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Methyl 4-bromo-3-methoxybenzoate

Methyl 4-bromo-3-methoxybenzoate Structure
Methyl 4-bromo-3-methoxybenzoate structure
CAS No.
17100-63-9
Chemical Name:
Methyl 4-bromo-3-methoxybenzoate
Synonyms
Methyl 4-broMo-2-hydroxbenzoate;Methyl 4-bromo-3-methoxybenzoate;2-Bromo-5-(methoxycarbonyl)anisole;4-BROMO-3-METHOXYBENZOIC ACID METHYL ESTER;3-methoxy-4-bromobenzoic acid methyl ester;Benzoic acid,4-broMo-3-Methoxy-, Methyl ester;2-Bromo-5-(methoxycarbonyl)anisole, Methyl 4-bromo-m-anisate
CBNumber:
CB2197201
Molecular Formula:
C9H9BrO3
Molecular Weight:
245.07
MDL Number:
MFCD08436018
MOL File:
17100-63-9.mol
MSDS File:
SDS
Last updated:2026-09-12 18:50:25
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Methyl 4-bromo-3-methoxybenzoate Properties

Melting point 58-61
Boiling point 172-173 °C
Density 1.462±0.06 g/cm3(Predicted)
storage temp. Sealed in dry,Room Temperature
form powder
color Lemony cream
InChI InChI=1S/C9H9BrO3/c1-12-8-5-6(9(11)13-2)3-4-7(8)10/h3-5H,1-2H3
InChIKey XLKDKHRGIJWOSN-UHFFFAOYSA-N
SMILES C(OC)(=O)C1=CC=C(Br)C(OC)=C1

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P305+P351+P338
Hazard Codes  Xi
Hazard Note  Irritant/Keep Cold
HS Code  2918999090

Methyl 4-bromo-3-methoxybenzoate price More Price(41)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
AstaTech 63202 METHYL 4-BROMO-3-METHOXY-BENZOATE 97% 17100-63-9 5G $24 2026-04-30 Buy
AstaTech 63202 METHYL 4-BROMO-3-METHOXY-BENZOATE 97% 17100-63-9 25G $89 2026-04-30 Buy
AstaTech 63202 METHYL 4-BROMO-3-METHOXY-BENZOATE 97% 17100-63-9 4*25G $357 2026-04-30 Buy
Matrix Scientific 119198 Methyl 4-bromo-3-methoxybenzoate 17100-63-9 1.00g $60 2026-05-18 Buy
Matrix Scientific 119198 Methyl 4-bromo-3-methoxybenzoate 17100-63-9 5.00g $242 2026-05-18 Buy
Product number Packaging Price Buy
63202 5G $24 Buy
63202 25G $89 Buy
63202 4*25G $357 Buy
119198 1.00g $60 Buy
119198 5.00g $242 Buy

Methyl 4-bromo-3-methoxybenzoate Chemical Properties,Uses,Production

Synthesis Reference(s)

Tetrahedron Letters, 10, p. 1623, 1969 DOI: 10.1017/S0009838800024678

Synthesis

METHYL 4-BROMO-3-HYDROXYBENZOATE

106291-80-9

Dimethyl sulfate

77-78-1

METHYL 4-BROMO-3-METHOXYBENZOATE

17100-63-9

Step B. Synthesis of methyl 4-bromo-3-methoxybenzoate Methyl 4-bromo-3-hydroxybenzoate (27 mmol), potassium carbonate (33 mmol) and dimethyl sulfate (32 mmol) obtained from Step A were dissolved in acetone (40 mL) under nitrogen protection. The reaction mixture was heated to reflux temperature and stirred for 3 hours. After completion of the reaction, the mixture was cooled and the reaction was quenched by slowly adding 5 mL of water. Subsequently, the acetone was removed by rotary evaporator and diluted by adding 30 mL of water. The product in the aqueous phase was extracted with dichloromethane (3 × 20 mL). The organic phases were combined, dried with anhydrous magnesium sulfate, filtered and concentrated under reduced pressure to afford the title compound methyl 4-bromo-3-methoxybenzoate (6.5 g, 99% yield) as a white crystalline solid.

