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2,4,6-Tris(bromomethyl)mesitylene

2,4,6-Tris(bromomethyl)mesitylene Structure
2,4,6-Tris(bromomethyl)mesitylene structure
CAS No.
21988-87-4
Chemical Name:
2,4,6-Tris(bromomethyl)mesitylene
Synonyms
1,3,5-TRIS(BROMOMETHYL)-2,4,6-TRIMETHYLBENZENE;JACS-21988-87-4;Einecs 244-697-1;2,4,6-Tris(bromometh;2,4,6-Tris(brommethyl)mesitylen;2,4,6-TRIS(BROMOMETHYL)MESITYLENE;2,4,6-tribromethyltrimethylbenzene;2,4,6-Tris(bromomethyl)mesitylene 98%;2,4,6-Tribromomethyl-1,3,5-trimethylbenzene;1,3,5-tris(brommethyl)-2,4,6-trimethylbenzol
CBNumber:
CB0218395
Molecular Formula:
C12H15Br3
Molecular Weight:
398.96
MDL Number:
MFCD00192554
MOL File:
21988-87-4.mol
MSDS File:
SDS
Last updated:2026-05-27 17:25:09
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2,4,6-Tris(bromomethyl)mesitylene Properties

Melting point 187-189 °C (lit.)
Boiling point 399.8±37.0 °C(Predicted)
Density 1.759±0.06 g/cm3(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form powder to crystal
color White to Almost white
InChI InChI=1S/C12H15Br3/c1-7-10(4-13)8(2)12(6-15)9(3)11(7)5-14/h4-6H2,1-3H3
InChIKey BHIFXIATEXVOQA-UHFFFAOYSA-N
SMILES C1(CBr)=C(C)C(CBr)=C(C)C(CBr)=C1C
CAS DataBase Reference 21988-87-4(CAS DataBase Reference)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Corrosion (GHS05)Exclamation Mark (GHS07)
GHS05,GHS07
Signal word  Danger
Hazard statements  H302+H312+H332-H314
Precautionary statements  P260-P280-P301+P312-P303+P361+P353-P304+P340+P310-P305+P351+P338
PPE Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Hazard Codes  C,Xi
Risk Statements  20/21/22-34
Safety Statements  22-26-27-36/37/39-45
RIDADR  UN 3261 8/PG 2
WGK Germany  3
Hazard Note  Irritant
HazardClass  8
PackingGroup  III
HS Code  2903998090
Storage Class 8A - Combustible corrosive hazardous materials
Hazard Classifications Acute Tox. 4 Oral
Eye Dam. 1
Skin Corr. 1B

2,4,6-Tris(bromomethyl)mesitylene price More Price(36)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 388467 2,4,6-Tris(bromomethyl)mesitylene 98% 21988-87-4 5g $122 2026-04-30 Buy
TCI Chemical T1641 1,3,5-Tris(bromomethyl)-2,4,6-trimethylbenzene 21988-87-4 5G $88 2026-04-30 Buy
TCI Chemical T1641 1,3,5-Tris(bromomethyl)-2,4,6-trimethylbenzene 21988-87-4 25G $223 2026-04-30 Buy
Apolloscientific OR30276 1,3,5-Tri(bromomethyl)-2,4,6-trimethylbenzene 97% 21988-87-4 1g $21 2026-06-04 Buy
Apolloscientific OR30276 1,3,5-Tri(bromomethyl)-2,4,6-trimethylbenzene 97% 21988-87-4 5g $24 2026-06-04 Buy
Product number Packaging Price Buy
388467 5g $122 Buy
T1641 5G $88 Buy
T1641 25G $223 Buy
OR30276 1g $21 Buy
OR30276 5g $24 Buy

2,4,6-Tris(bromomethyl)mesitylene Chemical Properties, Uses, Production

Uses

2,4,6-Tribromomethyltrimethylbenzene is used as an organic building block and a general reagent.

Synthesis

Formaldehyde

50-00-0

Mesitylene

108-67-8

2,4,6-Tris(bromomethyl)mesitylene

21988-87-4

Under nitrogen atmosphere, 1,3,5-trimethylbenzene (0.7 mL, 5 mmol) was added to the reaction vial, followed by the sequential addition of acetic acid (2.6 mL) and 33% wt solution of hydrobromic acid acetic acid (3.5 mL). Next, paraformaldehyde (570 mg, 18.8 mmol, 3.7 equiv) was added. The reaction mixture was stirred at 95 °C. After 3 h, the solid was observed to start precipitating. Stirring of the reaction mixture was continued for 9 h, followed by cooling to room temperature. The reaction mixture was poured into ice water and the solid product was collected by filtration and dried. Recrystallization by mixed solvent recrystallization of dichloromethane and petroleum ether afforded the target compound 2,4,6-tribromomethyltrimethylbenzene as white needle-like crystals (1.99 g, 5 mmol, 99% yield).1H NMR (500 MHz, CDCl3) δ 4.61 (s, 6H), 2.50 (s, 9H).13C NMR (126 MHz, CDCl3) δ 137.84, 133.18, 29.93, 15.38.

