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1-(2-Bromoethyl)-4-fluorobenzene

1-(2-Bromoethyl)-4-fluorobenzene Structure
1-(2-Bromoethyl)-4-fluorobenzene structure
CAS No.
332-42-3
Chemical Name:
1-(2-Bromoethyl)-4-fluorobenzene
Synonyms
4-FLUOROPHENETHYL BROMIDE;4-Fluorophenylethyl broMide;4-Fluorophenethyl bromide,97%;4-Fluorophenethyl bromide 97%;2-(4-FLUOROPHENYL)ETHYL BROMIDE;4-FLUORO-1-(2-BROMOETHYL)BENZENE;1-BROMO-2-(4-FLUOROPHENYL)ETHANE;1-FLUORO-4-(2-BROMOETHYL)BENZENE;4-(2-BroMoethyl)-1-fluorobenzene;1-(2-Bromoethyl)-4-fluorobenzene
CBNumber:
CB0280259
Molecular Formula:
C8H8BrF
Molecular Weight:
203.05
MDL Number:
MFCD03844794
MOL File:
332-42-3.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-09-12 18:48:05
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1-(2-Bromoethyl)-4-fluorobenzene Properties

Boiling point 100-104 °C15 mm Hg(lit.)
Density 1.4498 g/mL at 25 °C(lit.)
refractive index n20/D 1.534(lit.)
Flash point 200 °F
storage temp. Sealed in dry,Room Temperature
form Liquid or Low Melting Solid
color Clear colorless to light yellow or white to pale yellow
InChI 1S/C8H8BrF/c9-6-5-7-1-3-8(10)4-2-7/h1-4H,5-6H2
InChIKey FLRUNCJXOVYWDH-UHFFFAOYSA-N
SMILES Fc1ccc(CCBr)cc1
CAS DataBase Reference 332-42-3(CAS DataBase Reference)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)Environment (GHS09)
GHS07,GHS09
Signal word  Warning
Hazard statements  H302-H411
Precautionary statements  P264-P270-P273-P301+P312-P391-P501
PPE Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes  Xn,N
Risk Statements  22-51/53
Safety Statements  61
RIDADR  UN 3082 9 / PGIII
WGK Germany  2
HazardClass  9
HS Code  29039990
Storage Class 10 - Combustible liquids
Hazard Classifications Acute Tox. 4 Oral
Limited Quantities 5.0 kg (11 lbs) (solid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)
NFPA 704
1
1 0

1-(2-Bromoethyl)-4-fluorobenzene price More Price(55)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 652008 4-Fluorophenethyl bromide 97% 332-42-3 5g $73.5 2023-01-07 Buy
TCI Chemical F0431 2-(4-Fluorophenyl)ethyl Bromide >95.0%(GC) 332-42-3 1g $30 2026-04-30 Buy
TCI Chemical F0431 2-(4-Fluorophenyl)ethyl Bromide >95.0%(GC) 332-42-3 5g $99 2026-04-30 Buy
Biosynth FF23447 4-Fluorophenethyl bromide 332-42-3 50g $900 2026-06-04 Buy
Biosynth FF23447 4-Fluorophenethyl bromide 332-42-3 100g $900 2026-06-04 Buy
Product number Packaging Price Buy
652008 5g $73.5 Buy
F0431 1g $30 Buy
F0431 5g $99 Buy
FF23447 50g $900 Buy
FF23447 100g $900 Buy

1-(2-Bromoethyl)-4-fluorobenzene Chemical Properties,Uses,Production

Chemical Properties

Clear slightly yellow liquid

Uses

An intermediate in the production of protein A mimetics, serotonin antagonists, and other CNS agents

Synthesis

4-Fluorophenethyl alcohol

7589-27-7

1-(2-BROMOETHYL)-4-FLUOROBENZENE

332-42-3

Preparative Example 1 Synthesis of 4-fluorophenethyl bromide: Triphenylphosphine (222 g) and N-bromosuccinimide (151 g) were sequentially added to a solution of 4-fluorophenylethanol (100 g) in dichloromethane (1 L) under cooling conditions in an ice bath and the reaction was carried out with continuous stirring for 1 hour. Upon completion of the reaction, the resulting solution was concentrated under reduced pressure and the precipitated crystals were subsequently filtered. The filtrate was further concentrated to afford the target product 4-fluorobromoethylbenzene (133 g) as a colorless oil (yield: 92%). The product was characterized by 1H-NMR (400 MHz, CDCl3): δ (ppm) 3.14 (2H, t, J = 8 Hz), 3.54 (2H, t, J = 8 Hz), 6.98-7.03 (2H, m), 7.15-7.18 (2H, m).

