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3-Bromo-2-hydroxy-5-methylpyridine

CAS No.
17282-02-9
Chemical Name:
3-Bromo-2-hydroxy-5-methylpyridine
Synonyms
3-BROMO-5-METHYLPYRIDIN-2-OL;3-Bromo-2-hydroxy-5-picoline;TIMTEC-BB SBB003679;3-Bromo-5-methyl-2-pyridone;5-Bromo-2-hydroxy-3-picoline;3-Bromo-5-methyl-2-pyridinol;2-HYDROXY-3-BROMO-5-PICOLINE;3-bromo-5-methyl-2(1H)-pyridone;3-Bromo-5-methyl-2-pyridone >3-BROMO-5-METHYL-2(1H)-PYRIDINONE
CBNumber:
CB0237273
Molecular Formula:
C6H6BrNO
Molecular Weight:
188.02
MDL Number:
MFCD03791312
MOL File:
17282-02-9.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-09-12 18:47:42

3-Bromo-2-hydroxy-5-methylpyridine Properties

Melting point 78-82 °C (lit.)
Boiling point 324.0±42.0 °C(Predicted)
Density 1.622±0.06 g/cm3(Predicted)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
pka 10.95±0.10(Predicted)
form powder to crystal
color White to Orange to Green
BRN 1423374
InChI 1S/C6H6BrNO/c1-4-2-5(7)6(9)8-3-4/h2-3H,1H3,(H,8,9)
InChIKey KHBRMXVUQOVORD-UHFFFAOYSA-N
SMILES Cc1cnc(O)c(Br)c1
CAS DataBase Reference 17282-02-9(CAS DataBase Reference)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Corrosion (GHS05)Exclamation Mark (GHS07)
GHS05,GHS07
Signal word  Danger
Hazard statements  H302-H315-H318-H335
Precautionary statements  P280-P301+P312+P330-P302+P352-P305+P351+P338+P310
target organs Respiratory system
PPE dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes  Xn,Xi
Risk Statements  22-37/38-41-36/37/38
Safety Statements  26-36/37/39-36
RIDADR  1993
WGK Germany  3
Hazard Note  Irritant/Keep Cold
PackingGroup  III
HS Code  29333990
Storage Class 11 - Combustible Solids
Hazard Classifications Acute Tox. 4 Oral
Eye Dam. 1
Skin Irrit. 2
STOT SE 3
NFPA 704
1
2 0

3-Bromo-2-hydroxy-5-methylpyridine price More Price(70)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 636371 3-Bromo-2-hydroxy-5-methylpyridine 97% 17282-02-9 1g $170 2023-06-20 Buy
TCI Chemical B3350 3-Bromo-5-methyl-2-pyridone >98.0%(GC)(T) 17282-02-9 1g $188 2026-04-30 Buy
TCI Chemical B3350 3-Bromo-5-methyl-2-pyridone >98.0%(GC)(T) 17282-02-9 5g $749 2026-04-30 Buy
Usbiological 266440 3-Bromo-2-hydroxy-5-methylpyridine Asreported 17282-02-9 2g $333 2026-06-03 Buy
Usbiological 266440 3-Bromo-2-hydroxy-5-methylpyridine Asreported 17282-02-9 5g $483 2026-06-03 Buy
Product number Packaging Price Buy
636371 1g $170 Buy
B3350 1g $188 Buy
B3350 5g $749 Buy
266440 2g $333 Buy
266440 5g $483 Buy

3-Bromo-2-hydroxy-5-methylpyridine Chemical Properties, Uses, Production

Chemical Properties

White solid

Synthesis

2-Hydroxy-5-methylpyridine

1003-68-5

3-BROMO-2-HYDROXY-5-METHYLPYRIDINE

17282-02-9

5-Methylpyridin-2-ol (1 g, 9.16 mmol) was used as starting material and dissolved in 4 mL of carbon disulfide (CS2). Bromine (Br2, 0.47 mL) was slowly added to this solution at room temperature and the reaction mixture was stirred for 2 hours. Upon completion of the reaction, aqueous sodium thiosulfate (Na2S2O3) was added to quench the reaction, followed by extraction of the reaction mixture with ethyl acetate (EtOAc). The organic layer was separated, dried over anhydrous magnesium sulfate (MgSO4) and concentrated under reduced pressure to afford the solid product 3-bromo-2-hydroxy-5-methylpyridine (1.7 g, 98% yield). The structure of the product was confirmed by 1H-NMR (CDCl3): δ 7.73 (1H, s), 7.22 (1H, s), 2.10 (3H, s).

