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4-Chloro-2-nitroaniline

CAS No.
89-63-4
Chemical Name:
4-Chloro-2-nitroaniline
Synonyms
PARA CHLORO ORTHO NITRO ANILINE;4-Chloro-2-nitrobenzenamine;FAST RED 3GL BASE;PCONA;RED 3GL BASE;c.i. azoic diazo component no. 9;PCON;devolredf;red3gsalt;redbase3gl
CBNumber:
CB3854602
Molecular Formula:
C6H5ClN2O2
Molecular Weight:
172.57
MDL Number:
MFCD00007836
MOL File:
89-63-4.mol
MSDS File:
SDS
Last updated:2026-06-04 16:00:12
Product description Number Pack Size Price
4-Chloro-2-nitroaniline 99% 101664 250g $251
4-Chloro-2-nitroaniline >98.0%(GC) C0215 25g $45
4-Chloro-2-nitroaniline >98.0%(GC) C0215 500g $225
4-Chloro-2-nitroaniline Asreported 267309 50g $290
4-Chloro-2-nitroaniline Asreported 267309 100g $369
More product size

4-Chloro-2-nitroaniline Properties

Melting point 117-119 °C(lit.)
Boiling point 200°C (rough estimate)
Density 1.37
refractive index 1.6460 (estimate)
Flash point 191 °C
storage temp. room temp
solubility 0.5g/l (anhydrous substance)
pka pK1: 1.10(+1) (25°C)
Colour Index 37040
form Crystalline Powder or Chunks
color Orange
PH 7 (0.5g/l, H2O, 20℃)
Water Solubility INSOLUBLE
BRN 512436
Henry's Law Constant 8.2×101 mol/(m3Pa) at 25℃, HSDB (2015)
Stability Stable. Combustible. Incompatible with strong oxidizing agents.
InChI 1S/C6H5ClN2O2/c7-4-1-2-5(8)6(3-4)9(10)11/h1-3H,8H2
InChIKey PBGKNXWGYQPUJK-UHFFFAOYSA-N
SMILES Nc1ccc(Cl)cc1[N+]([O-])=O
CAS DataBase Reference 89-63-4(CAS DataBase Reference)
FDA UNII 1929LY233C
NIST Chemistry Reference Aniline, 4-chloro-2-nitro-(89-63-4)
EPA Substance Registry System 4-Chloro-2-nitroaniline (89-63-4)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Skull and Crossbones (GHS06)Health Hazard (GHS08)Environment (GHS09)
GHS06,GHS08,GHS09
Signal word  Danger
Hazard statements  H300+H310+H330-H373-H410
Precautionary statements  P262-P273-P280-P302+P352+P310-P304+P340+P310-P314
PPE Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Hazard Codes  T+,N,T
Risk Statements  26/27/28-33-51/53
Safety Statements  28-36/37-45-61-28A
RIDADR  UN 2237 (CHLORONITROANILINES)
WGK Germany  2
RTECS  BX1575000
Autoignition Temperature 964 °F
Hazard Note  Very Toxic
TSCA  TSCA listed
HazardClass  6.1
PackingGroup  III
HS Code  29214210
Storage Class 6.1A - Combustible acute toxic Cat. 1 and 2
very toxic hazardous materials
Hazard Classifications Acute Tox. 1 Dermal
Acute Tox. 2 Inhalation
Acute Tox. 2 Oral
Aquatic Acute 1
Aquatic Chronic 2
STOT RE 2
Hazardous Substances Data 89-63-4(Hazardous Substances Data)
REACH Registrations Active
Limited Quantities 5.0 kg (11 lbs) (solid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)
NFPA 704
1
4 0

4-Chloro-2-nitroaniline price More Price(28)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 101664 4-Chloro-2-nitroaniline 99% 89-63-4 250g $251 2026-04-30 Buy
TCI Chemical C0215 4-Chloro-2-nitroaniline >98.0%(GC) 89-63-4 25g $45 2026-04-30 Buy
TCI Chemical C0215 4-Chloro-2-nitroaniline >98.0%(GC) 89-63-4 500g $225 2026-04-30 Buy
Usbiological 267309 4-Chloro-2-nitroaniline Asreported 89-63-4 50g $290 2026-06-03 Buy
Usbiological 267309 4-Chloro-2-nitroaniline Asreported 89-63-4 100g $369 2026-06-03 Buy
Product number Packaging Price Buy
101664 250g $251 Buy
C0215 25g $45 Buy
C0215 500g $225 Buy
267309 50g $290 Buy
267309 100g $369 Buy

