Chemical Safety Data Sheet MSDS / SDS
Phenyllithium
Revision Date:2026-03-21Revision Number:1
Product identifier
- Product name: Phenyllithium
- CBnumber: CB4853905
- CAS: 591-51-5
- EINECS Number: 209-720-1
- Synonyms: PHLI;PHENYLLITHIUM
Relevant identified uses of the substance or mixture and uses advised against
- Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
- Uses advised against: none
Company Identification
- Company: Chemicalbook
- Address: Building 1, Huihuang International, Shangdi 10th Street, Haidian District, Beijing
- Telephone: 010-86108875
GHS Label elements, including precautionary statements
-
Symbol(GHS)
- Signal wordDanger
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P273 Avoid release to the environment.
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
Hazard statements
H412 Harmful to aquatic life with long lasting effects
H335 May cause respiratory irritation
H314 Causes severe skin burns and eye damage
H226 Flammable liquid and vapour
Substance
- Product name: Phenyllithium
- Synonyms: PHLI;PHENYLLITHIUM
- CAS: 591-51-5
- EC number: 209-720-1
- MF: C6H5Li
- MW: 84.04
4.1 Description of first-aid measures
General adviceFirst aiders need to protect themselves. Show this material safety data sheet to the doctor in attendance.
If inhaled
After inhalation: fresh air. Call in physician.
In case of skin contact
In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately.
In case of eye contact
After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist.
Remove contact lenses.
If swallowed
Remove contact lenses.
After swallowing: make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11
4.3 Indication of any immediate medical attention and special treatment needed
No data available
4.4 Notes to physician
No data available
5.1 Extinguishing media
Suitable extinguishing mediaDry powder Sand
Unsuitable extinguishing media
Water Foam
5.2 Special hazards arising from the substance or mixture
Carbon oxides
Combustible.
Caution! in contact with water product releases:
Hydrogen
Vapors are heavier than air and may spread along floors.
May not get in touch with: Water
Forms explosive mixtures with air at elevated temperatures.
Development of hazardous combustion gases or vapours possible in the event of fire.
Combustible.
Caution! in contact with water product releases:
Hydrogen
Vapors are heavier than air and may spread along floors.
May not get in touch with: Water
Forms explosive mixtures with air at elevated temperatures.
Development of hazardous combustion gases or vapours possible in the event of fire.
5.3 Advice for firefighters
Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.
Remove container from danger zone and cool with water. Prevent fire extinguishing water from contaminating surface water or the ground water system.
Remove container from danger zone and cool with water. Prevent fire extinguishing water from contaminating surface water or the ground water system.
6.1 Personal precautions, protective equipment and emergency procedures
Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition.
Evacuate the danger area, observe emergency procedures, consult an expert.
For personal protection see section 8.
Evacuate the danger area, observe emergency procedures, consult an expert.
For personal protection see section 8.
6.2 Environmental precautions
Do not let product enter drains. Risk of explosion.
6.3 Methods and materials for containment and cleaning up
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up carefully with liquid-absorbent material (e.g.
Chemizorb®). Dispose of properly. Clean up affected area.
Chemizorb®). Dispose of properly. Clean up affected area.
6.4 Reference to other sections
For disposal see section 13.
7.1 Precautions for safe handling
Advice on safe handlingWork under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols.
Keep workplace dry. Do not allow product to come into contact with water.
Advice on protection against fire and explosion
Keep workplace dry. Do not allow product to come into contact with water.
Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge.
Hygiene measures
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.
For precautions see section 2.2.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditionsKeep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition. Keep locked up or in an area accessible only to qualified or authorized persons.
Never allow product to get in contact with water during storage.
Recommended storage temperature see product label.
Storage class
Never allow product to get in contact with water during storage.
Recommended storage temperature see product label.
