(R)-(-)-alpha-(Trifluoromethyl)benzyl alcohol

(R)-(-)-alpha-(Trifluoromethyl)benzyl alcohol Suppliers list

Company Name:	TCI (Shanghai) Development Co., Ltd.
Tel:	021-67121386
Email:	Sales-CN@TCIchemicals.com

Company Name:	Shanghai Longsheng chemical Co.,Ltd.
Tel:	58099637 13585536065
Email:	sales@shlschem.com

(R)-(-)-alpha-(Trifluoromethyl)benzyl alcohol Basic information

Product Name:	(R)-(-)-alpha-(Trifluoromethyl)benzyl alcohol
Synonyms:	(R)-(-)-1-PHENYL-2,2,2-TRIFLUOROETHANOL;(R)-(-)-2,2,2-TRIFLUORO-1-PHENYLETHANOL;(-)-PHENYL(TRIFLUOROMETHYL)CARBINOL;(-)-Phenyl(trifluoromethyl)carbinol, (R)-(-)-1-Phenyl-2,2,2-trifluoroethanol;(1R)-1-Phenyl-2,2,2-trifluoroethanol;(αR)-α-(Trifluoromethyl)benzenemethanol;(R)-(-)-ALPHA-(TRIFLUOROMETHYL)BENZYL AL COHOL, 99% (97% EE/GLC);(r)-(-)-α-(trifluoromethyl)benzyl alcohol
CAS:	10531-50-7
MF:	C8H7F3O
MW:	176.14
EINECS:	234-094-1
Product Categories:
Mol File:	10531-50-7.mol

(R)-(-)-alpha-(Trifluoromethyl)benzyl alcohol Chemical Properties

Melting point	20 °C(lit.)
Boiling point	73-76 °C9 mm Hg(lit.)
density	1.300 g/mL at 20 °C(lit.)
refractive index	n20/D 1.459(lit.)
Fp	189 °F
storage temp.	Keep in dark place,Inert atmosphere,Room temperature
pka	11.91±0.10(Predicted)
form	clear liquid
color	Colorless to Almost colorless
Optical Rotation	-32.968°(C=0.01gml DCM)
CAS DataBase Reference	10531-50-7(CAS DataBase Reference)

Safety Information

MSDS Information

Provider	Language
SigmaAldrich	English

(R)-(-)-alpha-(Trifluoromethyl)benzyl alcohol Usage And Synthesis

Uses	(R)-2,2,2-Trifluoro-1-phenylethanol is a building block used in the synthesis of mesoporous metal-organic frameworks.
Purification Methods	Purify the chiral alcohols by fractional distillation preferably in a vacuum. [Morrison & Ridgeway Tetrahedron Lett 573 1969, NMR: Pirkle & Beare J Am Chem Soc 90 6250 1968.] The racemate [340-05-6] has b 52-54o/2mm,57-59o/2mm, 64-65o/5mm, d 4 20 1.293, n D 20 1.457, and the 2-carbobenzoyl derivative has m 137-138o [Mosher et al. J Am Chem Soc 78 4374 1956]. [Beilstein 6 IV 3043.]

(R)-(-)-alpha-(Trifluoromethyl)benzyl alcohol Preparation Products And Raw materials

Raw materials	Benzene, [2,2,2-trifluoro-1-[(trimethylsilyl)oxy]ethyl]--->4,4,4-trifluoro-3-hydroxy-1,3-diphenyl-1-butanone-->(S)-(-)-1-Phenylethanol-->(S)-(+)-alpha-(Trifluoromethyl)benzyl alcohol-->Trifluoroacetophenone-->(S)-(+)-Methyl mandelate-->(R)-(-)-Methyl mandelate-->Benzaldehyde
Preparation Products	(R)-(+)-1-Phenyl-1-propanol

Tag:(R)-(-)-alpha-(Trifluoromethyl)benzyl alcohol(10531-50-7) Related Product Information

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