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2-Amino-4-methylbenzonitrile

2-Amino-4-methylbenzonitrile structure

CAS No.: 26830-96-6

Chemical Name:: 2-Amino-4-methylbenzonitrile

Synonyms: 6-Cyano-m-toluidine;3-Amino-4-cyanotoluene;2-Cyano-5-methylaniline;2-AMINO-4-METHYLBENZONITRILE;4-Methyl-2-aminobenzonitrile;Benzonitrile, 2-aMino-4-Methyl-;2-Amino-4-methylbenzonitrile >2-Cyano-5-methylaniline, 3-Amino-4-cyanotoluene;3-Amino-4-cyanotoluene 2-Cyano-5-methylaniline 6-Cyano-m-toluidine;2-Cyano-5-methylaniline, 3-Amino-4-cyanotoluene, 6-Cyano-m-toluidine

CBNumber:: CB1187357

Molecular Formula:: C8H8N2

Molecular Weight:: 132.16

MDL Number:: MFCD00173706

MOL File:: 26830-96-6.mol

Last updated:2026-01-13 11:14:08

Product description	Number	Pack Size	Price
2-Amino-4-methylbenzonitrile 97%	214280	1g	$33.85
2-Amino-4-methylbenzonitrile 97%	214280	5g	$115
2-Amino-4-methylbenzonitrile >98.0%(GC)	A2448	1g	$105
2-Amino-4-methylbenzonitrile >98.0%(GC)	A2448	5g	$332
2-Amino-4-methylbenzonitrile	A577268	1g	$75
More product size

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2-Amino-4-methylbenzonitrile Properties

Melting point	92-95 °C (lit.)
Boiling point	150-152 °C(Press: 15 Torr)
Density	1.10±0.1 g/cm3(Predicted)
storage temp.	Keep in dark place,Inert atmosphere,Room temperature
solubility	soluble in Methanol
pka	1.94±0.10(Predicted)
form	Powder
color	Light yellow to Yellow to Orange
InChI	1S/C8H8N2/c1-6-2-3-7(5-9)8(10)4-6/h2-4H,10H2,1H3
InChIKey	LGNVAEIITHYWCG-UHFFFAOYSA-N
SMILES	Cc1ccc(C#N)c(N)c1
CAS DataBase Reference	26830-96-6(CAS DataBase Reference)
UNSPSC Code	12352100
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H302+H312+H332-H315-H319-H335

Precautionary statements

P261-P280-P301+P312-P302+P352+P312-P304+P340+P312-P305+P351+P338

target organs

Respiratory system

PPE

dust mask type N95 (US), Eyeshields, Gloves

Hazard Codes

Xn,T

Risk Statements

20/21/22-36/37/38

Safety Statements

26-36-36/37

RIDADR

3439

WGK Germany

Hazard Note

Toxic

HazardClass

6.1

PackingGroup

III

HS Code

29269090

Storage Class

11 - Combustible Solids

Hazard Classifications

Acute Tox. 4 Oral
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3

NFPA 704

	0
2		0

2-Amino-4-methylbenzonitrile price More Price(30)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	214280	2-Amino-4-methylbenzonitrile 97%	26830-96-6	1g	$33.85	2025-07-31	Buy
Sigma-Aldrich	214280	2-Amino-4-methylbenzonitrile 97%	26830-96-6	5g	$115	2025-07-31	Buy
TCI Chemical	A2448	2-Amino-4-methylbenzonitrile >98.0%(GC)	26830-96-6	1g	$105	2025-07-31	Buy
TCI Chemical	A2448	2-Amino-4-methylbenzonitrile >98.0%(GC)	26830-96-6	5g	$332	2025-07-31	Buy
TRC	A577268	2-Amino-4-methylbenzonitrile	26830-96-6	1g	$75	2021-12-16	Buy

Product number	Packaging	Price	Buy
214280	1g	$33.85	Buy
214280	5g	$115	Buy
A2448	1g	$105	Buy
A2448	5g	$332	Buy
A577268	1g	$75	Buy

2-Amino-4-methylbenzonitrile Chemical Properties,Uses,Production

Chemical Properties

white to light yellow crystal powder

Uses

2-Amino-4-methylbenzonitrile was used in the synthesis of:

7-methyl-4-(phenylamino)quinazoline-2(1H)-selone
racemic aminoquinolines, potential acetylcholinesterase (AChE) inhibitors

Synthesis

26830-95-5

26830-96-6

a) Synthesis of 2-amino-4-methylbenzonitrile 4-Methyl-2-nitrobenzonitrile (4.9 g, 30 mmol) was mixed with 10% palladium-carbon catalyst (500 mg) in 1,4-dioxane (60 mL), and the reaction was stirred overnight under a hydrogen atmosphere (balloon pressurized). Upon completion of the reaction, the catalyst was removed by diatomaceous earth filtration and the filtrate was concentrated under reduced pressure to give the crude product. The crude product was further purified by fast column chromatography (eluent: dichloromethane) to afford 2-amino-4-methylbenzonitrile as a light yellow solid (3.3 g, 83% yield). 1H-NMR (300 MHz, CDCl3) δ 7.26 (d, J = 8.3 Hz, 1H), 6.56 (s, 1H), 6.55 (s, 1H), 4.32 (br s, 2H), 2.29 (s, 3H).