Storage class (TRGS 510): 3: Flammable liquids
8.1 Control parameters
Ingredients with workplace control parameters| ['Component', 'CAS-No.', 'Value', 'Control\nparameters', 'Basis'] | ['biphenyl', '92-52-4', 'PC-TWA', '1.5 mg/m3', 'Occupational exposure limits for\nhazardous agents in the\nworkplace - Chemical\nhazardous agents.'] | ['benzene', '71-43-2', 'PC-TWA', '3 mg/m3', 'Occupational exposure limits for\nhazardous agents in the\nworkplace - Chemical\nhazardous agents.'] | ['', 'Remarks', 'G1 - Carcinogenic to humans\nSkin', None, None] | ['', '', 'PC-STEL', '6 mg/m3', 'Occupational exposure limits for\nhazardous agents in the\nworkplace - Chemical\nhazardous agents.'] | ['', '', 'G1 - Carcinogenic to humans\nSkin', None, None] |
|---|
| ['Component', 'CAS-No.', 'Parameters', 'Value', 'Biological\nspecimen', 'Basis'] | ['', '71-43-2', 'S-\nphenylmerc\napturic acid\n（S-PMA）', '47micro\nmoles\nper\nmillimole\ncreatinin\ne', 'Urine', 'China. Biological\nOccupational\nExposure Indices'] | ['', 'Remarks', 'After shift', None, None, None] | ['', '', 'S-\nphenylmerc\napturic acid\n（S-PMA）', '100µg/g\ncreatinin\ne', 'Urine', 'China. Biological\nOccupational\nExposure Indices'] |
|---|---|---|---|
| ['', '', 't,t-muconic\nacid (tt-MA)', '2.4Millim\noles per\nmole\ncreatinin\ne', 'Urine', 'China. Biological\nOccupational\nExposure Indices'] | ['', '', 'After shift', None, None, None] | ['', '', 't,t-muconic\nacid (tt-MA)', '3mg/g\ncreatinin\ne', 'Urine', 'China. Biological\nOccupational\nExposure Indices'] | ['', '', 'After shift', None, None, None] |
After shift
8.2 Exposure controls
Appropriate engineering controlsImmediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.
Personal protective equipment
Eye/face protection
Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles
Skin protection
This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell,
Internet: www.kcl.de).
Splash contact
Material: butyl-rubber
Minimum layer thickness: 0.7 mm
Break through time: 10 min
Material tested:Butoject® (KCL 898)
Internet: www.kcl.de).
Splash contact
Material: butyl-rubber
Minimum layer thickness: 0.7 mm
Break through time: 10 min
Material tested:Butoject® (KCL 898)
Body Protection
Flame retardant antistatic protective clothing.
Respiratory protection
required when vapours/aerosols are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system.
Control of environmental exposure
Do not let product enter drains. Risk of explosion.
Information on basic physicochemical properties
- a) Physical stateliquid
- b) Colordark brown
- c) OdorNo data available
- d) Melting point/freezing pointNo data available
- e) Initial boiling point and boiling range140-143 °C
- f) Flammability (solid, gas)No data available
- g) Upper/lower flammability or explosive limitsNo data available
- h) Flash point25 °C - Information refers to the main ingredient.
- i) Autoignition temperatureThe substance or mixture is not classified as pyrophoric.
- j) Decomposition temperatureNo data available
- k) pHNo data available
- l) ViscosityViscosity, kinematic: No data available
Viscosity, dynamic: No data available - m) Water solubilityat 20 °C Risk of violent reaction.
- n) Partition coefficient n-octanol/waterNo data available
- o) Vapor pressureNo data available
- p) Density0.85 g/cm3 at 20 °C
- Relative density0.835 g/mL at 25 °C
- q) Relative vapor densityNo data available
- r) Particle characteristicsNo data available
- s) Explosive propertiesNot classified as explosive.
- t) Oxidizing propertiesnone
- SolubilityMiscible with ether and hydrocarbons.