References

[1] Journal of Organic Chemistry, 2006, vol. 71, # 18, p. 7035 - 7044
[2] Tetrahedron Asymmetry, 2001, vol. 12, # 4, p. 585 - 596
[3] Patent: US2002/19531, 2002, A1
[4] Bioorganic and Medicinal Chemistry, 2009, vol. 17, # 8, p. 2989 - 3002
[5] Patent: EP2508526, 2012, A1. Location in patent: Page/Page column 48

1-(2-Bromoethyl)-4-fluorobenzene Preparation Products And Raw materials

Raw materials

4-Fluorophenethyl alcohol N-Bromosuccinimide Triphenylphosphine Dichloromethane

Preparation Products

1-(2-Bromoethyl)-4-fluorobenzene Suppliers

Global( 175)Suppliers
Supplier Tel Email Country ProdList Advantage
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24512 81
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Changzhou Huanling Chemical Co., Ltd. 89803005 18206112582 info@huanlingchem.com China 983 68
Adamas Reagent, Ltd. 400-6009262 15618770481 yhx@titansci.com China 14098 59
Accela ChemBio Co.,Ltd. 021-50795510 4000665055 marketing@accelachem.com China 10972 64
Shanghai Longsheng chemical Co.,Ltd. 58099637 13585536065 sales@shlschem.com China 9880 59
Shanghai Harvest Chemical Industrial Co., Ltd. 15721252604 17321035817 sales@harvest-chem.com China 2829 64
Shanghai Hanhong Scientific Co.,Ltd. 021-54306202 13764082696 info@hanhongsci.com China 42917 64
Supplier Advantage
J & K SCIENTIFIC LTD. 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 62
TCI (Shanghai) Development Co., Ltd. 81
Energy Chemical 61
Changzhou Huanling Chemical Co., Ltd. 68
Adamas Reagent, Ltd. 59
Accela ChemBio Co.,Ltd. 64
Shanghai Longsheng chemical Co.,Ltd. 59
Shanghai Harvest Chemical Industrial Co., Ltd. 64
Shanghai Hanhong Scientific Co.,Ltd. 64

View Lastest Price from 1-(2-Bromoethyl)-4-fluorobenzene manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
1-(2-BROMOETHYL)-4-FLUOROBENZENE pictures 2026-09-02 1-(2-BROMOETHYL)-4-FLUOROBENZENE
332-42-3
 $1.00-100.00 1KG 99% Henan Fengda Chemical Co., Ltd
1-(2-BROMOETHYL)-4-FLUOROBENZENE pictures 2021-08-12 1-(2-BROMOETHYL)-4-FLUOROBENZENE
332-42-3
 $10.00-15.00 1KG 99%+ HPLC Zhuozhou Wenxi import and Export Co., Ltd
2-(4-Fluorophenyl)ethyl Bromide pictures 2021-07-02 2-(4-Fluorophenyl)ethyl Bromide
332-42-3
 $10.00-15.00 1KG 99%+ HPLC Zhuozhou Wenxi import and Export Co., Ltd

1-(2-Bromoethyl)-4-fluorobenzene Spectrum

1-(2-BROMOETHYL)-4-FLUOROBENZENE(332-42-3)1HNMR

332-42-3(1-(2-Bromoethyl)-4-fluorobenzene)Related Search:

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1-(1-bromoethyl)-4-fluorobenzene 2-Bromo-3-(4-fluoro-3-methylphenyl)prop-1-ene 2-BROMO-2-PHENYL-1-(γ-FLUOROPHENYL)-ETHANONE 2-Bromo-3-(3,4-difluorophenyl)-1-propene 2-Bromo-3-(3-chloro-4-fluorophenyl)-1-propene
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1-FLUORO-4-(2-BROMOETHYL)BENZENE 1-BROMO-2-(4-FLUOROPHENYL)ETHANE 2-(4-FLUOROPHENYL)ETHYL BROMIDE 4-FLUORO-1-(2-BROMOETHYL)BENZENE 4-FLUOROPHENETHYL BROMIDE 1-(2-Bromoethyl)-4-fluoroBenzene,4-FluorophenethylBromide 1-Bromo-2-(4-fluorophenyl)ethane 97% 1-Bromo-2-(4-fluorophenyl)ethane97% 1-Fluoro-4-(2-bromoethyl)benzene, 4-Fluoro-1-(2-bromoethyl)benzene 4-Fluorophenethyl bromide 97% 4-Fluorophenethyl bromide,97% 1-(2-Bromoethyl)-4-fluorobenzene, 1-Bromo-2-(4-fluorophenyl)ethane 4-(2-BroMoethyl)-1-fluorobenzene 1-(2-Bromoethyl)-4-fluorobenzene 1-Bromo-2-(4-fluorophenyl)ethane 4-Fluorophenethyl Bromide 4-Fluorophenylethyl broMide 2-(4-Fluorophenyl)ethylBromide> Benzene, 1-(2-bromoethyl)-4-fluoro- 1-(2-BROMOETHYL)-4-FLUOROBENZENE ISO 9001：2015 REACH 1-(2-Bromoethyl)-4-fluorobenzene 332-42-3 FC6H4CH2CH2Br Halogenated Hydrocarbons Organic Building Blocks Building Blocks Aryl C8 Fluorine series Aromatics Intermediates & Fine Chemicals Pharmaceuticals