References

[1] Chemical Communications, 2011, vol. 47, # 31, p. 8808 - 8810
[2] Journal of the Chemical Society, Perkin Transactions 2, 2001, # 2, p. 214 - 228
[3] Patent: US5891909, 1999, A
[4] Patent: EP906091, 2006, B1. Location in patent: Page/Page column 46
[5] Journal fuer Praktische Chemie (Leipzig), 1889, vol. <2> 40, p. 12

2-Amino-4-methylbenzonitrile Preparation Products And Raw materials

Raw materials

Copper(I) Cyanide 4-Chloro-3-nitrotoluene Ethanol N,N-Dimethylformamide Acetic acid

Iron 4-Methyl-2-nitrobenzonitrile 1,4-Dioxane Hydrogen

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Preparation Products

2-Amino-4-methylbenzoic acid 2-Amino-4-methylbenzamide 7-methylquinazolin-4-amine 7-METHYLQUINAZOLINE-2,4(1H,3H)-DIONE

2-Amino-4-methylbenzonitrile Suppliers

Global( 193)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Hebei Chuanghai Biotechnology Co., Ltd	+8615350571055	Sibel@chuanghaibio.com	China	8753	58
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	33024	60
career henan chemical co	+86-0371-86658258 +8613203830695	sales@coreychem.com	China	29831	58
Changzhou Ansciep Chemical Co., Ltd.	+86 519 86305871	sales@ansciepchem.com	CHINA	4241	58
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63687	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49977	58
Fuxin Pharmaceutical	+86-021-021-50872116 +8613122107989	contact@fuxinpharm.com	China	10000	58
Guangzhou Yuheng Pharmaceutical Technology Co., Ltd	+8613580539051	joe@yuhengpharm.com	CHINA	21142	58
SIMAGCHEM CORP	+86-5922680277 +86-13806087780	sale@simagchem.com	China	17346	58
Hefei TNJ Chemical Industry Co.,Ltd.	+86-0551-65418671 +8618949823763	sales@tnjchem.com	China	34563	58

Supplier	Advantage
Hebei Chuanghai Biotechnology Co., Ltd	58
ATK CHEMICAL COMPANY LIMITED	60
career henan chemical co	58
Changzhou Ansciep Chemical Co., Ltd.	58
Alchem Pharmtech,Inc.	58
CONIER CHEM AND PHARMA LIMITED	58
Fuxin Pharmaceutical	58
Guangzhou Yuheng Pharmaceutical Technology Co., Ltd	58
SIMAGCHEM CORP	58
Hefei TNJ Chemical Industry Co.,Ltd.	58

View Lastest Price from 2-Amino-4-methylbenzonitrile manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2026-01-30	2-Amino-4-methylbenzonitrile 26830-96-6	US $0.00-0.00 / KG	1KG	99%	20 mt	Hebei Chuanghai Biotechnology Co., Ltd
2021-08-12	2-Amino-4-methylbenzonitrile 26830-96-6	US $15.00-10.00 / KG	1KG	99%+ HPLC	Monthly supply of 1 ton	Zhuozhou Wenxi import and Export Co., Ltd
2019-07-10	2-Amino-4-methylbenzonitrile 26830-96-6	US $3.00 / ASSAYS	1KG	99%	100kg	Career Henan Chemical Co

2-Amino-4-methylbenzonitrile
26830-96-6
US $0.00-0.00 / KG
99%
Hebei Chuanghai Biotechnology Co., Ltd

2-Amino-4-methylbenzonitrile
26830-96-6
US $15.00-10.00 / KG
99%+ HPLC
Zhuozhou Wenxi import and Export Co., Ltd

2-Amino-4-methylbenzonitrile
26830-96-6
US $3.00 / ASSAYS
99%
Career Henan Chemical Co

2-Amino-4-methylbenzonitrile Spectrum

2-Amino-4-methylbenzonitrile(26830-96-6)FT-IR 2-Amino-4-methylbenzonitrile(26830-96-6)IR

26830-96-6(2-Amino-4-methylbenzonitrile)Related Search:

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4-Methyl-2-aminobenzonitrile 2-AMINO-4-METHYLBENZONITRILE 2-Cyano-5-methylaniline, 3-Amino-4-cyanotoluene, 6-Cyano-m-toluidine 2-Cyano-5-methylaniline, 3-Amino-4-cyanotoluene Benzonitrile, 2-aMino-4-Methyl- 3-Amino-4-cyanotoluene 2-Cyano-5-methylaniline 6-Cyano-m-toluidine 2-Amino-4-methylbenzonitrile > 2-Cyano-5-methylaniline 3-Amino-4-cyanotoluene 6-Cyano-m-toluidine 26830-96-6 H2NC6H3CH3CN C8 to C9 Building Blocks Cyanides/Nitriles Nitrogen Compounds Organic Building Blocks Aromatic Nitriles Amines Phenyls & Phenyl-Het Nitrile Phenyls & Phenyl-Het C8 to C9 Cyanides/Nitriles Nitrogen Compounds