References

[1] Patent: US2006/199806, 2006, A1. Location in patent: Page/Page column 23
[2] Patent: US2006/287522, 2006, A1. Location in patent: Page/Page column 24
[3] Beilstein Journal of Organic Chemistry, 2016, vol. 12, p. 2267 - 2273
[4] Yakugaku Zasshi, 1930, vol. 50, p. 224,227; dtsch. Ref. S. 26
[5] Chem.Abstr., 1930, p. 3513

Methyl 4-bromo-3-methoxybenzoate synthesis

106291-80-9
77-78-1
17100-63-9
Synthesis of Methyl 4-bromo-3-methoxybenzoate from Methyl 4-bromo-3-hydroxybenzoate and Dimethyl sulfate

Methyl 4-bromo-3-methoxybenzoate Preparation Products And Raw materials

Raw materials

Methyl 4-bromo-3-hydroxybenzoate 4-Bromo-3-hydroxybenzoic acid Methanol 4-Bromo-3-methoxybenzoic acid Acetone
Potassium carbonate Dimethyl sulfate Iodomethane

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Preparation Products

Methyl 4-bromo-3-methoxybenzoate Suppliers

Global( 149)Suppliers
Supplier Tel Email Country ProdList Advantage
Shanghai Harvest Chemical Industrial Co., Ltd. 15721252604 17321035817 sales@harvest-chem.com China 2829 64
Changzhou Anxuan Chemical, Co., Ltd. 13912302692 sales@anxuanchem.com China 4824 58
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
ShangHai DEMO Chemical Co.,Ltd 400-021-7337 2355568890 sales@demochem.com China 2569 57
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Wuhan Chemwish Technology Co., Ltd 86-027-67849912 sales@chemwish.com China 35884 56
Capot Chemical Co., Ltd +86 (0) 571 85 58 67 18 China 18187 66
Changzhou Huanling Chemical Co., Ltd. 89803005 18206112582 info@huanlingchem.com China 983 68
Jia Xing Isenchem Co.,Ltd 0573-85285100 18627885956 isenchem@163.com China 9389 66
Supplier Advantage
Shanghai Harvest Chemical Industrial Co., Ltd. 64
Changzhou Anxuan Chemical, Co., Ltd. 58
J & K SCIENTIFIC LTD. 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 62
ShangHai DEMO Chemical Co.,Ltd 57
Energy Chemical 61
Wuhan Chemwish Technology Co., Ltd 56
Capot Chemical Co., Ltd 66
Changzhou Huanling Chemical Co., Ltd. 68
Jia Xing Isenchem Co.,Ltd 66

View Lastest Price from Methyl 4-bromo-3-methoxybenzoate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
METHYL 4-BROMO-3-METHOXYBENZOATE pictures 2024-08-21 METHYL 4-BROMO-3-METHOXYBENZOATE
17100-63-9
 1kg 98% 1ton Changzhou Anxuan Chemical Co., Ltd
METHYL 4-BROMO-3-METHOXYBENZOATE pictures 2019-07-06 METHYL 4-BROMO-3-METHOXYBENZOATE
17100-63-9
 $1.00 1kg 98% 1000kg Career Henan Chemical Co

Methyl 4-bromo-3-methoxybenzoate Spectrum

METHYL 4-BROMO-3-METHOXYBENZOATE(17100-63-9)1HNMR

17100-63-9(Methyl 4-bromo-3-methoxybenzoate)Related Search:

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Methyl 4-bromo-3-methoxybenzoate Methyl 4-bromo-2-methoxybenzoate 98 3-Methoxybenzoic acid Methyl 3-methoxybenzoate 4-Bromo-3-methoxybenzoic acid
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tert-Butyl 4-bromo-3,5-dimethoxybenzoate 4-Bromo-3,5-dimethoxybenzoic acid methyl ester Methyl 4-bromo-2-methoxybenzoate

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4-BROMO-3-METHOXYBENZOIC ACID METHYL ESTER 2-Bromo-5-(methoxycarbonyl)anisole Methyl 4-broMo-2-hydroxbenzoate 2-Bromo-5-(methoxycarbonyl)anisole, Methyl 4-bromo-m-anisate Benzoic acid,4-broMo-3-Methoxy-, Methyl ester 3-methoxy-4-bromobenzoic acid methyl ester Methyl 4-bromo-3-methoxybenzoate 17100-63-9 blocks Bromides Carboxes