3-Bromo-2-hydroxy-5-methylpyridine
- CAS No.
- 17282-02-9
- Chemical Name:
- 3-Bromo-2-hydroxy-5-methylpyridine
- Synonyms
- 3-BROMO-5-METHYLPYRIDIN-2-OL;3-Bromo-2-hydroxy-5-picoline;TIMTEC-BB SBB003679;3-Bromo-5-methyl-2-pyridone;5-Bromo-2-hydroxy-3-picoline;3-Bromo-5-methyl-2-pyridinol;2-HYDROXY-3-BROMO-5-PICOLINE;3-bromo-5-methyl-2(1H)-pyridone;3-Bromo-5-methyl-2-pyridone >3-BROMO-5-METHYL-2(1H)-PYRIDINONE
- CBNumber:
- CB0237273
- Molecular Formula:
- C6H6BrNO
- Molecular Weight:
- 188.02
- MDL Number:
- MFCD03791312
- MOL File:
- 17282-02-9.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Melting point | 78-82 °C (lit.) |
|---|---|
| Boiling point | 324.0±42.0 °C(Predicted) |
| Density | 1.622±0.06 g/cm3(Predicted) |
| storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
| pka | 10.95±0.10(Predicted) |
| form | powder to crystal |
| color | White to Orange to Green |
| BRN | 1423374 |
| InChI | 1S/C6H6BrNO/c1-4-2-5(7)6(9)8-3-4/h2-3H,1H3,(H,8,9) |
| InChIKey | KHBRMXVUQOVORD-UHFFFAOYSA-N |
| SMILES | Cc1cnc(O)c(Br)c1 |
| CAS DataBase Reference | 17282-02-9(CAS DataBase Reference) |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) | ![]() ![]() GHS05,GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H302-H315-H318-H335 | |||||||||
| Precautionary statements | P280-P301+P312+P330-P302+P352-P305+P351+P338+P310 | |||||||||
| target organs | Respiratory system | |||||||||
| PPE | dust mask type N95 (US), Eyeshields, Gloves | |||||||||
| Hazard Codes | Xn,Xi | |||||||||
| Risk Statements | 22-37/38-41-36/37/38 | |||||||||
| Safety Statements | 26-36/37/39-36 | |||||||||
| RIDADR | 1993 | |||||||||
| WGK Germany | 3 | |||||||||
| Hazard Note | Irritant/Keep Cold | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29333990 | |||||||||
| Storage Class | 11 - Combustible Solids | |||||||||
| Hazard Classifications | Acute Tox. 4 Oral Eye Dam. 1 Skin Irrit. 2 STOT SE 3 |
|||||||||
| NFPA 704 |
|
3-Bromo-2-hydroxy-5-methylpyridine price More Price(70)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 636371 | 3-Bromo-2-hydroxy-5-methylpyridine 97% | 17282-02-9 | 1g | $170 | 2023-06-20 | Buy |
| TCI Chemical | B3350 | 3-Bromo-5-methyl-2-pyridone >98.0%(GC)(T) | 17282-02-9 | 1g | $188 | 2026-04-30 | Buy |
| TCI Chemical | B3350 | 3-Bromo-5-methyl-2-pyridone >98.0%(GC)(T) | 17282-02-9 | 5g | $749 | 2026-04-30 | Buy |
| Usbiological | 266440 | 3-Bromo-2-hydroxy-5-methylpyridine Asreported | 17282-02-9 | 2g | $333 | 2026-06-03 | Buy |
| Usbiological | 266440 | 3-Bromo-2-hydroxy-5-methylpyridine Asreported | 17282-02-9 | 5g | $483 | 2026-06-03 | Buy |
3-Bromo-2-hydroxy-5-methylpyridine Chemical Properties, Uses, Production
Chemical Properties
White solid
Synthesis
1003-68-5
17282-02-9
5-Methylpyridin-2-ol (1 g, 9.16 mmol) was used as starting material and dissolved in 4 mL of carbon disulfide (CS2). Bromine (Br2, 0.47 mL) was slowly added to this solution at room temperature and the reaction mixture was stirred for 2 hours. Upon completion of the reaction, aqueous sodium thiosulfate (Na2S2O3) was added to quench the reaction, followed by extraction of the reaction mixture with ethyl acetate (EtOAc). The organic layer was separated, dried over anhydrous magnesium sulfate (MgSO4) and concentrated under reduced pressure to afford the solid product 3-bromo-2-hydroxy-5-methylpyridine (1.7 g, 98% yield). The structure of the product was confirmed by 1H-NMR (CDCl3): δ 7.73 (1H, s), 7.22 (1H, s), 2.10 (3H, s).
References
[1] Patent: EP3239143, 2017, A2. Location in patent: Paragraph 0168
[2] Patent: US2008/85906, 2008, A1. Location in patent: Page/Page column 15
3-Bromo-2-hydroxy-5-methylpyridine Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
| Wuhan Chemwish Technology Co., Ltd | 86-027-67849912 | sales@chemwish.com | China | 35884 | 56 |
| Capot Chemical Co., Ltd | +86 (0) 571 85 58 67 18 | China | 18187 | 66 | |
| Shanghai Longsheng chemical Co.,Ltd. | 58099637 13585536065 | sales@shlschem.com | China | 9880 | 59 |
| Shanghai Hanhong Scientific Co.,Ltd. | 021-54306202 13764082696 | info@hanhongsci.com | China | 42917 | 64 |
| Syntechem Co.,Ltd | info@syntechem.com | China | 12973 | 57 | |
| Shenyang Comrade Chemical Co., Ltd. | +86(24) 31938773(O) | sales@co-chem.com | China | 225 | 62 |
View Latest Price from 3-Bromo-2-hydroxy-5-methylpyridine manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
![]() |
2026-08-20 | 3-BROMO-2-HYDROXY-5-METHYLPYRIDINE
17282-02-9
|
$1.10 | 1g | 99.00% | 100 Tons Min | Dideu Industries Group Limited | |
![]() |
2021-08-12 | 3-BROMO-2-HYDROXY-5-METHYLPYRIDINE
17282-02-9
|
$10.00-15.00 | 1KG | 99%+ HPLC | Zhuozhou Wenxi import and Export Co., Ltd | ||
![]() |
2021-07-02 | 3-Bromo-5-methyl-2-pyridone
17282-02-9
|
$10.00-15.00 | 1KG | 99%+ HPLC | Zhuozhou Wenxi import and Export Co., Ltd |
-

- 3-BROMO-2-HYDROXY-5-METHYLPYRIDINE
17282-02-9
- $1.10
- 99.00%
- Dideu Industries Group Limited
-

- 3-BROMO-2-HYDROXY-5-METHYLPYRIDINE
17282-02-9
- $10.00-15.00
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
-

- 3-Bromo-5-methyl-2-pyridone
17282-02-9
- $10.00-15.00
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
17282-02-9 (3-Bromo-2-hydroxy-5-methylpyridine) Related Search:
1of4