References

[1] Patent: EP3239143, 2017, A2. Location in patent: Paragraph 0168
[2] Patent: US2008/85906, 2008, A1. Location in patent: Page/Page column 15

3-Bromo-2-hydroxy-5-methylpyridine Preparation Products And Raw materials

Raw materials

Preparation Products

Global Suppliers ( 175)
Supplier Tel Email Country ProdList Advantage
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24512 81
Wuhan Chemwish Technology Co., Ltd 86-027-67849912 sales@chemwish.com China 35884 56
Capot Chemical Co., Ltd +86 (0) 571 85 58 67 18 China 18187 66
Shanghai Longsheng chemical Co.,Ltd. 58099637 13585536065 sales@shlschem.com China 9880 59
Shanghai Hanhong Scientific Co.,Ltd. 021-54306202 13764082696 info@hanhongsci.com China 42917 64
Syntechem Co.,Ltd info@syntechem.com China 12973 57
Shenyang Comrade Chemical Co., Ltd. +86(24) 31938773(O) sales@co-chem.com China 225 62

View Latest Price from 3-Bromo-2-hydroxy-5-methylpyridine manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
3-BROMO-2-HYDROXY-5-METHYLPYRIDINE pictures 2026-08-20 3-BROMO-2-HYDROXY-5-METHYLPYRIDINE
17282-02-9
$1.10 1g 99.00% 100 Tons Min Dideu Industries Group Limited
3-BROMO-2-HYDROXY-5-METHYLPYRIDINE pictures 2021-08-12 3-BROMO-2-HYDROXY-5-METHYLPYRIDINE
17282-02-9
$10.00-15.00 1KG 99%+ HPLC Zhuozhou Wenxi import and Export Co., Ltd
3-Bromo-5-methyl-2-pyridone pictures 2021-07-02 3-Bromo-5-methyl-2-pyridone
17282-02-9
$10.00-15.00 1KG 99%+ HPLC Zhuozhou Wenxi import and Export Co., Ltd
3-BROMO-5-METHYL-2(1H)-PYRIDINONE TIMTEC-BB SBB003679 2-HYDROXY-3-BROMO-5-PICOLINE 3-Bromo-2-hydroxy-5-methylpyridine 98% 3-Bromo-2-hydroxy-5-picoline 17282-02-9 3-BROMO-2-HYDROXY-5-PICOLINE (3-BROMO-2-HYDROXY-5-METHYLPYRIDINE) 3-Bromo-5-methyl-2-pyridone 3-Bromo-5-methyl-2-pyridinol 5-Bromo-2-hydroxy-3-picoline 2-HYDROXY-3-BROMO-5-METHYLPYRIDINE 3-BroMo-5-Methyl-1H-pyridin-2-one 3-Bromo-5-methylpyridin-2-ol, 5-Bromo-6-hydroxy-3-picoline 3-Bromo-5-methyl-2-pyridinol 3-Bromo-2-hydroxy-5-methylpyridine 2(1H)-Pyridinone,3-broMo-5-Methyl- 3-bromo-5-methyl-2(1H)-pyridone JR-8301, 3-Bromo-2-hydroxy-5-methylpyridine, 97% 3-Bromo-5-methyl-2-pyridone > 3-BROMO-2-HYDROXY-5-METHYLPYRIDINE ISO 9001:2015 REACH 3-BROMO-5-METHYLPYRIDIN-2-OL 3-Bromo-2-hydroxy-5-picoline 3-Bromo-2-hydroxy-5-methylpyridine 17282-02-9 17282-020-9 Pyridines Heterocyclic Building Blocks Halogenated Heterocycles Building Blocks C6Heterocyclic Building Blocks Halogenated Heterocycles Heterocyclic Building Blocks blocks Bromides Pyridines Pyridine