1,3-Bis(diphenylphosphino)propane

1,3-Bis(diphenylphosphino)propane Suppliers list

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1,3-Bis(diphenylphosphino)propane manufacturers

1,3-Bis(diphenylphosphino)propane-An Organophosphorus Compound
1,3-Bis(diphenylphosphino)propane (DPPP) is an organophosphorus compound with the formula Ph2P(CH2)3PPh2. The compound is a wh....
Nov 11，2019

1,3-Bis(diphenylphosphino)propane Basic information

Product Name:	1,3-Bis(diphenylphosphino)propane
Synonyms:	1,3-BIS(DIPHENYLPHOSPHINE)PROPANE;1,3-BIS(DIPHENYLPHOSPHINO)PROPANE;DPPP;TRIMETHYLENEBIS(DIPHENYLPHOSPHINE);[3-(Diphenylphosphino)propyl](diphenyl)phosphine;1,3-Propanediylbis(diphenylphosphine);Bis(1,3-diphenylphosphino)propane;Phosphine, 1,3-propanediylbis[diphenyl-
CAS:	6737-42-4
MF:	C27H26P2
MW:	412.45
EINECS:	229-791-2
Product Categories:	Phosphine Ligands;Synthetic Organic Chemistry;Ligand;API intermediates;organophosphine ligand;API intermediate;Phosphines;Achiral Phosphine;Aryl Phosphine
Mol File:	6737-42-4.mol

1,3-Bis(diphenylphosphino)propane Chemical Properties

Melting point	63-65 °C (lit.)
Boiling point	529.7±33.0 °C(Predicted)
Fp	235°C
storage temp.	Inert atmosphere,Room Temperature
form	Granules or Powder
color	White to light yellow-beige
Water Solubility	insoluble
Sensitive	Air Sensitive
BRN	2821785
InChI	InChI=1S/C27H26P2/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27/h1-12,14-21H,13,22-23H2
InChIKey	LVEYOSJUKRVCCF-UHFFFAOYSA-N
SMILES	P(C1C=CC=CC=1)(C1C=CC=CC=1)CCCP(C1C=CC=CC=1)C1C=CC=CC=1
CAS DataBase Reference	6737-42-4(CAS DataBase Reference)
NIST Chemistry Reference	1,3-Bis(diphenylphosphino)propane(6737-42-4)
EPA Substance Registry System	Phosphine, 1,3-propanediylbis[diphenyl- (6737-42-4)

Safety Information

MSDS Information

Provider	Language
1,3-Bis(diphenylphosphino)propane	English
SigmaAldrich	English
ACROS	English
ALFA	English

1,3-Bis(diphenylphosphino)propane Usage And Synthesis

Description	1,3-Bis(diphenylphosphino)propane is a ligand for metal-catalyzed substitution reactions of aryl and vinyl triflates, halides, and carbonates; carbonylation reactions; Grignard coupling; diene alkylation; macrocycle synthesis.
Chemical Properties	white to light yellow crystal powde
Uses	1,3-Bis(diphenylphosphino)propane is used as a bidentate ligand in coordination chemistry and form complex dichloro(1,3-bis(diphenylphosphino)propane)nickel by reacting with nickel(II) chloride. This complex is used as a catalyst for Kumada coupling reaction. It also acts as a ligand for palladium(II) catalysts which is useful for the co-polymerization of carbon monoxide and ethylene to get polyketones. Further, it is employed in palladium-catalyzed arylation under Heck reaction and Suzuki reaction. In addition to this, it serves as a catalyst for Negishi coupling and Sonogashira coupling reactions.
reaction suitability	reagent type: ligand reaction type: C-C Bond Formation reagent type: ligand reaction type: Carbonylations reagent type: ligand reaction type: Negishi Coupling reagent type: ligand reaction type: Sonogashira Coupling reagent type: ligand reaction type: Suzuki-Miyaura Coupling

1,3-Bis(diphenylphosphino)propane Preparation Products And Raw materials

Raw materials	Ethanol-->Sodium hydroxide-->Hydrochloric acid-->Ethyl acetate-->Tetrahydrofuran-->Dichloromethane-->Sodium-->Magnesium sulfate-->Acetone-->n-Butyllithium-->Triphenylphosphine-->Lithium-->Diphenylphosphine-->1,3-Dibromopropane-->1,3-Dichloropropane-->3-(diphenylphosphoryl)propyl(diphenyl)phosphine oxide-->Diphenylphosphine oxide-->1-Bromo-3-chloropropane
Preparation Products	[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride-->3-DODECYLTHIOPHENE

Tag:1,3-Bis(diphenylphosphino)propane(6737-42-4) Related Product Information

Bis-Tris propane Di(trimethylol propane) Diphenylmethane tert-Butylchlorodiphenylsilane N-(Carboxymethyl)-N-(phosphonomethyl)-glycine Diphenylsilane Chlorodiphenylphosphine Diphenylphosphine 1,1'-Bis(diphenylphosphino)ferrocene 1,2-Bis(diphenylphosphino)ethane 1,4-Bis(diphenylphosphino)butane Propane DICHLORO[1,3-BIS(DIPHENYLPHOSPHINO)PROPANE]PALLADIUM(II) (2R,4R)-(+)-2,4-BIS(DIPHENYLPHOSPHINO)PENTANE (2S,4S)-(-)-2,4-BIS(DIPHENYLPHOSPHINO)PENTANE [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride 1,1,1-TRIS(DIPHENYLPHOSPHINOMETHYL)ETHANE TRIMETHYLENEBIS(TRIPHENYLPHOSPHONIUM BROMIDE)

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