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N-Boc-(S)-2-amino-3-benzyloxy-1-propanol

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N-Boc-(S)-2-amino-3-benzyloxy-1-propanol manufacturers

  • Boc-D-Ser(Bzl)-OL
  • Boc-D-Ser(Bzl)-OL pictures
  • 2026-09-20
  • CAS:79069-15-1
  • Min. Order: 1kg
  • Purity: 98%
  • Supply Ability: 1T+
N-Boc-(S)-2-amino-3-benzyloxy-1-propanol Basic information
Product Name:N-Boc-(S)-2-amino-3-benzyloxy-1-propanol
Synonyms:(R)-(+)-3-BENZYLOXY-2-(TERT-BUTOXYCARBONYLAMINO)-1-PROPANOL;N-T-BUTOXYCARBONYL-O-BENZYL-L-SERINOL;N-T-BUTOXYCARBONYL-O-BENZYL-D-SERINOL;N-ALPHA-T-BOC-O-BENZYL-L-SERINOL;N-ALPHA-T-BOC-O-BENZYL-D-SERINOL;BOC-O-BENZYL-D-SERINOL;BOC-O-BENZYL-L-SERINOL;BOC-D-SER(BZL)-OL
CAS:79069-15-1
MF:C15H23NO4
MW:281.35
EINECS:
Product Categories:Amino Alcohols;Boc-Amino acid series;Amino Acids
Mol File:79069-15-1.mol
N-Boc-(S)-2-amino-3-benzyloxy-1-propanol Structure
N-Boc-(S)-2-amino-3-benzyloxy-1-propanol Chemical Properties
Melting point 66-69 °C(lit.)
alpha -14 º (c=1 in chloroform)
Boiling point 443.1±40.0 °C(Predicted)
density 1.105
storage temp. Inert atmosphere,2-8°C
solubility Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
form Powder
pka11.58±0.46(Predicted)
AppearanceWhite to off-white Solid
InChIInChI=1S/C15H23NO4/c1-15(2,3)20-14(18)16-13(9-17)11-19-10-12-7-5-4-6-8-12/h4-8,13,17H,9-11H2,1-3H3,(H,16,18)/t13-/m0/s1
InChIKeyMSIDLARYVJJEQY-ZDUSSCGKSA-N
SMILESC(OC(C)(C)C)(=O)N[C@@H](CO)COCC1=CC=CC=C1
CAS DataBase Reference79069-15-1(CAS DataBase Reference)
Safety Information
WGK Germany 3
HS Code 2924297099
MSDS Information
ProviderLanguage
SigmaAldrich English
N-Boc-(S)-2-amino-3-benzyloxy-1-propanol Usage And Synthesis
Chemical PropertiesWhite to off-white solid
SynthesisUnder an atmosphere of argon, to a solution of 2,5-dioxopyrrolidin-1-yl O-benzyl-N-t-butoxycarbonyl-L-serinate (4.41 g) in tetrahydrofuran(30 mL) was added sodium borohydride (644 mg) in ice bath and the mixture was stirred at room temperature overnight. Water was added to the reaction solution, which was extracted with ethyl acetate. The organic layer was washed with an aqueous saturated ammonium chloride solution and brine, dried over anhydrous magnesium sulfate, and concentrated to give N-Boc-(S)-2-amino-3-benzyloxy-1-propanol.
N-Boc-(S)-2-amino-3-benzyloxy-1-propanol
References[1] Synthetic Communications, 1996, vol. 26, # 13, p. 2511 - 2522
[2] Nucleosides and Nucleotides, 1999, vol. 18, # 8, p. 1845 - 1861
[3] Bioorganic and Medicinal Chemistry, 2012, vol. 20, # 2, p. 702 - 713
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