Tetraallyltin manufacturers
- Tetraallyltin
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- $1.00 / 1ASSAYS
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2020-01-09
- CAS:7393-43-3
- Min. Order: 1ASSAYS
- Purity: 85.0-99.8%
- Supply Ability: 20tons
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| | Tetraallyltin Basic information |
| | Tetraallyltin Chemical Properties |
| Boiling point | 69-70 °C1.5 mm Hg(lit.) | | density | 1.179 g/mL at 25 °C(lit.) | | refractive index | n20/D 1.539(lit.) | | Fp | 167 °F | | solubility | sol common organic solvents; insol H2O. | | form | Liquid | | color | Clear colorless | | Specific Gravity | 1.179 | | Water Solubility | Not miscible in water or difficult to mix. | | Sensitive | Air Sensitive | | BRN | 3536269 | | Exposure limits | ACGIH: TWA 0.1 mg/m3; STEL 0.2 mg/m3 (Skin)
NIOSH: IDLH 25 mg/m3; TWA 0.1 mg/m3 | | InChI | 1S/4C3H5.Sn/c4*1-3-2;/h4*3H,1-2H2; | | InChIKey | XJPKDRJZNZMJQM-UHFFFAOYSA-N | | SMILES | C=CC[Sn](CC=C)(CC=C)CC=C | | CAS DataBase Reference | 7393-43-3(CAS DataBase Reference) |
| Hazard Codes | T | | Risk Statements | 23/24/25 | | Safety Statements | 23-24/25-45-36/37 | | RIDADR | UN 2788 6.1/PG 3 | | WGK Germany | 3 | | F | 10-23 | | TSCA | No | | HazardClass | 6.1 | | PackingGroup | II | | HS Code | 29310099 | | Storage Class | 10 - Combustible liquids |
| | Tetraallyltin Usage And Synthesis |
| Chemical Properties | Clear Colorless liquid | | Uses | Applied as allyl transfer reagent. | | Application | Tetraallyltin is an allylic lithium precursor; an allylic nucleophile used in allylic transfer reactions and Stille couplings. | | Preparation | Tetraallyltin is synthesized by the reaction of Allylmagnesium Bromide with Tin(IV) Chloride in THF. | | reaction suitability | core: tin | | Purification Methods | Possible contaminants are allyl chloride and allyltin chloride. Check the 1H NMR and IR [Fishwick & Wallbridge J Organomet Chem 25 69 1970], and if impure, dissolve it in Et2O and shake it with a 5% aqueous solution of NaF which precipitates allyltin fluoride. Separate the Et2O layer, dry (MgSO4) and distil it at ~ 0.2mm. It decomposes slightly on repeated distillation. [O'Brien et al. Inorg Synth XIII 75 1972, Fishwick et al. J Chem Soc (A) 57 1971, Beilstein 4 III 1922.] |
| | Tetraallyltin Preparation Products And Raw materials |
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