ChemicalBook > Product Catalog >Organic Chemistry >Phosphines >2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL

2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL

Request For Quotation
2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Suppliers list
Company Name: J & K SCIENTIFIC LTD.  
Tel: 18210857532 18210857532
Email: jkinfo@jkchemical.com
Company Name: Meryer (Shanghai) Chemical Technology Co., Ltd.  
Tel: 4006356688 18621169109
Email: market03@meryer.com
Company Name: Beijing Donghualituo Techonlogy Development Co.,Ltd.  
Tel: 010-88425576
Email: sales@dhltchem.com
Company Name: Alfa Aesar  
Tel: 400-6106006
Email: saleschina@alfa-asia.com
Company Name: TCI (Shanghai) Development Co., Ltd.  
Tel: 021-67121386
Email: Sales-CN@TCIchemicals.com

2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL manufacturers
2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Basic information
Reaction
Product Name:2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL
Synonyms:[2-(2-diphenylphosphinophenyl)phenyl]-diphenylphosphine;2,2'-Bis(diphenylphosphino)-1,1'-biphenyl,98%BIPHEP;2,2'-Bis(diphenylphosphino)-1,1'-biphenyl, (BIPHEP);2,2’-Bis(diphenylphospino)-1,1’-biphenyl;PHOSPHINE, 1,1''-[[1,1''-BIPHENYL]-2,2''-DIYL]BIS[1,1-DIPHENYL-;2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL,98%;2,2'-Bis(diphenylphosphino)bip;{2-[2-(diphenylphosphanyl)phenyl]phenyl}diphenylphosphane
CAS:84783-64-2
MF:C36H28P2
MW:522.55
EINECS:
Product Categories:Achiral Phosphine;Aryl Phosphine;Phosphines;Biphenyl & Diphenyl ether;Phosphine Ligands;Synthetic Organic Chemistry
Mol File:84783-64-2.mol
2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Structure
2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Chemical Properties
Melting point 210-214 °C
Boiling point 635.5±48.0 °C(Predicted)
storage temp. 2-8°C, protect from light, stored under nitrogen
solubility soluble in Toluene
form crystal
color white
InChI1S/C36H28P2/c1-5-17-29(18-6-1)37(30-19-7-2-8-20-30)35-27-15-13-25-33(35)34-26-14-16-28-36(34)38(31-21-9-3-10-22-31)32-23-11-4-12-24-32/h1-28H
InChIKeyGRTJBNJOHNTQBO-UHFFFAOYSA-N
SMILESc1ccc(cc1)P(c2ccccc2)c3ccccc3-c4ccccc4P(c5ccccc5)c6ccccc6
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38-36
Safety Statements 37/39-26
WGK Germany WGK 3
TSCA No
HS Code 29310099
Storage Class11 - Combustible Solids
Hazard ClassificationsEye Irrit. 2
MSDS Information
ProviderLanguage
ACROS English
2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Usage And Synthesis
Reaction
  1. Supporting ligand in a chiral diamine-ruthenium system for the enantioselective hydrogenation of ketones.
  2. Useful ligand for palladium-catalyzed amination and Kumada cross-coupling reactions
  3. Useful ligand for palladium-catalyzed synthesis of butatrenes.
  4. Useful ligand for iridium-catalyzed C-C cross-coupling of allenes with primary alcohols via transfer hydrogenation.
  5. Useful ligand for iridium-catalyzed C-C cross-coupling of dienes with primary alcohols via transfer hydrogenation.
  6. Useful ligand for iridium-catalyzed C-C cross-coupling of allylic gem-dicarboxylates with aldehydes via transfer hydrogenation.
  7. Useful ligand for the palladium-catalyzed synthesis of chiral allenylsilanes.
  8. Ruthenium-catalyzed synthesis of indoles.
  9. Ruthenium-catalyzed oxidative cyclization.
  10. Rhodium-catalyzed boron arylation. 
Reactions of 84783-64-2_1
Reactions of 84783-64-2_2
Reactions of 84783-64-2_3
Chemical Propertieswhite crystalline powder or crystals
Uses2,2''-Bis(diphenylphosphino)-1,1’-biphenyl (CAS# 84783-64-2) is a chelating phosphine and has been used to study the effects of bite angles on the chemical and physical properties of transition metal complexes. 2,2''-Bis(diphenylphosphino)-1,1’-biphenyl appears as a catalytic ligand in Ni- and Pd-Catalyzed cross-electrophile coupling reactions to form highly substituted 1,3-dienes.
reaction suitabilityreaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL Preparation Products And Raw materials
Tag:2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL(84783-64-2) Related Product Information
2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL 3',6'-BIS(DIETHYLAMINO)-2-(4-NITROPHENYL)SPIRO[ISOINDOLE-1,9'-XANTHENE]-3-ONE DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) [(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II) chloride (S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL Diphenylphosphine (R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl R(+)-2 2'-bis-(diphenylphosphino)-6 6'-& DICHLORO[(R)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(R)-1,1-BIS(P-METHOXYPHENYL)-2-ISOPROPYLETHANE-1,2-DIAMINE]RUTHENIUM(II) DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II) PHOSPHINE OXIDE, [1,1'-BINAPHTHALENE]-2,2'-DIYLBIS (R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL DICHLORO[(S)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(S)-1,1-BIS(P-METHOXYPHENYL)-2-ISOPROPYLETHANE-1,2-DIAMINE]RUTHENIUM(II) (R)-H8-BINAP (R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE Chloro[(R)-(+)-5,5'-dichloro-6,6'-dimethoxy-2,2'-bis(diphenylphosphino)-1,1'-biphenyl](p-cymene)ruthenium(II)chlorideCH2Cl2adduct (R)-CYCLOHEXYL SONIPHOS