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ChemicalBook >> CAS DataBase List >>2-[4-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]oxyphenoxy]propanoic acid

2-[4-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]oxyphenoxy]propanoic acid

2-[4-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]oxyphenoxy]propanoic acid Structure
2-[4-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]oxyphenoxy]propanoic acid structure
CAS No.
69806-34-4
Chemical Name:
2-[4-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]oxyphenoxy]propanoic acid
Synonyms
HALOXYFOP;Haloxyfop (free acid);DOWCO453;AI3-27257;Halossifop;(±)-Haloxyfop;Haloxyfop (fre;UNII-7O9EWV477R;HALOXYFOP PESTANAL,;2-[4-[3-chloro-5-(tr
CBNumber:
CB1118535
Molecular Formula:
C15H11ClF3NO4
Molecular Weight:
361.7
MDL Number:
MFCD00871401
MOL File:
69806-34-4.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-07-31 15:25:14
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2-[4-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]oxyphenoxy]propanoic acid Properties

Melting point 107.5 °C
Boiling point 420.3±45.0 °C(Predicted)
Density 1.442±0.06 g/cm3(Predicted)
storage temp. 0-6°C
solubility DMSO : 100 mg/mL (276.47 mM; Need ultrasonic)
pka 3.12±0.10(Predicted)
form Solid
color White to off-white
BRN 1507817
Major Application agriculture
environmental
InChI 1S/C15H11ClF3NO4/c1-8(14(21)22)23-10-2-4-11(5-3-10)24-13-12(16)6-9(7-20-13)15(17,18)19/h2-8H,1H3,(H,21,22)
InChIKey GOCUAJYOYBLQRH-UHFFFAOYSA-N
SMILES CC(Oc1ccc(Oc2ncc(cc2Cl)C(F)(F)F)cc1)C(O)=O
CAS DataBase Reference 69806-34-4(CAS DataBase Reference)
FDA UNII 24TYO6H90H
EPA Substance Registry System Haloxyfop (69806-34-4)
UNSPSC Code 41116107
NACRES NA.24

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)Corrosion (GHS05)
GHS07,GHS05
Signal word  Danger
Hazard statements  H302-H318-H412
Precautionary statements  P273-P501-P264-P270-P301+P312-P330-P501-P280-P305+P351+P338-P310
PPE Eyeshields, Gloves, type N95 (US)
WGK Germany  3
RTECS  UA2458284
HS Code  29333990
Storage Class 11 - Combustible Solids
Hazard Classifications Acute Tox. 4 Oral
Aquatic Chronic 3
Eye Dam. 1

2-[4-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]oxyphenoxy]propanoic acid price More Price(18)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 45817 Haloxyfop PESTANAL 69806-34-4 100mg $111 2026-04-30 Buy
ChemScene CS-0013923 Haloxyfop 99.70% 69806-34-4 5mg $54 2026-06-04 Buy
ChemScene CS-0013923 Haloxyfop 99.70% 69806-34-4 10mg $87 2026-06-04 Buy
ChemScene CS-0013923 Haloxyfop 99.70% 69806-34-4 25mg $139 2026-06-04 Buy
ACHEMBLOCK X192122 2-[4-[[3-Chloro-5-(trifluoromethyl)-2-pyridyl]oxy]phenoxy]propanoic acid 95.00% 69806-34-4 250MG $335 2026-05-27 Buy
Product number Packaging Price Buy
45817 100mg $111 Buy
CS-0013923 5mg $54 Buy
CS-0013923 10mg $87 Buy
CS-0013923 25mg $139 Buy
X192122 250MG $335 Buy

2-[4-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]oxyphenoxy]propanoic acid Chemical Properties, Uses, Production

Uses

(±)-Haloxyfop is a herbicide.

Definition

ChEBI: 2-(4-{[3-chloro-5-(trifluoromethyl)pyridin-2-yl]oxy}phenoxy)propanoic acid is a monocarboxylic acid that is 2-phenoxypropanoic acid in which the hydrogen at the para position of the phenyl ring has been replaced by a [3-chloro-5-(trifluoromethyl)pyridin-2-yl]oxy group. It is a member of pyridines, an aromatic ether, a monocarboxylic acid, an organofluorine compound and an organochlorine compound.

