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Diethyl 2-bromo-2-methylmalonate

CAS No.
29263-94-3
Chemical Name:
Diethyl 2-bromo-2-methylmalonate
Synonyms
Diethyl 2-bromo;DIETHYL BROMOMETHYLMALONATE;Diethyl methylbromomalonate;Diethyl-2-Bro-2-Methylmalonate;Diethyl 2-bromo-2-methylmalote;DIETHYL 2-BROMO-2-METHYLMALONATE;Diethyl a-bromo-a-methylmalonate;Diethyl2-Bromo-2-methylmalonate>iethyl2-bromo-2-methylpropanedioate;Diethyl 2-broMo-2-MethylMalonate 98%
CBNumber:
CB3101744
Molecular Formula:
C8H13BrO4
Molecular Weight:
253.09
MDL Number:
MFCD00009125
MOL File:
29263-94-3.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-28 00:54:11

Diethyl 2-bromo-2-methylmalonate Properties

Boiling point 105-106 °C (5 mmHg)
Density 1.325 g/mL at 25 °C (lit.)
refractive index n20/D 1.449(lit.)
Flash point >230 °F
storage temp. Inert atmosphere,Room Temperature
form clear liquid
color Colorless to Almost colorless
BRN 1779673
InChI 1S/C8H13BrO4/c1-4-12-6(10)8(3,9)7(11)13-5-2/h4-5H2,1-3H3
InChIKey CSLQAXTUGPUBCW-UHFFFAOYSA-N
SMILES CCOC(=O)C(C)(Br)C(=O)OCC
CAS DataBase Reference 29263-94-3(CAS DataBase Reference)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Corrosion (GHS05)
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363-P405
PPE Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hazard Codes  C
Risk Statements  34-20/21/22
Safety Statements  26-36/37/39-45
RIDADR  UN 3265 8/PG 2
WGK Germany  3
HS Code  2917.19.7050
HazardClass  8
PackingGroup  III
Storage Class 8A - Combustible corrosive hazardous materials
Hazard Classifications Eye Dam. 1
Skin Corr. 1B
Limited Quantities 1.0 L (0.3 gallons) (liquid) or 1 Kg (2.2 lbs) (solid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)
NFPA 704
0
3 0

Diethyl 2-bromo-2-methylmalonate price More Price(28)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 139440 Diethyl 2-bromo-2-methylmalonate 98% 29263-94-3 25g $185 2026-04-30 Buy
TCI Chemical D4368 Diethyl 2-Bromo-2-methylmalonate >98.0%(GC)(T) 29263-94-3 25g $110 2026-04-30 Buy
Synthonix D47070 Diethyl 2-bromo-2-methylmalonate 98% 29263-94-3 1g $35 2026-05-06 Buy
Synthonix D47070 Diethyl 2-bromo-2-methylmalonate 98% 29263-94-3 5g $39 2026-05-06 Buy
Synthonix D47070 Diethyl 2-bromo-2-methylmalonate 98% 29263-94-3 10g $40 2026-05-06 Buy
Product number Packaging Price Buy
139440 25g $185 Buy
D4368 25g $110 Buy
D47070 1g $35 Buy
D47070 5g $39 Buy
D47070 10g $40 Buy

Diethyl 2-bromo-2-methylmalonate Chemical Properties,Uses,Production

Chemical Properties

CLEAR COLOURLESS LIQUID

Uses

Diethyl 2-bromo-2-methylmalonate was used to investigate the 1,2,2,6,6-pentamethylpiperidine as an effective reducing agent for the radical chain conversion of primary bromoesters to the corresponding esters. It was used in the synthesis of polystyrene macroinitiator via atom transfer radical polymerization.

General Description

Diethyl 2-bromo-2-methylmalonate acts as initiator during the atom transfer radical polymerization of methyl methacrylate.

Global( 150)Suppliers
Supplier Tel Email Country ProdList Advantage
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
3B Pharmachem (Wuhan) International Co.,Ltd. 18930552037 3bsc@sina.com China 15813 69
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24512 81
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Accela ChemBio Co.,Ltd. 021-50795510 4000665055 marketing@accelachem.com China 10972 64
RYSS TECH LTD 400-188-0725 +86 21 34310725 13611771617 China 1999 57
Shanghai Jian Chao Chemical Technology Co., Ltd. 150-2103-5486 18017383231 983544897@qq.com China 9336 55
TOKYO CHEMICAL INDUSTRY CO., LTD. 03-36680489 Sales-JP@TCIchemicals.com Japan 28364 80

View Lastest Price from Diethyl 2-bromo-2-methylmalonate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Diethyl 2-bromo-2-methylmalonate pictures 2025-05-26 Diethyl 2-bromo-2-methylmalonate
29263-94-3
$15.00-20.00 1kg 0.99 20tons Hebei Fengjia New Material Co., Ltd
Diethyl 2-bromo-2-methylmalonate pictures 2021-07-13 Diethyl 2-bromo-2-methylmalonate
29263-94-3
$10.00-15.00 1KG 99%+ HPLC Zhuozhou Wenxi import and Export Co., Ltd
Diethyl 2-bromo-2-methylmalonate pictures 2021-07-10 Diethyl 2-bromo-2-methylmalonate
29263-94-3
$10.00-15.00 1KG 99%+ HPLC Zhuozhou Wenxi import and Export Co., Ltd
2-BROMO-2-METHYLMALONIC ACID DIETHYL ESTER DIETHYL BROMOMETHYLMALONATE DIETHYL 2-BROMO-2-METHYLMALONATE 2-Brom-2-methylmalonic acid diethylester 2-BROMO-2-METHYLPROPANDIOIC ACID DIETHYL ESTER 2-(bromomethyl)-propanedioic acid diethyl ester Diethyl 2-bromo-2-methylmalonate, 98+% Diethyl-2-Bro-2-Methylmalonate 2-bromo-2-methylpropanedioic acid diethyl ester Diethyl 2-bromo-2-methylpropanedioate Diethyl a-bromo-a-methylmalonate Diethyl methylbromomalonate Malonic acid, bromomethyl-, diethyl ester Propanedioic acid, bromomethyl-, diethyl ester Diethyl 2-bromo Diethyl 2-broMo-2-MethylMalonate 98% Diethyl 2-bromo-2-methylmalote Diethyl2-Bromo-2-methylmalonate> Propanedioic acid, 2-bromo-2-methyl-, 1,3-diethyl ester iethyl2-bromo-2-methylpropanedioate 1,3-Diethyl 2-bromo-2-methylpropanedioate 29263-94-3 C8H13BrO4 BrCCH3CO2C2H52 Organic Building Blocks Esters C8 to C9 Carbonyl Compounds Building Blocks Pharmaceutical Intermediates TheMalonateRamificationProducts C8 to C9 Carbonyl Compounds Esters