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1,2-BIS(DIPHENYLPHOSPHINO)BENZENE

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Company Name: Henan Tianfu Chemical Co.,Ltd.
Tel: +86-0371-55170693 +86-19937530512
Email: info@tianfuchem.com
Products Intro: Product Name:1,2-BIS(DIPHENYLPHOSPHINO)BENZENE
CAS:13991-08-7
Purity:99% Package:25KG;5KG;1KG
Company Name: career henan chemical co
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Products Intro: Product Name: 1,2-BIS(DIPHENYLPHOSPHINO)BENZENE
CAS:13991-08-7
Purity:99% Package:1KG;1USD
Company Name: Accela ChemBio Inc.
Tel: +1-858-6993322
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Products Intro: Product Name:1,2-Bis(diphenylphosphino)benzene
CAS:13991-08-7
Purity:>=95% Package:1g;5g;10g;25g;100g
Company Name: Wuhan Pengo Technology.,Ltd.
Tel: +86-27-81330736 +86-13628634921
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Products Intro: Product Name:1,2-Bis(dimethylphosphino)benzene
CAS:13991-08-7
Purity:0.98 Package:100g,500g,1kg,10kg,100kg
Company Name: Shaanxi Dideu Medichem Co. Ltd
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Products Intro: Product Name:1,2-Bis(diphenylphosphino)benzene
CAS:13991-08-7
Purity:99% Package:1KG;1USD|25KG|100KG

1,2-BIS(DIPHENYLPHOSPHINO)BENZENE manufacturers
1,2-BIS(DIPHENYLPHOSPHINO)BENZENE Basic information
Product Name:1,2-BIS(DIPHENYLPHOSPHINO)BENZENE
Synonyms:1,2-BIS(DIPHENYLPHOSPHINO)BENZENE;1,2-BIS(DIPHENYLPHOSPHINO)BENZENE 98%;1,2-Bis(diphenylphosphanyl)benzene;dppbe;dppben;dppbenz;dppBz;o-bis(diphenylphosphino)benzene
CAS:13991-08-7
MF:C30H24P2
MW:446.47
EINECS:
Product Categories:Achiral Phosphine;Aryl Phosphine;Ligand;Catalysis and Inorganic Chemistry;Phosphorus Compounds;Polydentate Phosphine Ligands;organophosphine ligand
Mol File:13991-08-7.mol
1,2-BIS(DIPHENYLPHOSPHINO)BENZENE Structure
1,2-BIS(DIPHENYLPHOSPHINO)BENZENE Chemical Properties
Melting point 183-188 °C (lit.)
Boiling point 546.9±33.0 °C(Predicted)
storage temp. Inert atmosphere,Room Temperature
form Fine Crystalline Powder
color White
Water Solubility Insoluble in water.
Sensitive Air Sensitive
InChIInChI=1S/C30H24P2/c1-5-15-25(16-6-1)31(26-17-7-2-8-18-26)29-23-13-14-24-30(29)32(27-19-9-3-10-20-27)28-21-11-4-12-22-28/h1-24H
InChIKeyNFRYVRNCDXULEX-UHFFFAOYSA-N
SMILESP(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1P(C1C=CC=CC=1)C1C=CC=CC=1
CAS DataBase Reference13991-08-7(CAS DataBase Reference)
Safety Information
Risk Statements 36/37/38
Safety Statements 24/25
WGK Germany 3
TSCA No
HS Code 29319090
Storage Class11 - Combustible Solids
MSDS Information
ProviderLanguage
ACROS English
ALFA English
1,2-BIS(DIPHENYLPHOSPHINO)BENZENE Usage And Synthesis
Chemical Propertieswhite to light yellow crystal powde
Uses1,2-Bis(diphenylphosphino)benzene (DPPB) can be used:
  • As a chelating ligand in the synthesis of luminescent copper(I) halide complexes.
  • In the synthesis of copper-1,2-bis(diphenylphosphino)benzene catalyst which is used for the β-boration of α, β-unsaturated amide.
  • As an alternative to TMEDA for the selective cleavage of sp3 C-X bond in fluoroaromatic coupling reactions catalyzed by iron.
  • As a ligand in the synthesis of alkenylboronates from acetylenic esters.
  • To synthesize copper-diphosphine complexes which are used as homogeneous catalysts for N-formylation of a wide range of amines.

Application1,2-Bis(diphenylphosphino)benzene is a highly efficient bidentate phosphine ligand. It forms a stable five-membered ring chelate with a single transition metal atom (such as palladium, nickel, rhodium, gold, etc.) through its two adjacent diphenylphosphine groups. This structure gives the catalyst high activity and high stability, so it is widely used in various homogeneous catalytic reactions.
reaction suitabilityreagent type: ligand
reaction type: Baeyer-Villiger Oxidation
reagent type: ligand
reaction type: Cycloadditions
reagent type: ligand
reaction type: Reductions
1,2-BIS(DIPHENYLPHOSPHINO)BENZENE Preparation Products And Raw materials
Tag:1,2-BIS(DIPHENYLPHOSPHINO)BENZENE(13991-08-7) Related Product Information
1,5-Bis(diphenylphosphino)pentane 1,3-Bis(diphenylphosphino)propane 1,4-Bis(diphenylphosphino)butane Bis(diphenylphosphino)methane 1,2-BIS(DICHLOROPHOSPHINO)BENZENE 1,2-BIS(DIMETHOXYPHOSPHORYL)BENZENE 1,2-BIS(DICHLOROPHOSPHINO)ETHANE 1,2-BIS(DIETHYLPHOSPHINO)ETHANE 1,2-BIS(DIMETHYLPHOSPHINO)ETHANE 1,2-BIS(DICYCLOHEXYLPHOSPHINO)ETHANE 1.1'-Binaphthyl-2.2'-diphemyl phosphine 1,2-BIS(DIPHENYLPHOSPHINO)BENZENE Benzene 1,2-BIS(PHOSPHINO)BENZENE 1,3-BIS(DIPHENYLPHOSPHINO)BENZENE 1,4-BIS(DIPHENYLPHOSPHINO)BENZENE 1,2-BIS(DI-4-SULFONATOPHENYLPHOSPHINO)BENZENE TETRASODIUM SALT DMSO ADDUCT (1R,2R)-(+)-BIS(METHYLPHENYLPHOSPHINO)BENZENE