9.2 Other safety information
No data available
10.1 Chemical stability
sensitive to moisture
10.2 Possibility of hazardous reactions
Exothermic reaction with:
Oxidizing agents
Strong acids
Risk of explosion with: nitrogen trichloride
Risk of ignition or formation of inflammable gases or vapours with:
Alcohols nitrogen oxides
Oxidizing agents carbon dioxide combustible substances
Ether
Oxygen
Acids
Oxidizing agents
Strong acids
Risk of explosion with: nitrogen trichloride
Risk of ignition or formation of inflammable gases or vapours with:
Alcohols nitrogen oxides
Oxidizing agents carbon dioxide combustible substances
Ether
Oxygen
Acids
10.3 Conditions to avoid
Heating.
Moisture.
Moisture.
10.4 Incompatible materials
No data available
10.5 Hazardous decomposition products
In the event of fire: see section 5
11.1 Information on toxicological effects
Mixture Acute toxicityAcute toxicity estimate Oral - > 5,000 mg/kg (Calculation method)
Symptoms: If ingested, severe burns of the mouth and throat, as well as a danger of perforation of the esophagus and the stomach.
Acute toxicity estimate Inhalation - 4 h - 28.09 mg/l - vapor(Calculation method)
Symptoms: mucosal irritations, Cough, Shortness of breath, Possible damages:, damage of respiratory tract
Acute toxicity estimate Dermal - > 5,000 mg/kg (Calculation method)
Skin corrosion/irritation
Symptoms: If ingested, severe burns of the mouth and throat, as well as a danger of perforation of the esophagus and the stomach.
Acute toxicity estimate Inhalation - 4 h - 28.09 mg/l - vapor(Calculation method)
Symptoms: mucosal irritations, Cough, Shortness of breath, Possible damages:, damage of respiratory tract
Acute toxicity estimate Dermal - > 5,000 mg/kg (Calculation method)
Remarks: Mixture causes burns.
Remarks: Mixture causes burns.
Serious eye damage/eye irritation
Remarks: Mixture causes burns.
Remarks: Mixture causes serious eye damage.
Risk of blindness!
Respiratory or skin sensitization
Risk of blindness!
Classified based on available data. For more details, see section 2
Germ cell mutagenicity
Possible mutagen
Possible mutagen
Carcinogenicity
Possible mutagen
Possible human carcinogen
Possible human carcinogen
Reproductive toxicity
Possible human carcinogen
Suspected of damaging the unborn child.
Suspected of damaging fertility.
Specific target organ toxicity - single exposure
Suspected of damaging fertility.
Mixture may cause respiratory irritation.
Mixture may cause respiratory irritation.
Specific target organ toxicity - repeated exposure
Mixture may cause respiratory irritation.
Mixture may cause damage to organs through prolonged or repeated exposure.
- Blood
Mixture may cause damage to organs through prolonged or repeated exposure.
Aspiration hazard
- Blood
Mixture may cause damage to organs through prolonged or repeated exposure.
Classified based on available data. For more details, see section 2
11.2 Additional Information
Other dangerous properties can not be excluded.
This substance should be handled with particular care.
Handle in accordance with good industrial hygiene and safety practice.
Components 1,1'-Oxybis(butane)
This substance should be handled with particular care.
Handle in accordance with good industrial hygiene and safety practice.
Acute toxicity
LD50 Oral - Rat - male - 7,400 mg/kg (OECD Test Guideline 401)
LC50 Inhalation - Rat - male - 4 h - 21.6 mg/l - vapor (OECD Test Guideline 403)
LD50 Dermal - Rabbit - male - 7,741 mg/kg (OECD Test Guideline 402)
LC50 Inhalation - Rat - male - 4 h - 21.6 mg/l - vapor (OECD Test Guideline 403)
LD50 Dermal - Rabbit - male - 7,741 mg/kg (OECD Test Guideline 402)
Skin corrosion/irritation
Skin - Rabbit
Result: Mild skin irritation - 4 h (OECD Test Guideline 404)
Remarks: (Regulation (EC) No 1272/2008, Annex VI)
Remarks: Drying-out effect resulting in rough and chapped skin.
Dermatitis
Result: Mild skin irritation - 4 h (OECD Test Guideline 404)
Remarks: (Regulation (EC) No 1272/2008, Annex VI)
Remarks: Drying-out effect resulting in rough and chapped skin.
