ChemicalBook--->CAS DataBase List--->2627-86-3

2627-86-3

2627-86-3 Structure

2627-86-3 Structure
IdentificationMore
[Name]

L-1-Phenylethylamine
[CAS]

2627-86-3
[Synonyms]

1-PHENYLETHYLAMINE
(1S)-1-PHENYLETHYLAMINE
L-(-)-1-PHENYLETHYLAMINE
(-)-L-ALPHA-METHYLBENZYLAMINE
L(-)-ALPHA-METHYLBENZYLAMINE
L-ALPHA-METHYLBENZYLAMINE
L-(-)-ALPHA-PHENYLETHYLAMINE
L-ALPHA-PHENYLETHYLAMINE
L-(-)-A-METHYLBENZYLAMINE
L-PHENYLETHYLAMINE
(S)-(-)-1-METHYLBENZYLAMINE
(S)-1-PHENYLETHANAMINE
(S)-(-)-1-PHENYLETHYLAMINE
(S)-1-PHENYLETHYLAMINE
S-ALFA-METHYLBENZYLAMINE
(S)-(-)-ALPHA-METHYLBENZYLAMINE
(S)(-)-ALPHA-PHENETHYLAMINE
S-(-)-ALPHA-PHENYLETHYLAMINE
(S)-(-)-A-METHYLBENZYLAMINE
(-)-alpha-Phenethylamine
[EINECS(EC#)]

220-098-0
[Molecular Formula]

C8H11N
[MDL Number]

MFCD00064406
[Molecular Weight]

121.18
[MOL File]

2627-86-3.mol
Chemical PropertiesBack Directory
[Appearance]

Colorless to light yellow liqui
[Melting point ]

-10 °C
[alpha ]

-40 º (neat)
[Boiling point ]

187 °C(lit.)
[density ]

0.94 g/mL at 25 °C(lit.)
[vapor pressure ]

0.5 mm Hg ( 20 °C)
[refractive index ]

n20/D 1.526(lit.)
[Fp ]

175 °F
[storage temp. ]

2-8°C
[solubility ]

42g/l
[form ]

Liquid
[pka]

9.04±0.10(Predicted)
[color ]

Clear colorless
[PH]

>7 (H2O, 20°C) (undiluted)
[Optical Rotation]

[α]20/D 39°, neat
[Water Solubility ]

slightly soluble
[Sensitive ]

Air Sensitive
[Merck ]

14,6026
[BRN ]

2204907
[InChI]

1S/C8H11N/c1-7(9)8-5-3-2-4-6-8/h2-7H,9H2,1H3/t7-/m0/s1
[InChIKey]

RQEUFEKYXDPUSK-ZETCQYMHSA-N
[SMILES]

C[C@H](N)c1ccccc1
[LogP]

1.31 at 25℃
[CAS DataBase Reference]

2627-86-3(CAS DataBase Reference)
[NIST Chemistry Reference]

Benzenemethanamine, «alpha»-methyl-, (S)-(2627-86-3)
[Storage Precautions]

Air sensitive
[EPA Substance Registry System]

2627-86-3(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)Skull and Crossbones (GHS06)
GHS05,GHS06
[Signal word ]

Danger
[Hazard statements ]

H302-H311-H314
[Precautionary statements ]

P280-P301+P312+P330-P301+P330+P331-P303+P361+P353-P305+P351+P338
[Hazard Codes ]

C,Xi
[Risk Statements ]

R21/22:Harmful in contact with skin and if swallowed .
R34:Causes burns.
R35:Causes severe burns.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S27:Take off immediately all contaminated clothing .
[RIDADR ]

UN 2922 8/PG 2
[WGK Germany ]

1
[RTECS ]

DP5775000
[F ]

3-10-23-34
[Autoignition Temperature]

355 °C
[Hazard Note ]

Irritant
[TSCA ]

Yes
[REACH Registrations]

Active
[HazardClass ]

8
[PackingGroup ]

III
[HS Code ]

29214980
[Storage Class]

6.1A - Combustible acute toxic Cat. 1 and 2
very toxic hazardous materials
[Hazard Classifications]

Acute Tox. 3 Dermal
Acute Tox. 4 Oral
Skin Corr. 1B
[Toxicity]

LD50 orally in Rabbit: 980 mg/kg LD50 dermal Rabbit 730 mg/kg
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Sodium hydroxide-->Methanol-->Diethyl ether-->L(+)-Tartaric acid-->DL-alpha-Methylbenzylamine
[Preparation Products]

(R)-(+)-2-Methyl-2-propanesulfinamide-->(S)-(-)-2-Azetidinecarboxylic acid-->(R)-(+)-1,1'-Bi-2-naphthol-->(R)-3-Aminoquinuclidine dihydrochloride-->(S)-(-)-1,1'-Bi-2-naphthol-->(R)-(+)-Bornylamine-->Esfenvalerate-->(-)-Bis[(S)-1-phenylethyl]amine hydrochloride-->(S)-(-)-N-Benzyl-1-phenylethylamine-->(-)-Bis[(S)-1-phenylethyl]amine-->(R)-(+)-N-Benzyl-1-phenylethylamine-->(S)-(-)-N,alpha-dimethylbenzylamine-->(S)-(-)-1-Phenylethyl isocyanate-->2,2,2-Trifluoro-N-[(S)-alpha-methylbenzyl]acetamide
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

L(-)-alpha-Methylbenzylamine(2627-86-3).msds
Hazard InformationBack Directory
[Chemical Properties]

Colorless to light yellow liqui
[Uses]

L-1-Phenylethylamine can be used in a one-pot, multi-component synthesis of a highly substituted, chiral pyrrole
[Definition]

ChEBI: The (S)-enantiomer of 1-phenylethanamine.
[General Description]

(S)-(?)-α-Methylbenzylamine is a chiral derivatizing agent, which is employed for derivatizing enantiomers into diastereoisomers.
[Flammability and Explosibility]

Nonflammable
[Toxics Screening Level]

The ITSL for L-alpha-phenylethylamine is 0.1 μg/m3 based on an annual averaging time.
Spectrum DetailBack Directory
[Spectrum Detail]

L-1-Phenylethylamine(2627-86-3)MS
L-1-Phenylethylamine(2627-86-3)1HNMR
L-1-Phenylethylamine(2627-86-3)13CNMR
L-1-Phenylethylamine(2627-86-3)IR1
L-1-Phenylethylamine(2627-86-3)IR2
L-1-Phenylethylamine(2627-86-3)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

L(-)-alpha-Methylbenzylamine, 99+%, (99% ee)(2627-86-3)
[Alfa Aesar]

(S)-(-)-1-Phenylethylamine, ChiPros 99+%, ee 99.5%(2627-86-3)
[Sigma Aldrich]

2627-86-3(sigmaaldrich)
[TCI AMERICA]

(S)-(-)-1-Phenylethylamine,>98.0%(GC)(2627-86-3)
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