Production Methods

Haloxyfop is synthesised as haloxyfop-R-methyl through a multi-step process that constructs its pyridyl ether structure. The synthesis typically begins with 2,3-dichloro-5-trifluoromethylpyridine, which is dissolved in a polar aprotic solvent like dimethylacetamide. This is reacted with (R)-(+)-2-(4-hydroxyphenoxy)propionic acid methyl ester in the presence of a base such as potassium carbonate under nitrogen atmosphere and heat, forming the key ether linkage via nucleophilic substitution. After the reaction, the mixture is cooled and subjected to vacuum distillation to remove solvents, followed by aqueous workup and acid washing to eliminate residual bases and impurities. The organic phase is then washed repeatedly with deionized water and dried, and the final product is obtained by desolventising under heat.

Mechanism of action

Selective, absorbed by roots and foliage. Acetyl CoA carboxylase inhibitor (ACCase) - distrupts fatty acid biosynthesis and lipid formation.

Pesticide Type

Herbicide; Metabolite

2-[4-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]oxyphenoxy]propanoic acid synthesis

69806-40-2
69806-34-4
Synthesis of 2-[4-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]oxyphenoxy]propanoic acid from Methyl 2-(4-((3-chloro-5-(trifluoromethyl)-2-pyridinyl)oxy)phenoxy)propanoate

2-[4-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]oxyphenoxy]propanoic acid Preparation Products And Raw materials

Raw materials

Methyl 2-(4-((3-chloro-5-(trifluoromethyl)-2-pyridinyl)oxy)phenoxy)propanoate

Preparation Products

2-[4-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]oxyphenoxy]propanoic acid Suppliers

Global Suppliers ( 118)
Supplier Tel Email Country ProdList Advantage
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Chemsky（shanghai）International Co.,Ltd. 021-50135380 shchemsky@sina.com China 32273 50
Syntechem Co.,Ltd info@syntechem.com China 12973 57
Sichuan Kulinan Technology Co., Ltd 400-1166-196 18981987031 cdhxsj@163.com China 11674 57
Shanghai Aladdin Bio-Chem Technology Co.,LTD 400-6206333 13167063860 anhua.mao@aladdin-e.com China 29977 65
The future of Shanghai Industrial Co., Ltd. 021-61552785 sales@shshiji.com China 9531 55
Nanjing Sunlida Biological Technology Co., Ltd. 025-57798810 18652991625 sales@sunlidabio.com China 3223 55
Shanghai JONLN Reagent Co., Ltd. 400-0066400 13621662912 422131432@qq.com China 9970 55
TianJin Alta Scientific Co., Ltd. 022-65378550-8551 contact@altascientific.com China 2772 58
Bide Pharmatech Ltd. 400-164-7117 18317119277 product02@bidepharm.com China 40000 60
Supplier Advantage
J & K SCIENTIFIC LTD. 76
Chemsky（shanghai）International Co.,Ltd. 50
Syntechem Co.,Ltd 57
Sichuan Kulinan Technology Co., Ltd 57
Shanghai Aladdin Bio-Chem Technology Co.,LTD 65
The future of Shanghai Industrial Co., Ltd. 55
Nanjing Sunlida Biological Technology Co., Ltd. 55
Shanghai JONLN Reagent Co., Ltd. 55
TianJin Alta Scientific Co., Ltd. 58
Bide Pharmatech Ltd. 60

View Latest Price from 2-[4-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]oxyphenoxy]propanoic acid manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Haloxyfop pictures 2026-07-14 Haloxyfop
69806-34-4
 $40.00-64.00 99.96% 10g TargetMol Chemicals Inc.
2-[4-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]oxyphenoxy]propanoic acid pictures 2021-08-12 2-[4-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]oxyphenoxy]propanoic acid
69806-34-4
 $10.00-15.00 1KG 99%+ HPLC Zhuozhou Wenxi import and Export Co., Ltd
2-[4-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]oxyphenoxy]propanoic acid pictures 2019-12-23 2-[4-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]oxyphenoxy]propanoic acid
69806-34-4
 $1.00 1g 99% 1000KGS Career Henan Chemical Co
  • Haloxyfop pictures
  • Haloxyfop
    69806-34-4
  • $40.00-64.00
  • 99.96%
  • TargetMol Chemicals Inc.

