHENYL-4,6-DIMETHOXY-2-PYRIMIDYLAMINO FORMATE;4,6-dimethoxy-N-phenyl-2-pyrimidinamine;4,6-Dimethoxy-2-(phenoxycarbonyl)aminopyrimidine;2-((PHENOXYCARBONYL)AMINO)-4,6-DIMETHOXYPYRIMIDINE;N-(4,6-dimethoxy-2-pyrimidinyl)carbamic acid phenyl ester;(4,6-DIMETHOXY-PYRIMIDIN-2-YL)-CARBAMIC ACID PHENYL ESTER;Phenyl(4,6-dimethoxy-2-pyrimidinyl)carbamate;PHENYL N-(4, 6-DIMETHOXY PYRIMIDINE-2-YL) CARBAMATE | | CAS: | 89392-03-0 | | MF: | C13H13N3O4 | | MW: | 275.26 | | EINECS: | 406-600-2 | | Product Categories: | Heterocycle-Pyrimidine series;Amines | | Mol File: | 89392-03-0.mol |  |
| | 4,6-Dimethoxy-2-(phenoxycarbonyl)aminopyrimidine Chemical Properties |
| Hazard Codes | Xi,N | | Risk Statements | 43-51/53 | | Safety Statements | 24-37-61 | | RIDADR | UN 3077 9/PG III | | TSCA | TSCA listed | | HazardClass | 9 | | PackingGroup | III | | HS Code | 2933599590 |
| | 4,6-Dimethoxy-2-(phenoxycarbonyl)aminopyrimidine Usage And Synthesis |
| Chemical Properties | Crystalline Powder | | Uses | Intermediate for the production of Sulfonyl Urea herbicides. Product Data Sheet | | Flammability and Explosibility | Non flammable | | Synthesis | To a stirred solution of 2-amino-4,6-dimethoxypyrimidine (1 g, 6.45 mmol) in acetonitrile (10 mL) was added triethylamine (0.85 g, 8.40 mmol) at room temperature, followed by the slow dropwise addition of phenyl chloroformate (1.31 g, 8.37 mmol). The reaction mixture was heated to 60 °C and stirred for 6 hours. After completion of the reaction, the mixture was cooled to room temperature, diluted with water (6 mL), the precipitated solid was collected by filtration and dried under vacuum to afford 2-((phenoxycarbonyl)aminomethyl)-4,6-dimethoxypyrimidine (Compound 6) as a white solid in the following yields: 1.48 g, 83%; melting point: 119 °C; 1H NMR (400 MHz, DMSO-d6): δ 7.65 (s 1H), 7.42-7.40 (m, 2H), 7.18-7.14 (m, 3H), 5.80 (s, 1H), 3.96 (s, 6H); ESI-MS: m/z, 276.1 (M + 1). | | References | [1] Asian Journal of Chemistry, 2017, vol. 29, # 7, p. 1477 - 1481 |
| | 4,6-Dimethoxy-2-(phenoxycarbonyl)aminopyrimidine Preparation Products And Raw materials |
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