Dermatitis
Serious eye damage/eye irritation
Eyes - Rabbit
Result: Moderate eye irritation (OECD Test Guideline 405)
Remarks: (Regulation (EC) No 1272/2008, Annex VI)
Respiratory or skin sensitization
Result: Moderate eye irritation (OECD Test Guideline 405)
Remarks: (Regulation (EC) No 1272/2008, Annex VI)
Open epicutaneous test - Guinea pig
Result: negative (OECD Test Guideline 406)
Germ cell mutagenicity
Result: negative (OECD Test Guideline 406)
Test Type: Ames test
Test system: Salmonella typhimurium
Result: negative
Test Type: In vitro mammalian cell gene mutation test
Test system: Chinese hamster ovary cells
Result: negative
Test Type: Mutagenicity (mammal cell test): chromosome aberration.
Test system: Human lymphocytes
Result: negative
Carcinogenicity
Test system: Salmonella typhimurium
Result: negative
Test Type: In vitro mammalian cell gene mutation test
Test system: Chinese hamster ovary cells
Result: negative
Test Type: Mutagenicity (mammal cell test): chromosome aberration.
Test system: Human lymphocytes
Result: negative
Classified based on available data. For more details, see section 2
Reproductive toxicity
Classified based on available data. For more details, see section 2
Specific target organ toxicity - single exposure
May cause respiratory irritation.
Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)
Specific target organ toxicity - repeated exposure
Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)
Classified based on available data. For more details, see section 2
Aspiration hazard
Classified based on available data. For more details, see section 2
phenyllithium Acute toxicity
Oral: No data available
Inhalation: No data available
Dermal: No data available
Skin corrosion/irritation
Inhalation: No data available
Dermal: No data available
Classified based on available data. For more details, see section 2
Serious eye damage/eye irritation
Remarks: Causes serious eye damage.
Respiratory or skin sensitization
Classified based on available data. For more details, see section 2
Germ cell mutagenicity
Classified based on available data. For more details, see section 2
Carcinogenicity
Classified based on available data. For more details, see section 2
Reproductive toxicity
Classified based on available data. For more details, see section 2
Specific target organ toxicity - single exposure
Classified based on available data. For more details, see section 2
Specific target organ toxicity - repeated exposure
Classified based on available data. For more details, see section 2
Aspiration hazard
Classified based on available data. For more details, see section 2
biphenyl Acute toxicity
LD50 Oral - Rat - 2,140 mg/kg
Symptoms: Irritations of mucous membranes in the mouth, pharynx, oesophagus and gastrointestinal tract.
Remarks: (RTECS)
Symptoms: mucosal irritations, Cough, Shortness of breath, Inhalation may lead to the formation of oedemas in the respiratory tract., Possible damages:, damage of respiratory tract
LD50 Dermal - Rabbit - > 5,010 mg/kg
Remarks: (RTECS)
Skin corrosion/irritation
Symptoms: Irritations of mucous membranes in the mouth, pharynx, oesophagus and gastrointestinal tract.
Remarks: (RTECS)
Symptoms: mucosal irritations, Cough, Shortness of breath, Inhalation may lead to the formation of oedemas in the respiratory tract., Possible damages:, damage of respiratory tract
LD50 Dermal - Rabbit - > 5,010 mg/kg
Remarks: (RTECS)
Skin - Rabbit
Result: Severe irritations - 24 h (Draize Test)
Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)
Serious eye damage/eye irritation
Result: Severe irritations - 24 h (Draize Test)
Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)
Remarks: Causes serious eye irritation.
Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)
Respiratory or skin sensitization
Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)
Maximization Test - Guinea pig
Result: negative (OECD Test Guideline 406)
Germ cell mutagenicity
Result: negative (OECD Test Guideline 406)
Test Type: Ames test
Result: negative
Remarks: (HSDB)
Test Type: In vitro mammalian cell gene mutation test
Test system: mouse lymphoma cells
Result: positive
Method: OECD Test Guideline 474
Species: Mouse - male and female
Result: negative
Carcinogenicity
Result: negative
Remarks: (HSDB)
Test Type: In vitro mammalian cell gene mutation test
Test system: mouse lymphoma cells
Result: positive
Method: OECD Test Guideline 474
Species: Mouse - male and female
Result: negative
Classified based on available data. For more details, see section 2
Reproductive toxicity
Classified based on available data. For more details, see section 2
Specific target organ toxicity - single exposure
Inhalation - May cause respiratory irritation. - Respiratory system
Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)
Acute oral toxicity - Irritations of mucous membranes in the mouth, pharynx, oesophagus and gastrointestinal tract.
Acute inhalation toxicity - mucosal irritations, Cough, Shortness of breath,
Inhalation may lead to the formation of oedemas in the respiratory tract., Possible damages:, damage of respiratory tract
Specific target organ toxicity - repeated exposure
Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)
Acute oral toxicity - Irritations of mucous membranes in the mouth, pharynx, oesophagus and gastrointestinal tract.
Acute inhalation toxicity - mucosal irritations, Cough, Shortness of breath,
Inhalation may lead to the formation of oedemas in the respiratory tract., Possible damages:, damage of respiratory tract
Classified based on available data. For more details, see section 2
Aspiration hazard
Classified based on available data. For more details, see section 2
Hydrocarbons, C6, n-alkanes, isoalkanes, cyclics, n-hexane rich Acute toxicity
LD50 Oral - Rat - male and female - 16,750 mg/kg (OECD Test Guideline 401)
Symptoms: Nausea
LC50 Inhalation - Rat - male - 259.35 mg/l - vapor (OECD Test Guideline 403)
Symptoms: Irritation symptoms in the respiratory tract., Inhalation may lead to the formation of oedemas in the respiratory tract.
LD50 Dermal - Rabbit - 3,350 mg/kg (OECD Test Guideline 402)
Skin corrosion/irritation
Symptoms: Nausea
LC50 Inhalation - Rat - male - 259.35 mg/l - vapor (OECD Test Guideline 403)
Symptoms: Irritation symptoms in the respiratory tract., Inhalation may lead to the formation of oedemas in the respiratory tract.
LD50 Dermal - Rabbit - 3,350 mg/kg (OECD Test Guideline 402)
Remarks: Causes skin irritation.
Serious eye damage/eye irritation
Remarks: Possible damages:
Risk of corneal clouding.
Respiratory or skin sensitization
Risk of corneal clouding.
Classified based on available data. For more details, see section 2
Germ cell mutagenicity
Classified based on available data. For more details, see section 2
Carcinogenicity
Classified based on available data. For more details, see section 2
Reproductive toxicity
Suspected of damaging fertility.
Specific target organ toxicity - single exposure
May cause drowsiness or dizziness. - Central nervous system
Acute oral toxicity - Nausea
Acute inhalation toxicity - Irritation symptoms in the respiratory tract., Inhalation may lead to the formation of oedemas in the respiratory tract.
Specific target organ toxicity - repeated exposure
Acute oral toxicity - Nausea
Acute inhalation toxicity - Irritation symptoms in the respiratory tract., Inhalation may lead to the formation of oedemas in the respiratory tract.
May cause damage to organs through prolonged or repeated exposure.
Aspiration hazard
Aspiration hazard, Aspiration may cause pulmonary edema and pneumonitis.
benzene Acute toxicity
LD50 Oral - Rat - male - > 2,000 mg/kg (OECD Test Guideline 401)
Symptoms: Nausea
LD50 Oral - Rat - male and female - 3,002 mg/kg (OECD Test Guideline 401)
Symptoms: Risk of aspiration upon vomiting., Aspiration may cause pulmonary edema and pneumonitis.