2-[4-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]oxyphenoxy]propanoic acid Spectrum

2-[4-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]oxyphenoxy]propanoic acid(69806-34-4)1HNMR

69806-34-4 (2-[4-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]oxyphenoxy]propanoic acid) Related Search:

Benzofluorfen Fluroxypyr Lactofen Quizalofop-p-ethyl Glyphosate
MCPA SODIUM metamifop Chlorothalonil Bismerthiazol Ethyl 2-[4-([3-chloro-5-(trifluoromethyl)-2-pyridinyl]oxy)-2-(phenylsulfonyl)phenoxy]propanoate
Pyridine 2-[4-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]oxyphenoxy]propanoic acid Haloxyfop-etotyl Methyl 2-(4-((3-chloro-5-(trifluoromethyl)-2-pyridinyl)oxy)phenoxy)propanoate 2-(4-((3-Chloro-5-(trifluoromethyl)-2-pyridinyl)oxy)phenoxy)-propanoic acid methyl ester

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2-[4-[3-CHLORO-5-(TRIFLUOROMETHYL)PYRIDIN-2-YL]OXYPHENOXY]PROPANOIC ACID 2-[4-(3-CHLORO-5-TRIFLUOROMETHYL-2-PYRIDYLOXY)PHENOXY]PROPIONIC ACID ethoxyethyl(RS)-2-(4-(3-chloro-5-trifluoromethyl-2-pyridyloxy)phenoxy)propionic acid ethyl(RS)-2-(4-(3-chloro-5-trifluoromethyl-2-pyridyloxy)phenoxy)propionic acid (±)2-(4-(3-chloro-5-trifluoromehtyl-2-pyridyloxy)phenoxy)propionic acid (RS)-2-(4-(3-chloro-5-trifluoromethyl-2-pyridyloxy)phenoxy)propionic acid Haloxyfop Solution, 1000ppm HALOXYFOP PESTANAL, Propanoic acid, 2-4-3-chloro-5-(trifluoromethyl)-2-pyridinyloxyphenoxy- haloxyfop (bsi,ansi,iso,wssa) DOWCO453 Halossifop 2-[4-[3-chloro-5-(tr Haloxyfop (fre 2-[4-[[3-Chloro-5-(trifluoromethyl)-2-pyridyl]oxy]phenoxy]propanoic Acid (95905-78-5) haloxyfop Haloxyfop @100 μg/mL in MeOH Haloxyfop@1000 μg/mL in Acetonitrile Haloxyfop @100 μg/mL in AcCN HaloxyfopSolution,10mg/L,2x5ml Haloxyfop Solution in Acetonitrile, 100μg/mL AI3-27257 UNII-7O9EWV477R 4-[3,5-BIS(TRIFLUOROMETHYL)PHENYL]-30-THIOSEMICARBAZIDE C14060000 Haloxyfop (freEacid) Haloxyfop 10.0 μg/ml Acetonitrile L14060000ALHaloxyfop (freEacid) 10μg/mLin A Haloxyfop (free acid) in Methanol Haloxyfop (free acid) in Acetonitrile Haloxyfop, 10 mM in DMSO (±)-Haloxyfop Haloxyfop (free acid) 100 μg/mL in Acetonitrile Haloxyfop (free acid) 10 μg/mL in Acetonitrile HALOXYFOP Haloxyfop (free acid) 69806-34-4 C15H11CIF3NO4 HA -HTPesticides&Metabolites Alpha sort Baby Food Directives 13/2003 EC&14/2003 ECPesticides&Metabolites European Community: ISO and DIN H Herbicides H-MAlphabetic Method Specific Phenoxy structure