- Allyl(bromo)magnesium
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- $1.00 / 1kg
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2019-07-06
- CAS:1730-25-2
- Min. Order: 1kg
- Purity: 99%
- Supply Ability: Customized
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| | ALLYLMAGNESIUM BROMIDE Basic information |
| | ALLYLMAGNESIUM BROMIDE Chemical Properties |
| density | 0.851 g/mL at 25 °C | | Fp | −40 °F | | storage temp. | Refrigerator | | form | Solution | | color | Yellow-green or gray | | Sensitive | air sensitive, moisture sensitive | | BRN | 969335 | | InChI | InChI=1S/C3H5.BrH.Mg/c1-3-2;;/h3H,1-2H2;1H;/q;;+1/p-1 | | InChIKey | FEMBXICCJNZMMC-UHFFFAOYSA-M | | SMILES | C([Mg]Br)C=C | | CAS DataBase Reference | 1730-25-2 |
| Hazard Codes | F+,C,F | | Risk Statements | 12-14/15-19-22-34-66-67-11 | | Safety Statements | 9-16-29-33-43-45-36/37/39-26 | | RIDADR | UN 3399 4.3/PG 1 | | WGK Germany | 1 | | F | 1-3-10 | | HazardClass | 8 | | PackingGroup | III | | HS Code | 29319090 | | Storage Class | 4.3 - Hazardous materials which set free flammable gases upon contact with water | | Hazard Classifications | Acute Tox. 4 Oral
Eye Dam. 1
Flam. Liq. 1
Skin Corr. 1B
STOT SE 3
Water-react 1 |
| | ALLYLMAGNESIUM BROMIDE Usage And Synthesis |
| Chemical Properties | Yellow-green or grey liquid | | Uses | Allylmagnesium bromide solution can be used in the Grignard reaction, which is a key step to synthesize:
- 2-(9,10-dihydro-9,10-propanoanthracen-9-yl)-N-methylethanamine (2), a homolog of benzoctamine
- tarchonanthuslactone
- (+)-preussin
- polyhydroxylated quinolizidine alkaloids
| | Application |
Allylmagnesium bromide is a Grignard reagent used for introducing the allyl group. It can also be used in place of the bromide to give allylmagnesium chloride.
| | reaction suitability | reaction type: Grignard Reaction | | Synthesis | Allylmagnesium bromide can be synthesized by treatment of magnesium with allyl bromide while maintaining the reaction temperature below 0 °C to suppress formation of hexadiene.
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| | ALLYLMAGNESIUM BROMIDE Preparation Products And Raw materials |
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