Acetylacetonato(1,5-cyclooctadiene)rhodium(I)
- CAS No.
- 12245-39-5
- Chemical Name:
- Acetylacetonato(1,5-cyclooctadiene)rhodium(I)
- Synonyms
- rh(acac)(cod);NSC 240030;Chiralyst P310;Acetylacetonato(1,5-;(ACETYLACETONATO)(1,5-CYCLOOCTADIENE)RH&;acetylacetonate-1,5-cyclooctadienerhodium;Acetylacetonato(1,5-cyclooctadiene)rhodium(I);Acetylacetonato(cycloocta-1,5-diene)rhodium(I);(1,5-cyclooctadiene)(2,4-pentanedionato)rhodium;(1,5-cyclooctadiene)(2,4-pentanedionato)-rhodiu
- CBNumber:
- CB4469944
- Molecular Formula:
- C13H19O2Rh
- Molecular Weight:
- 310.19
- MDL Number:
- MFCD00075046
- MOL File:
- 12245-39-5.mol
- MSDS File:
- SDS
| Melting point | 138-140 °C(lit.) |
|---|---|
| storage temp. | Inert atmosphere,2-8°C |
| form | Crystals |
| color | Yellow to orange |
| Sensitive | Air Sensitive |
| Hydrolytic Sensitivity | 8: reacts rapidly with moisture, water, protic solvents |
| Exposure limits |
ACGIH: TWA 1 mg/m3 NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3 |
| InChI | 1S/C8H12.C5H8O2.Rh/c1-2-4-6-8-7-5-3-1;1-4(6)3-5(2)7;/h1-2,7-8H,3-6H2;3,6H,1-2H3;/q;;+1/p-1/b2-1-,8-7-;4-3-; |
| InChIKey | WDIAJTWVVLHUJU-SUESZSCISA-N |
| SMILES | CC(=O)\C=C(\C)O[Rh].C1CC=CCCC=C1 |
| UNSPSC Code | 12352103 |
| NACRES | NA.23 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) | ![]() GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319 | |||||||||
| Precautionary statements | P264-P280-P302+P352-P305+P351+P338-P332+P313-P337+P313 | |||||||||
| PPE | dust mask type N95 (US), Eyeshields, Gloves | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 26-37/39 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | VI9292000 | |||||||||
| TSCA | No | |||||||||
| HS Code | 28439000 | |||||||||
| Storage Class | 11 - Combustible Solids | |||||||||
| Hazard Classifications | Eye Irrit. 2 Skin Irrit. 2 |
|||||||||
| REACH Registrations | Inactive | |||||||||
| NFPA 704 |
|
Acetylacetonato(1,5-cyclooctadiene)rhodium(I) price More Price(36)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 683108 | (Acetylacetonato)(1,5-cyclooctadiene)rhodium(I) 99% | 12245-39-5 | 2g | $1080 | 2026-04-30 | Buy |
| Sigma-Aldrich | 335029 | (Acetylacetonato)(1,5-cyclooctadiene)rhodium(I) 99% | 12245-39-5 | 100mg | $125 | 2023-06-20 | Buy |
| Sigma-Aldrich | 8.24420 | Acetylacetonato(1,5-cyclooctadiene)rhodium(I) for synthesis | 12245-39-5 | 500mg | $91.2 | 2023-01-07 | Buy |
| Sigma-Aldrich | 8.24420 | Acetylacetonato(1,5-cyclooctadiene)rhodium(I) for synthesis | 12245-39-5 | 100mg | $139 | 2023-01-07 | Buy |
| Strem Chemicals | 45-0010 | Acetylacetonato(1,5-cyclooctadiene)rhodium(I), 98% 98% | 12245-39-5 | 100mg | $65 | 2026-04-30 | Buy |
Acetylacetonato(1,5-cyclooctadiene)rhodium(I) Chemical Properties, Uses, Production
Reactions
- Precursor for asymmetric hydrogenation reactions.
- Rh-catalyzed carbozincation of ynamides.
Chemical Properties
Orange crystal
Uses
Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis
General Description
Atomic number of base material: 45 Rhodium
reaction suitability
reagent type: catalyst
Safety Profile
Poison by intraperitoneal route. When heated to decomposition it emits toxic fumes of Rh
Acetylacetonato(1,5-cyclooctadiene)rhodium(I) Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Shanghai Hanhong Scientific Co.,Ltd. | 021-54306202 13764082696 | info@hanhongsci.com | China | 42917 | 64 |
| Chemsky(shanghai)International Co.,Ltd. | 021-50135380 | shchemsky@sina.com | China | 32273 | 50 |
| Nanjin Cynthia chemicals Technology Co.,Ltd | 0550-5618439 15951861180 | cynthiachem@163.com | China | 291 | 62 |
| Chengdu Ai Keda Chemical Technology Co., Ltd. | 4008-755-333 18080918076 | 800078821@qq.com | China | 9706 | 55 |
| Thermo Fisher Scientific | 800-810-5118 | cnchemical@thermofisher.com | China | 17752 | 75 |
| Beijing HuaMeiHuLiBiological Chemical | 010-56205725 | waley188@sohu.com | China | 12323 | 58 |
View Latest Price from Acetylacetonato(1,5-cyclooctadiene)rhodium(I) manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2021-07-02 | ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)
12245-39-5
|
$10.00-15.00 | 1KG | 99%+ HPLC | Zhuozhou Wenxi import and Export Co., Ltd | ||
![]() |
2020-01-09 | ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)
12245-39-5
|
$1.00 | 1KG | 99% | 100KG | Career Henan Chemical Co |
-

- ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)
12245-39-5
- $10.00-15.00
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
-

- ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)
12245-39-5
- $1.00
- 99%
- Career Henan Chemical Co