Symptoms: mucosal irritations
LD50 Dermal - Rabbit - 13,630 mg/kg
Remarks: (IUCLID)
Skin corrosion/irritation
Symptoms: Nausea
LD50 Oral - Rat - male and female - 3,002 mg/kg (OECD Test Guideline 401)
Symptoms: Risk of aspiration upon vomiting., Aspiration may cause pulmonary edema and pneumonitis.
Symptoms: mucosal irritations
LD50 Dermal - Rabbit - 13,630 mg/kg
Remarks: (IUCLID)
Skin - Rabbit
Result: irritating (OECD Test Guideline 404)
Remarks: (ECHA)
Serious eye damage/eye irritation
Result: irritating (OECD Test Guideline 404)
Remarks: (ECHA)
Eyes - Rabbit
Result: Irritating to eyes.
(OECD Test Guideline 405)
Remarks: (IUCLID)
Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)
Respiratory or skin sensitization
Result: Irritating to eyes.
(OECD Test Guideline 405)
Remarks: (IUCLID)
Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)
Maximization Test - Guinea pig
Result: negative (OECD Test Guideline 406)
Germ cell mutagenicity
Result: negative (OECD Test Guideline 406)
May cause genetic defects.
Test Type: Ames test
Test system: Escherichia coli/Salmonella typhimurium
Result: negative
Test Type: In vitro mammalian cell gene mutation test
Test system: mouse lymphoma cells
Result: negative
Test Type: Chromosome aberration test in vitro
Test system: Chinese hamster lung cells
Result: negative
Method: OECD Test Guideline 474
Species: Mouse - male - Bone marrow
Result: positive
Carcinogenicity
Test Type: Ames test
Test system: Escherichia coli/Salmonella typhimurium
Result: negative
Test Type: In vitro mammalian cell gene mutation test
Test system: mouse lymphoma cells
Result: negative
Test Type: Chromosome aberration test in vitro
Test system: Chinese hamster lung cells
Result: negative
Method: OECD Test Guideline 474
Species: Mouse - male - Bone marrow
Result: positive
May cause cancer. Positive evidence from human epidemiological studies.
Reproductive toxicity
Classified based on available data. For more details, see section 2
Specific target organ toxicity - single exposure
Classified based on available data. For more details, see section 2
Acute oral toxicity - Nausea
Acute oral toxicity - Risk of aspiration upon vomiting., Aspiration may cause pulmonary edema and pneumonitis.
Acute inhalation toxicity - mucosal irritations
Specific target organ toxicity - repeated exposure
Acute oral toxicity - Nausea
Acute oral toxicity - Risk of aspiration upon vomiting., Aspiration may cause pulmonary edema and pneumonitis.
Acute inhalation toxicity - mucosal irritations
Causes damage to organs through prolonged or repeated exposure.
- Blood
Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)
Aspiration hazard
- Blood
Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)
Aspiration may cause pulmonary edema and pneumonitis.
12.1 Toxicity
MixtureNo data available
12.2 Persistence and degradability
No data available
12.3 Bioaccumulative potential
No data available
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
12.6 Endocrine disrupting properties
No data available
12.7 Other adverse effects
Discharge into the environment must be avoided.
