(S)-(+)-2-[HYDROXY(DIPHENYL)METHYL]-1-METHYLPYRROLIDINE

(S)-(+)-2-[HYDROXY(DIPHENYL)METHYL]-1-METHYLPYRROLIDINE Suppliers list

Company Name:	Shanghai Daken Advanced Materials Co.,Ltd
Tel:	+86-2158073036
Email:	info@dakenam.com
Products Intro:	Product Name:(S)-(+)-2-[HYDROXY(DIPHENYL)METHYL]-1-METHYLPYRROLIDINE CAS:110529-22-1 Purity:99% Package:1KG,5KG,10KG

Company Name:	Alchem Pharmtech,Inc.
Tel:	8485655694
Email:	sales@alchempharmtech.com
Products Intro:	Product Name:(S)-Alpha,Alpha-Diphenylmethylprolinol CAS:110529-22-1 Purity:97+% Package:1g;10g;100g;;1kg Remarks:Z-25188

Company Name:	Wuhan Chemwish Technology Co., Ltd
Tel:	027-67849912
Email:	sales@chemwish.com
Products Intro:	Product Name:(S)-N-Methyl-alpha,alpha-diphenyl2-pyrrolidinemethanol CAS:110529-22-1 Purity:0.98 Package:1g;5g;25g;100;500g

Company Name:	CONIER CHEM AND PHARMA LIMITED
Tel:
Email:	sales@conier.com
Products Intro:	Product Name:alpha,alpha-diphenyl-n-methyl-l-prolinol CAS:110529-22-1 Purity:0.99 Package:1kg

Company Name:	career henan chemical co
Tel:	+86-0371-86658258
Email:	factory@coreychem.com
Products Intro:	Product Name:(S)-(+)-2-[HYDROXY(DIPHENYL)METHYL]-1-METHYLPYRROLIDINE CAS:110529-22-1 Purity:98%MIN Package:1KG;2USD

(S)-(+)-2-[HYDROXY(DIPHENYL)METHYL]-1-METHYLPYRROLIDINE manufacturers

(S)-(+)-2-[HYDROXY(DIPHENYL)METHYL]-1-METHYLPYRROLIDINE Basic information

Product Name:	(S)-(+)-2-[HYDROXY(DIPHENYL)METHYL]-1-METHYLPYRROLIDINE
Synonyms:	(S)-(+)-2-[HYDROXY(DIPHENYL)METHYL]-1-METHYLPYRROLIDINE;(S)-N-Methyl-alpha,alpha-diphenylpyrrolidinemethanol;Hydroxydiphenylmethylmethylpyrrolidine;a,a-Diphenyl-N-methyl-L-prolinol;(s)-n-methyl-à,à-diphenylpyrrolidinemethanol;(s)-α,α-diphenyl-n-methyl-2-pyrrolidinemethanol;à,à-diphenyl-n-methyl-l-prolinol;α,α-diphenyl-n-methyl-l-prolinol
CAS:	110529-22-1
MF:	C18H21NO
MW:	267.37
EINECS:	634-571-8
Product Categories:	Asymmetric Synthesis;Synthetic Organic Chemistry
Mol File:	110529-22-1.mol

(S)-(+)-2-[HYDROXY(DIPHENYL)METHYL]-1-METHYLPYRROLIDINE Chemical Properties

Melting point	66-72 °C
alpha	+52° (c=1, CHCl3)
Boiling point	406.8±25.0 °C(Predicted)
density	1.116±0.06 g/cm3(Predicted)
refractive index	55 ° (C=1, CHCl3)
storage temp.	Sealed in dry,2-8°C
solubility	sol hexane, benzene, toluene, Et2O, cyclohexane, dichloromethane
form	Powder
pka	13.15±0.29(Predicted)
color	white to pale-yellow
Optical Rotation	[α]20/D +55±3°, c = 1% in chloroform stab. with amylenes
BRN	4749387
InChI	1S/C18H21NO/c1-19-14-8-13-17(19)18(20,15-9-4-2-5-10-15)16-11-6-3-7-12-16/h2-7,9-12,17,20H,8,13-14H2,1H3/t17-/m0/s1
InChIKey	XIJAGFLYYNXCAB-KRWDZBQOSA-N
SMILES	CN1CCC[C@H]1C(O)(c2ccccc2)c3ccccc3
CAS DataBase Reference	110529-22-1(CAS DataBase Reference)

Safety Information

MSDS Information

(S)-(+)-2-[HYDROXY(DIPHENYL)METHYL]-1-METHYLPYRROLIDINE Usage And Synthesis

Reactions	Catalyst for the enantioselective addition of diethylzinc to α,β-unsaturated aldehydes
Chemical Properties	white to slightly yellow crystalline powder
Uses	(S)-(+)-2-[Hydroxy(diphenyl)methyl]-1-methylpyrrolidine is used for chiral ligand for the enantioselective addition of dialkylzincs, alkynylzinc, and cyanomethylzinc bromide to aldehydes; chiral ligand for the enantioselective Reformatsky reaction; chiral ligand for the enantioselective Diels-Alder reaction; chiral auxiliary for asymmetric polymerization.
Preparation	Reaction of Phenylmagnesium Bromide with (S)-N-[(benzyloxy)carbonyl]proline methyl ester and subsequent reduction with Lithium Aluminum Hydride affords the (S)-(+)-2-[Hydroxy(diphenyl)methyl]-1-methylpyrrolidine in 83% overall yield.

(S)-(+)-2-[HYDROXY(DIPHENYL)METHYL]-1-METHYLPYRROLIDINE Preparation Products And Raw materials

Tag:(S)-(+)-2-[HYDROXY(DIPHENYL)METHYL]-1-METHYLPYRROLIDINE(110529-22-1) Related Product Information

N-[(1S)-2'-aMino[1,1'-binaphthalen]-2-yl]-AcetaMide N-Methyl-L-prolinol (R)-(-)-2-[HYDROXY(DIPHENYL)METHYL]-1-METHYLPYRROLIDINE (S)-(-)-2-AMINO-1,1-DIPHENYL-1-PROPANOL (S)-(-)-α,α-Diphenyl-2-pyrrolidinemethanol L-(+)-Prolinol (1S,2S)-(+)-Pseudoephedrine hydrochloride (S)-2-Dimethylamino-1-phenyletanol (S)-(+)-2-[HYDROXY(DIPHENYL)METHYL]-1-METHYLPYRROLIDINE (-)-N-METHYLEPHEDRINE (2S)-2-ISOPROPYLPYRROLIDINE (S)-2-DIPHENYLMETHYLPYRROLIDINE (S)-(-)N-CARBOMETHOXY-ALPHA,ALPHA-DIPHENYL -2-PYRROLIDINEMETHANOL,98% (S,S)-(+)-2,6-BIS[2-(HYDROXYDIPHENYLMETHYL)-1-PYRROLIDINYL-METHYL]-4-METHYLPHENOL (S)-(-)-1,1-DIPHENYL-2-AMINOPROPANE 1,1-DIPHENYL-TETRAHYDRO-PYRROLO[1,2-C]OXAZOL-3-ONE 2-BENZYLPYRROLIDINE (1S,2S)-(+)-N-METHYLPSEUDOEPHEDRINE