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Bis[alpha,alpha-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur

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Company Name: Suzhou origin Specialty Chemicals Co., Ltd  Gold
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Bis[alpha,alpha-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur Basic information
Product Name:Bis[alpha,alpha-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur
Synonyms:Bis[a,a-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur;Bis[α,α-bis(trifluoromethyl)b;Martin Sulfurane Dehydrating agent technical grade;Sulfur, bis[a,a-bis(trifluoromethyl)benzenemethanolato-kO]diphenyl-, (T-4)-;-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur;Bis[αMARTIN SULFURANE DEHYDRATING AGENT;BIS[ALPHA,ALPHA-BIS(TRIFLUOROMETHYL)BENZENEMETHANOLATO]DIPHENYLSULFUR
CAS:32133-82-7
MF:C30H20F12O2S
MW:672.52
EINECS:
Product Categories:
Mol File:32133-82-7.mol
Bis[alpha,alpha-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur Structure
Bis[alpha,alpha-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur Chemical Properties
Melting point 106-108 °C(lit.)
density 1.32±0.1 g/cm3(Predicted)
storage temp. Freezer
solubility soluble in Methanol
form powder to crystal
color White to Orange to Green
BRN 1416879
Stability:Extremely Moisture Sensitive
InChIKeyRMIBJVUYNZSLSD-UHFFFAOYSA-N
SMILESS(C1=CC=CC=C1)(C1=CC=CC=C1)(OC(C(F)(F)F)(C(F)(F)F)C1=CC=CC=C1)OC(C(F)(F)F)(C(F)(F)F)C1=CC=CC=C1
Safety Information
Hazard Codes C
Risk Statements 34
Safety Statements 26-36/37/39-45
RIDADR UN 3261 8/PG 3
WGK Germany 3
F 10-21
HazardClass 8
PackingGroup II
HS Code 29309090
Storage Class8A - Combustible corrosive hazardous materials
Hazard ClassificationsSkin Corr. 1B
MSDS Information
ProviderLanguage
SigmaAldrich English
Bis[alpha,alpha-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur Usage And Synthesis
Chemical PropertiesIUPAC Name: [2-({diphenyl[(1,1,1,3,3,3-hexafluoro-2-phenylpropan-2-yl)oxy]-λ-sulfanyl}oxy)-1,1,1,3,3,3-hexafluoropropan-2-yl]benzene
UsesVersatile dehydrating and oxidizing agent. For chemistry and references, see Aldrichimica Acta .
PreparationBis[alpha,alpha-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur can be prepared by the reaction of the potassium salt of 1,1,1,3,3,3-hexafluoro-2-phenylisopropanol with diphenyl sulfide in the presence of chlorine in ether at -78 °C.
storageavoid moisture; readily hydrolyzed; stable at rt; decomposes slowly at rt in solution.
Bis[alpha,alpha-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur Preparation Products And Raw materials
Tag:Bis[alpha,alpha-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur(32133-82-7) Related Product Information
4-Hydroxybenzyl alcohol Diphenyl sulfide Bis[alpha,alpha-bis(trifluoromethyl)benzenemethanolato]diphenylsulfur 1,1,1,3,3,3-Hexafluoropropane 2-Trifluoromethyl-2-propanol 1,1,1,3,3,3-Hexafluoro-2-phenyl-2-propanol 1,1,1-Trifluoro-2-propanol 1,1,1,3,3,3-Hexafluoro-2-propanol 1-Phenyl-2,2,2-trifluoroethanol Hexafluoro-2-methylisopropanol 1,3-Difluoro-2-propanol (S)-1,1,1-Trifluoro-2-propanol 1,1,1,3,3,3-Hexafluoro-2-methylpropane (R)-(-)-alpha-(Trifluoromethyl)benzyl alcohol (S)-(+)-alpha-(Trifluoromethyl)benzyl alcohol 1-Fluoro-2-propanol 2-Phenyl-1,1,1-trifluoropropan-2-ol 1,3-Difluoro-2-methylpropan-2-ol