3-(3-Methoxy-phenyl)-3-oxo-propionic acid ethyl ester

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3-(3-Methoxy-phenyl)-3-oxo-propionic acid ethyl ester Basic information
Product Name:3-(3-Methoxy-phenyl)-3-oxo-propionic acid ethyl ester
Synonyms:559253_ALDRICH;ZINC02575227;ETHYL (3-METHOXYBENZOYL)ACETATE;Ethyl m-anisoylacetate;m-Anisoyl-acetic acid ethyl ester;3-keto-3-(3-methoxyphenyl)propionic acid ethyl ester;Ethyl (m-Methoxybenzoyl)acetate;Benzenepropanoic acid, 3-methoxy-β-oxo-, ethyl ester
CAS:27834-99-7
MF:C12H14O4
MW:222.24
EINECS:
Product Categories:C12 to C63;Carbonyl Compounds;Esters;Building Blocks;C12 to C63;Carbonyl Compounds;Chemical Synthesis;Organic Building Blocks
Mol File:27834-99-7.mol
3-(3-Methoxy-phenyl)-3-oxo-propionic acid ethyl ester Structure
3-(3-Methoxy-phenyl)-3-oxo-propionic acid ethyl ester Chemical Properties
Boiling point >268 °C(lit.)
density 1.146 g/mL at 25 °C(lit.)
refractive index n20/D 1.5360(lit.)
Fp >230 °F
storage temp. 2-8°C
form clear liquid
pka10.28±0.46(Predicted)
color Colorless to Light yellow to Light orange
InChI1S/C12H14O4/c1-3-16-12(14)8-11(13)9-5-4-6-10(7-9)15-2/h4-7H,3,8H2,1-2H3
InChIKeyFDPPVAYPZOORBP-UHFFFAOYSA-N
SMILESCCOC(=O)CC(=O)c1cccc(OC)c1
CAS DataBase Reference27834-99-7(CAS DataBase Reference)
Safety Information
WGK Germany 3
HS Code 2918.99.4700
Storage Class10 - Combustible liquids
MSDS Information
ProviderLanguage
SigmaAldrich English
3-(3-Methoxy-phenyl)-3-oxo-propionic acid ethyl ester Usage And Synthesis
UsesReactant involved in:• ;Stereoselective ketonization-olefination of indoles1• ;Lewis base catalyzed hydrosilylation2 and sequential reactions3,4• ;Asymmetric hydrogenation5• ;Organocatalytic reduction by trichlorosilane6
UsesReactant involved in:
  • Stereoselective ketonization-olefination of indoles
  • Lewis base catalyzed hydrosilylation and sequential reactions
  • Asymmetric hydrogenation
  • Organocatalytic reduction by trichlorosilane
3-(3-Methoxy-phenyl)-3-oxo-propionic acid ethyl ester Preparation Products And Raw materials
Tag:3-(3-Methoxy-phenyl)-3-oxo-propionic acid ethyl ester(27834-99-7) Related Product Information
4-Hydroxy-8-methoxy-quinoline-3-carboxylic acid ethyl ester 1-Cyclopropyl-6,7-difluoro-1,4-dihydro-8-methoxy-4-oxo-3-quinolinecarboxylic acid ethyl ester Quincarbate Ethyl 4-hydroxy-6-methoxyquinoline-3-carboxylate Ethyl 3,4,5-trimethoxybenzoylacetate 3-( 2,5-dimethowy-phenyl)-3-oxo-propionic acid ethyl ester 3-(3,5-Dimethoxy-phenyl)-3-oxo-propionic acid ethyl ester 3-(4-Bromo-2-fluoro-3-methoxy-phenyl)-3-oxo-propionic acid ethyl ester 3-Benzo[1,3]dioxol-5-yl-3-oxo-propionic acid ethyl ester 3-(3,4-Dimethoxy-phenyl)-3-oxo-propionic acid ethyl ester 3-Oxo-3-(2,4,5-trifluoro-3-methoxy-phenyl)-propionic acid ethyl ester 3-(3-Methoxy-phenyl)-3-oxo-propionic acid ethyl ester Ethyl 4-hydroxy-8-(trifluoromethoxy)quinoline-3-carboxylate 3-(2,3-Dimethoxy-phenyl)-3-oxo-propionic acid ethyl ester 3-(2-Hydroxy-4-methoxy-phenyl)-3-oxo-propionic acid ethyl ester 2-(4-Nitro-phenyl)-3-oxo-3-(2,4,5-trimethoxy-phenyl)-propionic acid ethyl ester 4-Oxo-6-trifluoromethoxy-1,4-dihydro-quinoline-3-carboxylic acid ethyl ester AURORA 17731