4-Chloro-2-nitroaniline Chemical Properties,Uses,Production

Chemical Properties

bright orange powder

Uses

A nitro-aromatic amine with mutagenicity and carcinogenicity

Uses

4-Chloro-2-nitroaniline is used almost exclusively as an intermediate in the synthesis of pigments. The greatest potential for human exposure to 4-chloro-2- nitroaniline is in production and use of pigments made from the compound.

Uses

4-Chloro-2-nitroaniline is used as pharmaceutical intermediate.

Production Methods

1,4-Dichloro-2-nitrobenzene is aminated at 165 ℃ by using a process similar to that described for 2- nitroaniline.

Preparation

4-Chloro-2-nitrobenzenamine of chlorine.

General Description

Bright orange powder.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

4-Chloro-2-nitroaniline forms explosive products on reaction with nitric acid. Can react with oxidizing agents.

Hazard

Toxic by ingestion and inhalation.

Fire Hazard

4-Chloro-2-nitroaniline is probably combustible.

Purification Methods

Crystallise the aniline from hot H2O (m 115.8-116o), EtOH, EtOH/H2O or *C6H6, and dry it for 10hours at 60o in vacuo. It has m 115.5-116o after sublimation. [Beilstein 12 H 729, 12 I 355, 12 II 396, 12 III 1649, 12 IV 1669.]

610-40-2
89-63-4
Synthesis of 4-Chloro-2-nitroaniline from 3,4-Dinitrochlorobenzene
Global( 49)Suppliers
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Alchemie Shanghai Co.,Ltd.
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View Lastest Price from 4-Chloro-2-nitroaniline manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
4-Chloro-2-nitroaniline pictures 2026-07-02 4-Chloro-2-nitroaniline
89-63-4
$2.20-8.80 1kg 99%min 100kg ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
4-Chloro-2-nitroaniline pictures 2026-06-30 4-Chloro-2-nitroaniline
89-63-4
1KG 98.0% 10000KGS Shaanxi Dideu New Materials Co. Ltd
fastred2ncsalt redbase3gl redbasecibavi redbaseirgavi redsaltcibavi redsaltnbgl Sanyo Fast Red Salt 3GL sanyofastredsalt3gl Shinnippon Fast Red 3GL Base shinnipponfastred3glbase Symulon Red 3GL Salt c.i.azoicdiazocomponent9 chloro-4nitro-2aniline Daito Red Base 3GL Daito Red Salt 3GL daitoredbase3gl daitoredsalt3gl Devol Red F Devol Red Salt F devolredf devolredsaltf Diazo Fast Red 3GL diazofastred3gl Fast Red 2NC Base Fast Red 2NC Salt 2-nitro-4-chloro aniline (4-chloro-2-nitroaniline) 1-Amino-4-chloro-2-nitrobenzene PCONA 4-Chloro-2-nitroaniline 10 μg/mL in Cyclohexane C.I. 37040 4-CHLORO-2-NITROANILINE 2-NITRO-4-CHLOROANILINE 2-AMINO-5-CHLORONITROBENZENE 4-chloro-2-nitrobenzene o-Nitro-p-Chloroaniline 4-Chloro-2-Nitroaniline paraChloro-o-Nitroaniline 4-Chlor-2-nitroanilin c.i. azoic diazo component no. 9 FAST RED 3GL BASE O-NITRO-P-CHLOROANILINE PCONA p-Chloro-o-nitroaniline RED 3G BASE 1-AMINO-4-CHLORO-2-NITROBENZENE Azoic DC 9(base) Fast Red 3GL Special 4-Chloro-2-nitroaniline,99% 4-chloro-2-nitro-anilin 4-chloro-2-nitro-benzenamid 4-chloro-2-nitro-benzenamin 4-Chloro-2-nitro-phenylamine Azoene Fast Red 3GL Base Azoene Fast Red 3GL Salt azoenefastred3glbase azoenefastred3glsalt Azofix Red 3GL Salt azoflyred3glsalt Azoic Diazo Component 9 Azoic diazo component 9, base