Components 1,1'-Oxybis(butane)
Toxicity to fish flow-through test LC50 - Pimephales promelas (fathead minnow) - 32.3 mg/l - 96 h (OECD Test Guideline 203)
Toxicity to daphnia semi-static test EC50 - Daphnia magna (Water flea) - > 18.76 and other aquatic mg/l - 48 h invertebrates (OECD Test Guideline 202)
Toxicity to algae static test ErC50 - Pseudokirchneriella subcapitata (green algae) - ca. 19.1 mg/l - 72 h (OECD Test Guideline 201)
Toxicity to bacteria static test EC50 - activated sludge - > 1,000 mg/l - 30 min (OECD Test Guideline 209)
Remarks: (above the solubility limit in the test medium)
phenyllithium
Toxicity to daphnia semi-static test EC50 - Daphnia magna (Water flea) - > 18.76 and other aquatic mg/l - 48 h invertebrates (OECD Test Guideline 202)
Toxicity to algae static test ErC50 - Pseudokirchneriella subcapitata (green algae) - ca. 19.1 mg/l - 72 h (OECD Test Guideline 201)
Toxicity to bacteria static test EC50 - activated sludge - > 1,000 mg/l - 30 min (OECD Test Guideline 209)
Remarks: (above the solubility limit in the test medium)
No data available
biphenyl
Toxicity to fish flow-through test LC50 - Pimephales promelas (fathead minnow) - 3 mg/l - 96 h (OECD Test Guideline 203)
Toxicity to daphnia flow-through test EC50 - Daphnia magna (Water flea) - 0.36 and other aquatic mg/l - 48 h invertebrates (US-EPA)
Toxicity to flow-through test NOEC - Oncorhynchus mykiss (rainbow trout) fish(Chronic toxicity) - 0.229 mg/l - 87 d (OECD Test Guideline 210)
Toxicity to daphnia Remarks: No data available and other aquatic invertebrates(Chronic toxicity)
Hydrocarbons, C6, n-alkanes, isoalkanes, cyclics, n-hexane rich
Toxicity to daphnia flow-through test EC50 - Daphnia magna (Water flea) - 0.36 and other aquatic mg/l - 48 h invertebrates (US-EPA)
Toxicity to flow-through test NOEC - Oncorhynchus mykiss (rainbow trout) fish(Chronic toxicity) - 0.229 mg/l - 87 d (OECD Test Guideline 210)
Toxicity to daphnia Remarks: No data available and other aquatic invertebrates(Chronic toxicity)
No data available
benzene
Toxicity to fish semi-static test LC50 - Oryzias latipes (Orange-red killifish) - > 100 mg/l - 96 h (OECD Test Guideline 203)
Toxicity to daphnia semi-static test EC50 - Daphnia magna (Water flea) - > 1,000 and other aquatic mg/l - 48 h invertebrates (OECD Test Guideline 202) semi-static test NOEC - Daphnia magna (Water flea) - > 1,000 mg/l - 48 h (OECD Test Guideline 202)
Toxicity to algae static test ErC50 - Pseudokirchneriella subcapitata (green algae) - > 1,000 mg/l - 72 h (OECD Test Guideline 201) static test NOEC - Pseudokirchneriella subcapitata (green algae) - >= 1,000 mg/l - 72 h (OECD Test Guideline 201)
Toxicity to bacteria static test EC50 - activated sludge - > 1,000 mg/l - 3 h (OECD Test Guideline 209)
Toxicity to flow-through test NOEC - Pimephales promelas (fathead fish(Chronic toxicity) minnow) - 0.8 mg/l - 32 d
Remarks: (ECHA)
Toxicity to daphnia semi-static test LC50 - Daphnia magna (Water flea) - > 100 and other aquatic mg/l - 21 d invertebrates(Chronic (OECD Test Guideline 211) toxicity)
Toxicity to daphnia semi-static test EC50 - Daphnia magna (Water flea) - > 1,000 and other aquatic mg/l - 48 h invertebrates (OECD Test Guideline 202) semi-static test NOEC - Daphnia magna (Water flea) - > 1,000 mg/l - 48 h (OECD Test Guideline 202)
Toxicity to algae static test ErC50 - Pseudokirchneriella subcapitata (green algae) - > 1,000 mg/l - 72 h (OECD Test Guideline 201) static test NOEC - Pseudokirchneriella subcapitata (green algae) - >= 1,000 mg/l - 72 h (OECD Test Guideline 201)
Toxicity to bacteria static test EC50 - activated sludge - > 1,000 mg/l - 3 h (OECD Test Guideline 209)
Toxicity to flow-through test NOEC - Pimephales promelas (fathead fish(Chronic toxicity) minnow) - 0.8 mg/l - 32 d
Remarks: (ECHA)
Toxicity to daphnia semi-static test LC50 - Daphnia magna (Water flea) - > 100 and other aquatic mg/l - 21 d invertebrates(Chronic (OECD Test Guideline 211) toxicity)
13.1 Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company.