References

[1] Journal of Organic Chemistry, 1993, vol. 58, # 5, p. 1262 - 1263
[2] Patent: WO2018/106112, 2018, A1. Location in patent: Page/Page column 70
[3] Synthesis, 1994, # 11, p. 1132 - 1132
[4] Organic Letters, 2009, vol. 11, # 11, p. 2229 - 2232
[5] Tetrahedron Letters, 2013, vol. 54, # 8, p. 771 - 774

2,4,6-Tris(bromomethyl)mesitylene Preparation Products And Raw materials

Raw materials

Formaldehyde Mesitylene

Preparation Products

2,4,6-Trimethylbenzene-1,3,5-tricarbaldehyde

2,4,6-Tris(bromomethyl)mesitylene Suppliers

Global Suppliers ( 151)
Supplier Tel Email Country ProdList Advantage
Beijing Stronger Science Co., Ltd. 0531-88924771 15614660963 elsa.hang@strongerscience.com China 10622 58
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24512 81
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Shijiazhuang Outejia Chemical Co. LTD 0311-87795622 sales@adonghui.com China 54 64
Shanghai Longsheng chemical Co.,Ltd. 58099637 13585536065 sales@shlschem.com China 9880 59
Nanjing Chemlin Chemical Co., Ltd 025-83697070 13770331960 info@chemlin.com.cn China 16306 64
Shanghai Hanhong Scientific Co.,Ltd. 021-54306202 13764082696 info@hanhongsci.com China 42917 64
Syntechem Co.,Ltd info@syntechem.com China 12973 57
Sichuan Kulinan Technology Co., Ltd 400-1166-196 18981987031 cdhxsj@163.com China 11674 57
Supplier Advantage
Beijing Stronger Science Co., Ltd. 58
J & K SCIENTIFIC LTD. 76
TCI (Shanghai) Development Co., Ltd. 81
Energy Chemical 61
Shijiazhuang Outejia Chemical Co. LTD 64
Shanghai Longsheng chemical Co.,Ltd. 59
Nanjing Chemlin Chemical Co., Ltd 64
Shanghai Hanhong Scientific Co.,Ltd. 64
Syntechem Co.,Ltd 57
Sichuan Kulinan Technology Co., Ltd 57

View Latest Price from 2,4,6-Tris(bromomethyl)mesitylene manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2,4,6-Tris(bromomethyl)mesitylene pictures 2026-09-02 2,4,6-Tris(bromomethyl)mesitylene
21988-87-4
 $1.00-100.00 1KG 99% Henan Fengda Chemical Co., Ltd
2,4,6-Tris(bromomethyl)mesitylene pictures 2021-08-12 2,4,6-Tris(bromomethyl)mesitylene
21988-87-4
 $10.00-15.00 1KG 99%+ HPLC Zhuozhou Wenxi import and Export Co., Ltd
1,3,5-Tris(bromomethyl)-2,4,6-trimethylbenzene pictures 2021-07-02 1,3,5-Tris(bromomethyl)-2,4,6-trimethylbenzene
21988-87-4
 $10.00-15.00 1KG 99%+ HPLC Zhuozhou Wenxi import and Export Co., Ltd

2,4,6-Tris(bromomethyl)mesitylene Spectrum

2,4,6-Tris(bromomethyl)mesitylene(21988-87-4)1HNMR2,4,6-Tris(bromomethyl)mesitylene(21988-87-4)Raman

21988-87-4 (2,4,6-Tris(bromomethyl)mesitylene) Related Search:

Tricine 4-Bromomethylbenzoic acid Bromotrimethylsilane 5-Methyl-1H-benzotriazole Mesitylene
2-(Trifluoromethyl)benzoic acid 2-(Trifluoromethyl)benzaldehyde 3-(Trifluoromethyl)benzaldehyde Tris(hydroxymethyl)aminomethane Buffer solution pH = 6,00 (20 °C) (potassium dihydrogen phosphate/sodium hydroxide)
3,5-Dimethylbenzyl bromide 4-Methylbenzyl bromide 1,3,5-Tris(bromomethyl)benzene Trimethyl phloroglucinol 2,4-Dimethylbenzyl bromide
1-(Bromomethyl)-2,3-dimethylbenzene 2,5-Dimethylbenzyl bromide 4-Fluorobenzyl bromide

1of4

1,3,5,5-TRIS(BROMOMETHYL)-2,4,6-TRIMETHYLBENZENE 1,3,5-tris(brommethyl)-2,4,6-trimethylbenzol 1,3,5-TRI(BROMOMETHYL)-2,4,6-TRIMETHYLBENZENE 2,4,6-TRIS(BROMOMETHYL)MESITYLENE 1,3,5-TRIS(BROMOMETHYL)-2,4,6-TRIMETHYLBENZENE 98+% T 2,4,6-Tris(bromomethyl)mesitylene 98% 2,4,6-Tribromomethyl-1,3,5-trimethylbenzene 2,4,6-Trimethyl-1,3,5-tris(bromomethyl)benzene 2,4,6-Tris(bromometh Einecs 244-697-1 JACS-21988-87-4 2,4,6-Tris(brommethyl)mesitylen Benzene, 1,3,5-tris(bromomethyl)-2,4,6-trimethyl- 2,4,6-Tris(bromomethyl)mesitylene ISO 9001：2015 REACH 2,4,6-tribromethyltrimethylbenzene 1,3,5-TRIS(BROMOMETHYL)-2,4,6-TRIMETHYLBENZENE 21988-87-4 CH33C6CH2Br3 C12H15Br3 Building Blocks C9 to C12 Aryl Halogenated Hydrocarbons Organic Building Blocks Aryl C9 to C12 Halogenated Hydrocarbons C9 to C12 Halogenated Hydrocarbons Building Blocks Chemical Synthesis Organic Building Blocks