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6-Bromo-2-methylquinoline

6-Bromo-2-methylquinoline Structure
6-Bromo-2-methylquinoline structure
CAS No.
877-42-9
Chemical Name:
6-Bromo-2-methylquinoline
Synonyms
6-BROMOQUINALDINE;6-Bromo-2-methyL;6-BROMOQUINAIDINE;6-Bromoquildine, 98%;6-BROMO-2-METHYLQUINOLINE;Quinoline, 6-bromo-2-methyl-;6-Bromo-2-methylquinoline >6-BroMo-2-Methylquinoline, 97+%;6-Bromo-2-methylquinoline, 97%, OS-2039;6-Bromo-2-methylquinoline ISO 9001：2015 REACH
CBNumber:
CB0156824
Molecular Formula:
C10H8BrN
Molecular Weight:
222.08
MDL Number:
MFCD00079724
MOL File:
877-42-9.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-27 17:20:13
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6-Bromo-2-methylquinoline Properties

Melting point 101-105 °C (lit.)
Boiling point 299.7±20.0 °C(Predicted)
Density 1.488±0.06 g/cm3(Predicted)
storage temp. Sealed in dry,Room Temperature
solubility soluble in Methanol
pka 5.02±0.43(Predicted)
form solid
color Grey
InChI 1S/C10H8BrN/c1-7-2-3-8-6-9(11)4-5-10(8)12-7/h2-6H,1H3
InChIKey SQRYQSKJZVQJAY-UHFFFAOYSA-N
SMILES Cc1ccc2cc(Br)ccc2n1
CAS DataBase Reference 877-42-9(CAS DataBase Reference)
NIST Chemistry Reference 6-Bromoquinaldine(877-42-9)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Corrosion (GHS05)Exclamation Mark (GHS07)Health Hazard (GHS08)
GHS05,GHS07,GHS08
Signal word  Danger
Hazard statements  H302-H315-H317-H318-H334-H335
Precautionary statements  P261-P280-P305+P351+P338-P342+P311
target organs Respiratory system
PPE dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Hazard Codes  Xn,Xi
Risk Statements  22-37/38-42-36/37/38-20/21/22
Safety Statements  26-39-36/37/39-24/25-22
WGK Germany  3
Hazard Note  Irritant
HS Code  29339900
Storage Class 11 - Combustible Solids
Hazard Classifications Acute Tox. 4 Oral
Eye Dam. 1
Resp. Sens. 1
Skin Irrit. 2
Skin Sens. 1
STOT SE 3
NFPA 704
1
2 0

6-Bromo-2-methylquinoline price More Price(50)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 649279 6-Bromo-2-methylquinoline 97% 877-42-9 5g $40.9 2026-04-30 Buy
Sigma-Aldrich 649279 6-Bromo-2-methylquinoline 97% 877-42-9 25g $148 2024-03-01 Buy
TCI Chemical B3039 6-Bromo-2-methylquinoline >98.0%(GC)(T) 877-42-9 5g $90 2026-04-30 Buy
TCI Chemical B3039 6-Bromo-2-methylquinoline >98.0%(GC)(T) 877-42-9 25g $293 2026-04-30 Buy
Activate Scientific AS40529 6-Bromo-2-methylquinoline 98% 877-42-9 5g $36 2026-06-04 Buy
Product number Packaging Price Buy
649279 5g $40.9 Buy
649279 25g $148 Buy
B3039 5g $90 Buy
B3039 25g $293 Buy
AS40529 5g $36 Buy

6-Bromo-2-methylquinoline Chemical Properties, Uses, Production

Chemical Properties

white to light yellow crystal powder

Synthesis

4-Bromoaniline

106-40-1

Crotonaldehyde

123-73-9

6-Bromo-2-methylquinoline

877-42-9

GENERAL METHOD: 4-Bromoaniline (1.50 mmol) and trans-2-butenal (1.00 mmol) were dissolved in 1.5 mL of ether (Et2O) in a reaction flask fitted with a magnetic stir bar, followed by the addition of silver(I)-exchanged montmorillonite K10 (0.50 g). After stirring for 5 min, the solvent was removed under vacuum to obtain a dry powder. The reaction mixture was heated at 120 °C for 3 hours. After the reaction mixture was cooled to room temperature, it was filtered through a short silica gel plug and the solid residue was washed well with dichloromethane (CH2Cl2). After removal of the solvent under vacuum, the crude product was purified by silica gel column chromatography, eluting using a solvent mixture of hexane/ethyl acetate (EtOAc) to give the final 6-bromo-2-methylquinoline (3a-3k). Note: For recycling/reuse studies, the crude product is separated by gravity filtration and the clay material is washed several times with dichloromethane (CH2Cl2), air-dried and weighed. The process is repeated for successive recycling/reuse reactions.

References

[1] Advanced Functional Materials, 2012, vol. 22, # 2, p. 345 - 352
[2] Heterocycles, 2016, vol. 92, # 12, p. 2213 - 2224
[3] Tetrahedron Letters, 2011, vol. 52, # 22, p. 2840 - 2843
[4] Chemical Communications, 2012, vol. 48, # 35, p. 4196 - 4198
[5] Dalton Transactions, 2012, vol. 41, # 20, p. 6189 - 6194

6-Bromo-2-methylquinoline synthesis

106-40-1
123-73-9
877-42-9
Synthesis of 6-Bromo-2-methylquinoline from 4-Bromoaniline and Crotonaldehyde (trans predominantly)

6-Bromo-2-methylquinoline Preparation Products And Raw materials

Raw materials

Bis[(pinacolato)boryl]Methane 2-Amino-5-bromobenzaldehyde Ethyl vinyl ether 6-Bromoquinoline Formaldehyde
6-bromo-1-oxido-quinoline Crotonaldehyde (trans predominantly) Ethanol 4-Bromoaniline

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Preparation Products

Methyl 6-bromoquinoline-2-carboxylate 6-Bromoquinoline-2-carboxylic acid 6-Fluoroquinaldine 6-ethynyl-2-methylquinoline 6-Bromo-quinoline-2-carboxylic acid amide

6-Bromo-2-methylquinoline Suppliers

Global Suppliers ( 218)
Supplier Tel Email Country ProdList Advantage
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
INTATRADE GmbH +49 3493/605464 sales@intatrade.de Germany 3563 66
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24512 81
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Carbott PharmTech Inc. 0535-6385396 info@carbottpharm.com China 996 56
Wuhan Chemwish Technology Co., Ltd 86-027-67849912 sales@chemwish.com China 35884 56
Capot Chemical Co., Ltd +86 (0) 571 85 58 67 18 China 18187 66
JinYan Chemicals(ShangHai) Co.,Ltd. 13817811078 sales@jingyan-chemical.com China 9963 60
Supplier Advantage
J & K SCIENTIFIC LTD. 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 62
INTATRADE GmbH 66
Alfa Aesar 84
TCI (Shanghai) Development Co., Ltd. 81
Energy Chemical 61
Carbott PharmTech Inc. 56
Wuhan Chemwish Technology Co., Ltd 56
Capot Chemical Co., Ltd 66
JinYan Chemicals(ShangHai) Co.,Ltd. 60

View Latest Price from 6-Bromo-2-methylquinoline manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
6-Bromo-2-methylquinoline pictures 2026-08-20 6-Bromo-2-methylquinoline
877-42-9
 $1.10 1g 99.00% 100 Tons Dideu Industries Group Limited
6-Bromo-2-methylquinoline pictures 2024-02-19 6-Bromo-2-methylquinoline
877-42-9
 $1250.00 1g 98 500 Kg R&D Scientific Inc.
6-Bromo-2-methylquinoline pictures 2023-08-18 6-Bromo-2-methylquinoline
877-42-9
 $10.00 1kg 99% 500t/month Henan Bao Enluo International TradeCo.，LTD

6-Bromo-2-methylquinoline Spectrum

6-Bromo-2-methylquinoline(877-42-9)1HNMR

877-42-9 (6-Bromo-2-methylquinoline) Related Search:

8-Methylquinoline 3-Bromoanisole 4-methylquinoline Quinaldine Cyclohexylmethyl bromide
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6-Bromo-4-hydroxy-2-(trifluoromethyl)quinoline Bromine Methyl bromide 5-Bromo-2-methylquinoline-4-carboxylic acid 3-Bromo-4-methylquinoline
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6-BROMOQUINAIDINE 6-BROMO-2-METHYLQUINOLINE 6-BROMOQUINALDINE 6-Bromoquinaldine, 6-Bromo-2-methyl-1-azanaphthalene 6-BroMo-2-Methylquinoline, 97+% Quinoline, 6-bromo-2-methyl- 6-Bromoquildine, 98% 6-Bromo-2-methylquinoline > 6-Bromo-2-methyL 6-Bromo-2-methylquinoline ISO 9001：2015 REACH 6-Bromo-2-methylquinoline, 97%, OS-2039 877-42-9 Quinolines Halogenated Heterocycles Heterocyclic Building Blocks Building Blocks Quinoline&Isoquinoline Alkylquinolines Haloquinolines Quinolines Building Blocks Halogenated Heterocycles Heterocyclic Building Blocks QuinolinesHeterocyclic Building Blocks