Offer surplus and non-recyclable solutions to a licensed disposal company.
14.1 UN number
ADR/RID: 2920
IMDG: 2920
IATA-DGR: 2920
IMDG: 2920
IATA-DGR: 2920
14.2 UN proper shipping name
ADR/RID: CORROSIVE LIQUID, FLAMMABLE, N.O.S. (phenyllithium)
IMDG: CORROSIVE LIQUID, FLAMMABLE, N.O.S. (phenyllithium)
IATA-DGR: Corrosive liquid, flammable, n.o.s. (phenyllithium)
IMDG: CORROSIVE LIQUID, FLAMMABLE, N.O.S. (phenyllithium)
IATA-DGR: Corrosive liquid, flammable, n.o.s. (phenyllithium)
14.3 Transport hazard class(es)
ADR/RID: 8 (3)
IMDG: 8 (3)
IATA-DGR: 8 (3)
IMDG: 8 (3)
IATA-DGR: 8 (3)
14.4 Packaging group
ADR/RID: II
IMDG: II
IATA-DGR: II
IMDG: II
IATA-DGR: II
14.5 Environmental hazards
ADR/RID: yes
IMDG Marine pollutant: yes
IATA-DGR: no
IMDG Marine pollutant: yes
IATA-DGR: no
14.6 Special precautions for user
Based on chemical properties, choose appropriate tools and conditions of transport.
Transporting tools shall be equipped with appropriate and sufficient firefighting equipment and emergency leaking installations. If transporting by road, please go along the specified route.
Transporting tools shall be equipped with appropriate and sufficient firefighting equipment and emergency leaking installations. If transporting by road, please go along the specified route.
14.7 Incompatible materials
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulatory information
Law on the Prevention and Control of Occupational Diseases
Regulations on Safety Management of Hazardous Chemicals
Catalogue of Hazardous Chemicals : Listed
Measures on the Environmental Administration of New Chemical Substances Registration
Registration/Notification number : B1A222210730 B1A222224913
Downstream users need to comply with the conditions of safe use of the chemical, understand the environmental and health hazard and risk management measures identified on the SDS as well as the local/national regulations concerning the chemical.
Other regulations
Please pay attention on the waste treatment should also comply with local regulations requirement.
Law on the Prevention and Control of Occupational Diseases
Regulations on Safety Management of Hazardous Chemicals
Catalogue of Hazardous Chemicals : Listed
Measures on the Environmental Administration of New Chemical Substances Registration
Registration/Notification number : B1A222210730 B1A222224913
Downstream users need to comply with the conditions of safe use of the chemical, understand the environmental and health hazard and risk management measures identified on the SDS as well as the local/national regulations concerning the chemical.
Other regulations
Please pay attention on the waste treatment should also comply with local regulations requirement.
Abbreviations and acronyms
CAS: Chemical Abstracts Service
TWA: Time-Weighted Average
STEL: Short-Term Exposure Limit
LD50: Lethal Dose 50%
LC50: Lethal Concentration 50%
EC50: Effective Concentration 50%
PEL: Permissible Exposure Limit
TLV: Threshold Limit Value
IMDG: International Maritime Dangerous Goods Code
IATA: International Air Transport Association
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
DOT: US Department of Transportation
NFPA: National Fire Protection Association
NIOSH: National Institute for Occupational Safety and Health
OSHA: Occupational Safety and Health Administration
TWA: Time-Weighted Average
STEL: Short-Term Exposure Limit
LD50: Lethal Dose 50%
LC50: Lethal Concentration 50%
EC50: Effective Concentration 50%
PEL: Permissible Exposure Limit
TLV: Threshold Limit Value
IMDG: International Maritime Dangerous Goods Code
IATA: International Air Transport Association
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
DOT: US Department of Transportation
NFPA: National Fire Protection Association
NIOSH: National Institute for Occupational Safety and Health
OSHA: Occupational Safety and Health Administration
Disclaimer:
The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Users of this MSDS must make independent judgments on the applicability of this SDS. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS.